Article
Chemistry, Physical
Yuqiang Sheng, Wenlu Li, Yongfa Zhu, Lili Zhang
Summary: The ultrathin PDI-phthalic nanosheet shows excellent photocatalytic performance, with high hydrogen evolution rate and efficient phenol degradation capability, outperforming other catalysts. The structure of ultrathin nanosheet, regulated by steric effect and hydrogen bonding, provides new ideas for the design of organic photocatalysts.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Jasper Deckers, Tom Cardeynaels, Laurence Lutsen, Benoit Champagne, Wouter Maes
Summary: In this study, four new donor-acceptor type perylene diimide (PDI) dyes were developed with high singlet oxygen quantum yields achieved without the aid of heavy atoms. Geometrical optimization and density functional theory calculations provided insights into the requirements for intersystem crossing.
Article
Multidisciplinary Sciences
Yongseok Hong, Maximilian Rudolf, Munnyon Kim, Juno Kim, Tim Schembri, Ana-Maria Krause, Kazutaka Shoyama, David Bialas, Merle I. S. Roehr, Taiha Joo, Hyungjun Kim, Dongho Kim, Frank Wuerthner
Summary: This study investigates the role of exciton coupling, exciton delocalization, and excimer state in facilitating the singlet fission process using a slip-stacked perylene bisimide array. The results provide insights into the structure-property relationship in dye arrays and have implications for the design of organic photonic and photovoltaic materials.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Zhaolong Wang, Yue Sun, Simin Lin, Gang Wang, Xingmao Chang, Xinyu Gou, Taihong Liu, Shengye Jin, Gang He, Yu-Chen Wei, Pi-Tai Chou, Yu Fang
Summary: The newly reported PBI-4Cz demonstrates exclusive charge separation within initial 0.5 ps, with resulting photo-physical effects significantly impacting multifunctional phototherapy.
SCIENCE CHINA-CHEMISTRY
(2021)
Article
Biochemistry & Molecular Biology
Katelyn M. Duncan, Donald L. Kellis, Jonathan S. Huff, Matthew S. Barclay, Jeunghoon Lee, Daniel B. Turner, Paul H. Davis, Bernard Yurke, William B. Knowlton, Ryan D. Pensack
Summary: This study investigates the electronic structure and excited-state dynamics of DNA-templated molecular aggregates. The researchers found a new nonradiative decay pathway in the dimers, which may facilitate singlet fission. This is of great significance in the fields of energy conversion and quantum information.
Article
Chemistry, Applied
Raquel C. R. Goncalves, Joao Pina, Susana P. G. Costa, M. Manuela M. Raposo
Summary: The study found that a BODIPY derivative showed a significant enhancement in singlet oxygen sensitization quantum yield with the decrease of solvent dielectric constant. Triplet state formation for the derivative was mediated by intramolecular charge transfer state in toluene, while hindered by fast recombination of the ICT state in polar solvents. The photoinduced dynamics of the BODIPY derivatives were characterized from femtosecond to nanosecond time scale using pump-probe transient absorption spectroscopy.
Article
Chemistry, Multidisciplinary
Pai Geng, Dezhang Chen, Sunil B. B. Shivarudraiah, Xihan Chen, Liang Guo, Jonathan E. E. Halpert
Summary: By studying the AgBiS2/Pc heterojunction, transient absorption spectroscopy was used to investigate singlet fission and carrier transfer processes. The transfer of triplets from pentacene to AgBiS2 and the transfer of holes from AgBiS2 to pentacene were observed. Singlet fission in pentacene was enhanced by modifying the crystallinity of the pentacene layer, and the first singlet fission AgBiS2/Pc solar cell was successfully fabricated. Singlet fission devices demonstrated higher external quantum efficiency, indicating the significant contribution of charges from the singlet fission process.
Article
Multidisciplinary Sciences
Xuejian Ma, Fei Zhang, Zhaodong Chu, Ji Hao, Xihan Chen, Jiamin Quan, Zhiyuan Huang, Xiaoming Wang, Xiaoqin Li, Yanfa Yan, Kai Zhu, Keji Lai
Summary: The study directly probes the free-carrier dynamics in Cs-doped FAPbI(3) thin films using spatiotemporal photoconductivity imaging, revealing that the lifetimes of electrons and holes in the material are compensated by their disparate mobility, resulting in comparable long diffusion lengths for both carriers. This unique charge trapping and de-trapping processes in hybrid trihalide perovskites play a crucial role in determining the superior diffusion dynamics of the material, which is vital for solar-cell applications.
