4.7 Article

Synthesis of porous-carbon@reduced graphene oxide with superior electrochemical behaviors for lithium-sulfur batteries

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 851, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.156832

Keywords

Lithium-sulfur batteries; Porous carbon; Reduced graphene oxide; Cathode; Capacity

Funding

  1. Natural Science Research Project for Universities in Anhui Province [KJ2018B14]
  2. Science and Technology Major Project of Anhui Province [18030901093]
  3. Key Research and Development Program of Wuhu [2019YF07]

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A nanosheet-like porous-carbon@reduced graphene oxide (PC@rGO) composite was prepared successfully via a facile method, showing high capacity and reversible capacity in Li-S batteries, indicating a promising direction for research on high energy density Li-S batteries.
Nanosheet-like porous-carbon@reduced graphene oxide (PC@rGO) composite is successfully prepared via a facile soaking and freeze-drying process followed by heat treatment. The structural and morphological characterizations demonstrate that the porous-carbon is homogenously embedded with rGO. When employed as a cathode material for Li-S batteries, the electrode delivers a high capacity of 634 mAh g(-1) at 1.0 A g(-1) after 100 cycles. Moreover, the reversible capacities of the composites reached 871, 792 and 694 mAh g(-1) at 0.2, 0.5 and 1.0 A g(-1), respectively. The outstanding electrochemical performance of the composites demonstrates a promising direction for research on superior high energy density Li-S batteries. (C) 2020 Elsevier B.V. All rights reserved.

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