Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 2, Pages 2117-2127Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.10.098
Keywords
Scale biowaste; Porous carbon; Electrocatalyst; Oxygen reduction
Categories
Funding
- National Natural Science Foundation of China [21805024]
- Basic Research and Frontier Exploration Project of Chongqing Municipality [cstc2018jcyjAX0461]
- Scientific and Technological Research Program of Chongqing Municipal Education Commission [KJQN201901335]
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A strategy to synthesize 3D porous nitrogen-doped network carbons for catalyzing the ORR has been proposed, showing comparable activity with Pt/C catalyst and outstanding stability. High electron transfer number and low peroxide yield indicate a four-electron reaction pathway, while the 3D porous structures effectively expose catalytic sites and promote mass transportation.
It is of great urgency to design inexpensive and high-performance oxygen reduction reaction (ORR) electrocatalysts derived from biowastes as substitutes for Pt-based materials in electrochemical energy-conversion devices. Here we propose a strategy to synthesize three-dimensional (3D) porous nitrogen-doped network carbons to catalyze the ORR from two-step pyrolysis engineering of biowaste scale combined with the use of a ZnCl2 activator and a FeCl2 promotor. Electrochemical tests show that the synthesized network carbons have exhibited comparable ORR catalytic activity with a half-wave potential (similar to 0.85 V vs. RHE) and outstanding cyclical stability in comparison to the Pt/C catalyst. Beyond that, a high electron transfer number (similar to 3.8) and a low peroxide yield (<7.6%) can be obtained, indicating a four-electron reaction pathway. The maximum power density is similar to 68 mW cm(-2), but continuous discharge curves (at a constant potential of similar to 1.30 V) for 12 h are not obviously declined in Zn-air battery tests using synthesized network carbons as the cathodic catalyst. The formation of 3D porous structures with high BET surface area can effectively expose the surface catalytic sites and promote mass transportation to boost the ORR activity. This work may open a new idea to prepare porous carbon-based catalysts for some important reactions in new energy devices. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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