NATURE COMMUNICATIONS
(2021)
Article
Chemistry, Physical
Wentao Zhang, Kunrui Wei, Wenguang Huang, Jianghua Yang, Yonghai Gan, Shujuan Zhang
Summary: Post-synthetic modification with beta-diketone has been shown to enhance the visible light response activities of metal-organic frameworks (MOFs). Through a joint mechanism of exciton-mediated energy transfer and photosensitization, diketone anchoring can improve the photocatalytic generation of singlet oxygen (O-1(2)) by MOFs.
APPLIED CATALYSIS A-GENERAL
(2021)
Article
Chemistry, Physical
Su Chen, Jiawang Zhou, Ryan M. Young, Michael R. Wasielewski
Summary: The study explores the excited-state decay pathways in organic chromophore assemblies by covalently attaching them to AAO membranes, showing that the interchromophore spacing can affect the charge transfer properties of excimer states. The charge separation process increases with solvent polarity in a symmetric breaking charge separation, while it decreases with an increase in average distance between chromophores.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Biochemistry & Molecular Biology
Igor E. Mikhnovets, Jiri Holoubek, Irina S. Panina, Jan Kotoucek, Daniil A. Gvozdev, Stepan P. Chumakov, Maxim S. Krasilnikov, Mikhail Y. Zhitlov, Evgeny L. Gulyak, Alexey A. Chistov, Timofei D. Nikitin, Vladimir A. Korshun, Roman G. Efremov, Vera A. Alferova, Daniel Ruzek, Ludek Eyer, Alexey V. Ustinov
Summary: Amphipathic perylene derivatives are effective antiviral compounds that target the viral envelope and act as fusion inhibitors. They damage the viral envelope using lipophilic perylene and singlet oxygen generated by light. Short alkyl chains contribute to strong antiviral activity, while longer alkyl chains reduce activity due to increased lipophilicity and aggregation.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Physical
Stefan Neppl, Johannes Mahl, Friedrich Roth, Giuseppe Mercurio, Guosong Zeng, Francesca M. Toma, Nils Huse, Peter Feulner, Oliver Gessner
Summary: This study investigates the transient charge distribution of a model hybrid system of nanoporous zinc oxide and ruthenium bipyridyl chromophores using time-resolved X-ray photoemission. The results show that the photoinjected electrons remain localized within less than 6 nm from the interface, leading to enhanced surface recombination and lower performance compared to titanium dioxide-based systems.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2021)
Article
Chemistry, Physical
Huihui Xu, Zhiqiang Wang, Shufan Feng, Xinman Liu, Xueqing Gong, Jianli Hua
Summary: In recent years, PDI-based supramolecular photocatalysts have attracted significant attention. The charge localization effects hinder the charge transfer in PDI, resulting in a high recombination rate and limited activity. This study developed three heteroatom bay-annulated perylene diimide supramolecule photocatalysts (N-APDI, S-APDI, and Se-APDI) for photocatalytic H2 evolution. Under visible-light irradiation, heteroatom-annulated PDI supramolecules exhibited better H2 evolution rate than non-heteroatom APDI, with N-APDI showing the highest hydrogen production rate of 61.49 mmol g-1 h-1 and an apparent quantum yield (AQY) of 5.90% at 420 nm. The improved photocatalytic activity of heteroatom-annulated PDI supramolecules can be attributed to stronger molecular dipole, which enhances the internal electric field magnitude and promotes charge separation and migration. Furthermore, heteroatom annulation can act as a more beneficial active site to promote HER activity. This work provides a new strategy for the development of supramolecular photocatalysts.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Materials Science, Multidisciplinary
Yuseong Kim, Byoungnam Park
Summary: We demonstrate an enhanced photo-Seebeck effect in air-stable MAPbI(3) perovskite through optical gating. Illumination by a laser diode leads to a significant increase in both the Seebeck coefficient and electrical conductivity. The n-type MAPbI(3) perovskite with residual PbI2 shows higher Seebeck enhancement and photoconductivity compared to the p-type perovskite. This indicates that the presence of PbI2 accelerates photoinduced charge transfer at the interface, resulting in dedoping and enhanced photo-Seebeck effect.
