Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 14, Pages 9314-9323Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.12.104
Keywords
Al-Bi-Zn composite powder; Gas atomization; Hydrogen production performance; Morphology evolution
Categories
Funding
- National Natural Science Foundation of China [51771158]
- Development and Reform Commission of Shenzhen Municipality [ZX20190229]
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The development of Al-Bi-Zn composite powders showed promising results in stable and high conversion rate hydrogen production, which could further improve the efficiency of hydrogen-oxygen fuel cells and extend their working life.
The development of mild hydrogen-generating materials is of great significance to improve the working life of hydrogen-oxygen fuel cells. In this study, Al-Bi-Zn composite powders were designed by phase diagram calculation and then prepared via the gas atomization method. The results indicated that the conversion yield of Al-12Bi-7Zn (wt.%) powder reached 98% with stable hydrogen production within 280 min at 50 degrees C. When composite powder reacted with NaCl solution to produce hydrogen, the dormant period of the reaction process was significantly shortened, but the conversion rate was slightly reduced. Additionally, the evolution of powder morphology during the reaction was investigated. The results showed that the continuous cracking of the powder led to the continuous exposure of fresh Al to react. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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