Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 2, Pages 314-317Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001335
Keywords
Enol phosphates; Phosphoric acids; Regioselectivity; Synthetic methods; Ynamides
Categories
Funding
- Liaoning Normal University [2019-BS151]
- Department of Science and Technology of Liaoning Province [2019-BS151]
- National Natural Science Foundation of China [81973540]
- Weifang University of Science and Technology [KJRC2019005, KJRC2020002]
Ask authors/readers for more resources
The metal-free hydrophosphoryloxylation of ynamides with phosphoric acids offers a rapid route to useful enol phosphates, with high selectivity, short reaction time, high efficiency, and wide substrate scope. Additionally, the products can act as effective partners in Suzuki-Miyaura cross-coupling reactions.
We herein report a metal-free hydrophosphoryloxylation of ynamides with phosphoric acids, which provides an expeditious route to access useful enol phosphates. The advantages of this protocol include exclusive selectivity, short reaction time, high efficiency, and broad substrate scope. Additionally, the products can serve as good partners in Suzuki-Miyaura cross-coupling.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