Article
Nanoscience & Nanotechnology
Xingchi Xiao, Liang Cheng, Di Bao, Qi Ying Tan, Teddy Salim, Cesare Soci, Elbert E. M. Chia, Yeng Ming Lam
Summary: Singlet fission (SF) materials have been used to improve the power conversion efficiency (PCE) of solar cells. However, SF implementation in perovskite solar cells has not been successful due to the lack of understanding of the SF/perovskite heterojunctions. In this study, the charge dynamics between a well-known SF molecule, TIPS-pentacene, and a triple-cation perovskite Cs-0.05(FA(0.85)MA(0.15))(0.95)PbI2.55Br0.45 were investigated. The results show that there is an electron-transfer process from TIPS-pentacene to perovskite, leading to an increase in carrier density in the perovskite layer. This study confirms the potential of SF-enhanced perovskite solar cells.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Review
Energy & Fuels
Qi-Meng Sun, Jing-Hui He, Jian-Mei Lu
Summary: This paper reviews recent advances in flexible absorption materials, including their definition, theoretical development, and classification. Potential application examples of flexible absorption materials are analyzed to guide their future development.
ENERGY SCIENCE & ENGINEERING
(2023)
Article
Chemistry, Physical
Yibo Zhang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: Multidimensional hierarchical hollow Co3O4/ZnIn2S4 tubular core-shell heterostructures were prepared by growing ultrathin 2D ZnIn2S4 nanosheets on 1D hollow Co3O4 nanotubes using a solvothermal method. This design not only prevents the self-assembly aggregation of ZnIn2S4 nanosheets, but also broadens their light-absorption range and enhances the utilization of visible light. The p-n heterojunction in the photocatalyst generates an internal electric field, which facilitates the separation and migration of photogenerated charge carriers and effectively suppresses their recombination.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Xi Liu, Jingkun Li, Andrea Zitolo, Meng Gao, Jun Jiang, Xiangtian Geng, Qianqian Xie, Di Wu, Huizhen Zheng, Xiaoming Cai, Jianmei Lu, Frederic Jaouen, Ruibin Li
Summary: In this study, it was found that metal-nitrogen-doped graphene materials can catalyze the oxidation of NADH into NAD+. Specifically, FeNGR exhibited NOX-like activity and high selectivity, and could target the liver to remedy metabolic flux anomaly in NAD+-deficient obese mice.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Guping Zhang, Xunxun Li, Mengmeng Wang, Xueqing Li, Yaru Wang, Shuting Huang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: This research constructs a stable p-n heterojunction of 2D/2D Co3O4/ZnIn2S4 with a strong built-in electric field, resulting in a highly efficient visible-light photocatalytic hydrogen generation. The improved photocatalytic performance is attributed to enhanced light absorption, abundant active sites, short charge transport distance, and high separation efficiency of photogenerated carriers. This study provides a new approach for the rational design and manufacturing of highly efficient 2D/2D heterojunction photocatalysts.
Article
Horticulture
Jian-mei Lu, Sven Landrein, Xing-zhen Song, Min Wu, Chun-fen Xiao, Peng Sun, Hui-zhen Jia, Jia-rui Yue, You-kai Xu
Summary: This study investigated the effect of polyploidy on phenotypic traits in different variants of Kaempferia. The results showed significant differences in traits such as leaf width and stomatal density. Furthermore, pentaploid individuals had higher (E)-Ethyl-p-methoxycinnamate content in their rhizomes but lower content in their leaves. These findings provide valuable references for plant identification and breeding in Kaempferia.
SCIENTIA HORTICULTURAE
(2023)
Article
Chemistry, Multidisciplinary
Chang Zhou, Qi-Meng Sun, Qiang Cao, Jing-Hui He, Jian-Mei Lu
Summary: Atomically dispersed Fe on three-dimensional N-doped carbon supports shows promise as a catalyst for microwave remediation of soil contaminated by Chloramphenicol (CAP). Due to the synergistic effect of microwave hot spots and reactive oxygen species, the catalyst can rapidly and effectively remove CAP from the soil.
