4.7 Article

Microstructural evolution and strengthening mechanisms in cold-rolled Cu-Ag alloys

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 851, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.156893

Keywords

Copper alloy; Eutectic; Dislocation strengthening; Microstructure; Deformation

Funding

  1. Special Program for Key Innovative of Science and Technology from Ningbo Science and Technology Bureau, China [2018B10053]
  2. Youth Jinggang Scholars Program in Jiangxi Province

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This study experimentally investigated the microstructural evolution and strengthening mechanisms of pure copper and Cu-Ag alloys subjected to cold rolling. The results showed that dislocation strengthening and boundary strengthening were the dominant mechanisms in cold-rolled Cu-Ag alloys, with the addition of silver leading to higher steady-state strength due to increased concentration of dislocations and subgrain boundaries, and a larger volume fraction of high-strength eutectic colonies in Cu-15Ag compared to Cu-10Ag.
In this work, the microstructural evolution and strengthening mechanisms of pure copper and Cu-Ag alloys subjected to cold rolling were experimentally investigated. Significant strain strengthening occurred during cold rolling, with steady-state strengths of 424, 666, and 686 MPa achieved upon large-strain cold rolling in pure copper, Cu-10Ag, and Cu-15Ag, respectively. Microstructural examination was performed to quantitatively determine the strengthening contributions of the grain boundaries, dislocations, Ag dispersoids, and solute atoms. Dislocation strengthening and boundary strengthening were shown to be the dominant strengthening mechanisms in the cold-rolled Cu-Ag alloys at steady state, accounting for >80% of the strengthening. In addition, Ag addition increased the limiting concentration of dislocations and subgrain boundaries in the Cu solid solution, resulting in higher steady-state strength of the cold-rolled Cu-Ag alloys relative to that of pure copper. The high Ag concentration also led to a larger volume fraction of the high-strength eutectic colony in Cu-15Ag, resulting in higher strength than that of Cu-10Ag. (C) 2020 Elsevier B.V. All rights reserved.

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