4.7 Article

Hierarchical porous TiNb2O7@N-doped carbon microspheres as superior anode materials for lithium ion storage

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 5, Pages 3425-3436

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.10.190

Keywords

Lithium-ion batteries; Anode material; TiNb2O7; N-doped carbon

Funding

  1. National Natural Science Foundation of China [21501101]
  2. Natural Science Foundation of Henan Province [182300410226]
  3. Technological Project of Henan Province [182102310068]
  4. Basic Construction Fund in Jilin Province [2019C042-8]
  5. Science and Technology Development Program of Jilin Province [20190103003JH]

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In this study, an ultrathin N-doped carbon coating was deposited onto hierarchical porous TiNb2O7 microspheres, leading to enhanced rate performance and cycling stability in lithium-ion batteries. TiNb2O7@N-doped carbon microspheres show promising potential as a negative electrode for high-power LIBs.
TiNb2O7 is considered to be one of the ideal candidate anode materials for lithium-ion batteries (LIBs) because of its safe working potential and high theoretical capacity. However, its low intrinsic conductivity and poor ionic diffusion rate hinder its practical application. In this study, an ultrathin N-doped carbon coating was uniformly deposited onto hierarchical porous TiNb2O7 microspheres by combining a solvothermal route with a carbonization process using ionic liquid. The TiNb2O7@N-doped carbon microspheres exhibited an ultra-high rate performance (208 mA h g(-1) at 30 C) and excellent cycling stability (specific capacity retention of 79% after 500 cycles at 10 C), and showed excellent electrochemical performance in a full cell using LiNi0.5Mn0.3Co0.2O2 as a cathode. The superior performance can be attributed to the synergistic effects between the ultrathin N-doped carbon coating and unique microstructure. Therefore, TiNb2O7@N-C is a promising negative electrode for high-power LIBs. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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