Article
Engineering, Environmental
Licheng Wan, Jun Han, Wenrou Tian, Najun Li, Dongyun Chen, Jianmei Lu
Summary: Both large adsorption capacity and high catalytic activity are essential for water purification through effective degradation of organic pollutants. In this study, a core-shell heterostructure (BTO@TD-COF) was fabricated for efficient adsorption and piezo-photocatalytic degradation of bisphenol A in water. BTO@TD-COF exhibited outstanding piezo-photocatalytic activity due to enhanced carrier separation by the built-in electric field generated in BTO under simultaneous ultrasound and visible-light irradiation. With favorable catalytic and adsorption performance, BTO-3@TD-COF (25 mg) achieved complete degradation of 5 ppm bisphenol A (1000 mL) within 75 min, which was significantly faster than BTO and TD-COF.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Inorganic & Nuclear
Xiaofang Liu, Jianhua Zhang, Liujun Jin, Chunchao Chen, Jinghui He, Qingfeng Xu, Jianmei Lu
Summary: Urea degradation is crucial in the nitrogen cycle, and understanding the electro-oxidation mechanism and designing catalysts is significant. A stable and active catalyst (PBA@NiFe/NF) loaded on nickel foam was synthesized, and in situ Raman spectra showed the maintenance of stable Ni(II) state during urea oxidation. The participation of iron significantly improved the electro-oxidation of urea. This work provides new insights for prolonging Ni(II) activity in urea electrocatalytic oxidation.
INORGANIC CHEMISTRY
(2023)
Article
Polymer Science
Wu-Ji Sun, Xiong-Jun Liu, Li-Juan Yuan, Han Xiao, Jian-Mei Lu
Summary: Polyethylene has limitations in HV/UHV power cables due to its low thermal stability and breakdown strength, despite its excellent electrical insulation. A new organic peroxide, Bi25, has been developed to efficiently trigger the crosslinking of polyethylene (Bi25-XLPE). Bi25-XLPE, with void-free nature, higher crosslinking density, and crystallinity, meets the insulation standard for 500 kV power cables. The breakdown strength (up to 61.66 kV/mm) and stability of Bi25-XLPE are confirmed by a constructed 500 kV power cable model using COMSOL.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Physical
Xueqing Li, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: In this study, an all-organic S-scheme heterojunction (PDINH/PCN) was obtained by in situ recrystallization of perylene-3, 4, 9, 10-tetracarboxylic diimide (PDINH) on the surface of porous carbon nitride (PCN). This structure enables the light-driven reaction of oxygen and water to produce hydrogen peroxide (H2O2), converting solar energy into green products. The design of a hierarchical porous photocatalyst improved mass transfer, enhanced light absorption, and increased specific surface area. The S-scheme heterojunction formed at the interface of PDINH and PCN facilitated carrier separation and transfer. The H2O2 production rate reached 922.4 lmol g-1h-1, which was 2.6 and 53.3 times higher than that of PCN and PDINH, respectively. Therefore, the all-organic S-scheme heterojunction provides insight for enhancing photocatalytic H2O2 production.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Wenrou Tian, Jun Han, Licheng Wan, Najun Li, Dongyun Chen, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: Lattice strain engineering induced by the difference in ion sizes was utilized to improve the piezoelectricity of SnS2, achieving complete removal of bisphenol A and high hydrogen generation. This lattice distortion engineering can serve as a guideline for the development of piezocatalysts for environmental remediation and production of hydrogen energy.
Article
Nanoscience & Nanotechnology
Jinyan Huo, Liujun Jin, Chunchao Chen, Dongyun Chen, Zhichuan Xu, Cecilia Devi Wilfred, Qingfeng Xu, Jianmei Lu
Summary: This study demonstrates the production of sulfur using a sulfide oxidation reaction (SOR) technique, and shows that a NiS-doped cobalt sulfide NiS-CoS-supported NiCo alloy foam can serve as a superior electrocatalyst with high stability. It also reveals the sulfurophobicity feature of the catalyst, preventing electrode corrosion during the SOR process. Additionally, the study unveils the chain-growth mechanism of the SOR.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Engineering, Chemical
Bingshu Jiang, Dongyun Chen, Najun Li, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: This study reports a photocatalyst based on reduced graphene oxide and CdS nanoparticles, modified with anthraquinone-2-sulfonate (AQS), which achieved a photocatalytic H2O2 yield of 558 μmol g(-1) h(-1) in purified water. The high performance of this composite photocatalyst is attributed to the combination of graphene and CdS promoting charge-carrier separation/transfer, increasing the quantity of adsorption and reaction sites, and the selective two-electron oxygen reduction capacity of AQS.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Nanoscience & Nanotechnology
Shuxian Wang, Wenrou Tian, Jun Han, Najun Li, Dongyun Chen, Qingfeng Xu, Hua Li, Jianmei Lu
