Reversible Speed Regulation of Self-Propelled Janus Micromotors via Thermoresponsive Bottle-Brush Polymers

This work reports a reversible braking system for micromotors that can be controlled by small temperature changes (approximate to 5 degrees C). To achieve this, gated-mesoporous organosilica microparticles are internally loaded with metal catalysts (to form the motor) and the exterior (partially) grafted with thermosensitive bottle-brush polyphos-phazenes to form Janus particles. When placed in an aqueous solution of H2O2 (the fuel), rapid forward propulsion of the motors ensues due to decomposition of the fuel. Conformational changes of the polymers at defined temperatures regulate the bubble formation rate and thus act as brakes with considerable deceleration/acceleration observed. As the components can be easily varied, this represents a versatile, modular platform for the exogenous velocity control of micromotors.

Automated summary

This study presents a reversible braking system for micromotors that can be controlled by small temperature changes. By using metal catalysts and thermosensitive polymers, the system controls bubble formation rate to regulate deceleration and acceleration for micromotors, providing a versatile and modular platform for external velocity control.