Summary: In this study, self-assembled monolayers (SAMs) were constructed on the surface of Ti3C2 MXene to improve its environmental stability and piezocatalytic activity. The surface-treated Ti3C2 exhibits different lattice parameters and symmetry, leading to an increased polarization. The presence of polar functional groups in SAMs significantly increases the surface potential of Ti3C2, promoting the migration of piezoelectric electrons. Among the different SAMs, Ti3C2/SAMs-NH2 shows the highest piezocatalytic performance, improving the removal of BPA and the production of H-2 by 7 and 1.8 times, respectively, and remains stable under 100% relative humidity for 15 days.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Nanoscience & Nanotechnology
Jinyan Huo, Liujun Jin, Chunchao Chen, Dongyun Chen, Zhichuan Xu, Cecilia Devi Wilfred, Qingfeng Xu, Jianmei Lu
Summary: This study demonstrates the use of a sulfur-doped nickel-cobalt sulfide catalyst for the sulfur production reaction from sulfide solution. The catalyst shows superior electrocatalytic activity and stability compared to other non-noble metal-based catalysts. The unique sulfurophobicity feature of the catalyst prevents electrode corrosion during the reaction. The study also reveals the chain-growth mechanism of the reaction and the direct transfer of electrons during the low-energy-consumption process.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Panpan Zhang, Xu Wang, Yangyang Yang, Haifeng Yang, Chunsheng Lu, Mingru Su, Yu Zhou, Aichun Dou, Xiaowei Li, Xiaochuan Hou, Yunjian Liu
Summary: In this study, the influence of transition metal doping on the electronic and mechanical properties and electrochemical performance of 2HMoS2/NC was investigated using Cobalt (Co) as an example. Co doping was found to effectively improve the electronic conductivity and active site areas of 2H-MoS2/NC at different positions, optimizing the adsorption and diffusion capability of potassium ions. Furthermore, the study revealed the optimal roles of different types of nitrogen atoms in kinetic adsorption, diffusion, and interfacial stability of potassium ions. These findings provide guidance for the experimental design of high rate 2H-MoS2/NC electrode materials and the optimal design of other functional composite materials.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zeeshan Ajmal, Mahmood Ul Haq, Shahid Zaman, M. K. Al-Muhanna, Anuj Kumar, Mohammed M. Fadhali, Siwar Ben Hadj Hassine, Muhammas Qasim, K. F. Alshammari, Ghulam Abbas Ashraf, Abdul Qadeer, Adil Murtaza, Sulaiman Al-Sulaimi, Huaqiang Zeng
Summary: This study presents a novel heterojunction structure (SrTiO3/CN-TAL10.0) for enhanced photocatalytic water splitting (PWS). The incorporation of thiophenedicarboxaldehyde (TAL) through copolymerization significantly improves the photocatalytic activity of carbon nitride (CN) while maintaining its photostability performance. The optimized composition allows efficient isolation of photoinduced charge carriers and enhanced charge transport, resulting in a remarkable increase in overall photocatalytic efficiency.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Angela Arnosa-Prieto, Patricia Diaz-Rodriguez, Manuel A. Gonzalez-Gomez, Pelayo Garcia-Acevedo, Lisandra de Castro-Alves, Yolanda Pineiro, Jose Rivas
Summary: Macrophages can exhibit different phenotypes depending on the microenvironment and the characteristics of magnetic iron oxide nanoparticles (MNPs). This study demonstrates that the concentration and morphology of MNPs can influence the polarization of macrophages. The findings have implications for therapeutics targeting tissue regeneration and tumor progression.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yu Fang, Cheng-Ye Zhu, Hao-Cheng Yang, Chao Zhang, Zhi-Kang Xu
Summary: This study demonstrates the advantages of vacuum-assisted interfacial polymerization (VAIP) in fabricating polyimide nanofiltration membranes. By using vacuum filtration, aqueous solutions of PIP can be evenly distributed on different microfiltration substrates, leading to the fabrication of uniform and ultra-thin polyamide layers with excellent performance. The membranes exhibit high rejection rates and water permeance, as well as satisfactory long-term stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Isaac J. Gresham, Edwin C. Johnson, Hayden Robertson, Joshua D. Willott, Grant B. Webber, Erica J. Wanless, Andrew R. J. Nelson, Stuart W. Prescott
Summary: Understanding the interactions between polymers and surfactants is crucial for optimizing commercial systems. This study tested the behavior of polymer-surfactant systems, revealing that they do not behave like polyelectrolytes in the presence of salt. Additionally, the structure of polymer-surfactant complexes under confinement differs from that of polyelectrolytes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yunxiao Xie, Cui Liu, Jie Zhang, Yan Li, Bin Li, Shilin Liu
Summary: This study aimed to improve the microstructure and rheological properties of W/W Pickering emulsions by crosslinking sodium alginate at the water-water interface, thereby enhancing the activity of encapsulated probiotics in simulated gastrointestinal digestion.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Sang Ho Lee, Yige Sun, Patrick S. Grant
Summary: This research developed an effective approach to enhance the charging rates of lithium ion batteries (LIBs) by strategically incorporating carbon nanotube (CNT) conductivity boosters into Li4Ti5O12 (LTO) electrodes. Multi-layer architectures comprising CNT-rich and CNT-free LTO electrode layers were manufactured using a layer-by-layer spray coating method to promote charge transfer kinetics of high mass loading electrodes. The best performing multi-layer was paired with a spray-coated LiFePO4 (LFP) positive electrode, resulting in attractive power performance that outperformed conventional LTO || LFP combinations.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jingwei Liang, Shaobin Li, Fengbo Li, Li Zhang, Yufeng Jiang, Huiyuan Ma, Kun Cheng, Liang Qing
Summary: A molybdenum-regulated self-supporting electrode material with rich vacancy defects has been successfully synthesized and shows exceptional catalytic activities and stability for electrocatalytic overall water splitting. This study provides a new perspective for the design and synthesis of non-precious metal bifunctional electrocatalysts.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jonas Blahnik, Jennifer Schuster, Rainer Mueller, Eva Mueller, Werner Kunz
Summary: This study investigates the relationship between the morphology of PMMA monopolymers and PMMA-PHEMA copolymers with the expected nature of surfactant-free microemulsions (SFMEs) before polymerization. It is found that previously mesostructured, surfactant-free mixtures can produce porous polymers of different morphologies, while unstructured, oil-rich regions lead to solid, transparent polymers without nanostructured morphologies. Additionally, a surfactant-based reference system shows similar phase behavior and polymer morphologies as the comparable surfactant-free system, indicating the importance of the hydrotropic behavior of HEMA in this system.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zheng-Fen Pu, Wen-Zhi She, Rong Sheng Li, Qiu-Lin Wen, Bi-Chao Wu, Chun-Hua Li, Jian Ling, Qiue Cao
Summary: This study synthesized two framework-isomeric covalent organic frameworks (COFs) and discovered that the light scattering signal of COFs can be used for the analytical detection of lead ions. By controlling synthesis conditions and introducing regulators, the morphology of COFs could be controlled and framework-isomeric COFs could be precisely synthesized.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yuchen Weng, Ying Hong, Jingyu Deng, Sicheng Cao, Li-Juan Fan
Summary: This paper reports the preparation of dynamic color-changing fluorescent polymer nanoparticles (PNPs) by constructing a fluorescence resonance energy transfer (FRET) pair. The PNPs show excellent anti-counterfeiting effects and reproducibility. The study demonstrates a promising encryption strategy that can achieve multiple outputs with simple operation.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Guodong Liu, Zijian Wang, Jianing Wang, Hanbin Liu, Zhijian Li
Summary: This study investigates the combination of multicolor switchable polyaniline (PANI) electrode and 1-methyl-4,4'-bipyridyl iodide (MBI), which demonstrates superior optical properties in visible and near-infrared light modulation, as well as excellent electrochemical performances. This combination can be used to develop novel electrochromic devices for applications in smart packaging, smart labels, and flexible smart windows.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Huying Yan, Yang Guo, Xingzhi Bai, Jiawei Qi, Haipeng Lu
Summary: By modifying Ti3C2Tx through heterogeneous interface engineering, optimized impedance matching is achieved, leading to enhanced electromagnetic wave absorption performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Kehu Zhang, Yang Zhou, Silvia Moreno, Simona Schwarz, Susanne Boye, Brigitte Voit, Dietmar Appelhans
Summary: This article presents an advanced crosslinking strategy to fabricate clustered polymersomes using host-guest interactions. By controlling the input of crosslinker and environmental conditions, reversible aggregation and disassembly of these polymersomes can be achieved. The size and structure of these clustered polymersomes can be regulated and visualized through a fluorescent enzymatic cascade reaction.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Physical
Junjie Xu, Weixiong Huang, Ruiling Li, Li Li, Jinjin Ma, Jiaou Qi, Haiyan Ma, Min Ruan, Lilin Lu
Summary: In this study, a potassium doped palladium catalyst was developed for acetylene hydrogenation, showing excellent catalytic performance and durability. The doping of potassium effectively weakened the adsorption of ethylene, improved ethylene selectivity, and lowered the barriers of hydrogen activation and transfer reactions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
