Article
Materials Science, Ceramics
Sami-ullah Rather, Hisham S. Bamufleh, Hesham Alhumade
Summary: The effects of Al3+ substitution in nanocrystalline cobalt ferrite were investigated using various characterization techniques. The results showed that thermal treatment played a significant role in the structure and properties of the aluminum-doped cobalt ferrite at the nanostructured scale. X-ray photoelectron spectroscopy (XPS) analysis revealed information about the composition and chemical state, confirming specific magnetic properties in the nano Al-doped cobalt ferrite.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
O. Dehghani Dastjerdi, H. Shokrollahi, N. Asakereh Raad
Summary: This study evaluated the structural and magnetic properties of rare-earth-doped garnets prepared by the solid-state route. The samples with Bi3+ cations showed the maximum saturation magnetization, while the presence of La3+ led to a decrease in Ms.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Materials Science, Ceramics
Sachin Kumar Godara, Mandeep Singh, Varinder Kaur, S. B. Narang, Ashwani Kumar Sood
Summary: In this study, Ba1-xCaxFe12O19 samples were synthesized using sol-gel auto-combustion method, with the maximum calcium solubility observed at 1200 degrees C. The XRD data showed a decrease in lattice parameters and cell volume with increasing 'x', while FESEM images revealed an increase in particle size. Magnetic measurements indicated that the highest saturation magnetization was found in the x = 0.50 sample, with a decrease in coercivity as 'x' increased.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Ritu Rani, Khalid Mujasam Batoo, Pankaj Sharma, Gagan Anand, Gagan Kumar, Sumit Bhardwaj, M. Singh
Summary: Intensive research has been conducted on spinel nano-ferrites due to their unique size dependent chemical and physical properties. Fabricated through solution-combustion method, cobalt-zinc spinel nano-ferrites doped with indium have been characterized for their structural, morphological, electric, and dielectric properties. The addition of In3+ ions has been found to increase resistivity and decrease dielectric constant with frequency, making these spinel nano-ferrites potentially useful for microwave applications.
CERAMICS INTERNATIONAL
(2021)
Article
Engineering, Manufacturing
Wei Xiao, Bei Li, Jun Yan, Ling Wang, Xuewu Huang, Jiefeng Gao
Summary: Three dimensional graphene-based hybrid materials have attracted much interest and are being applied in various fields. These materials provide a framework for other functional materials and facilitate electron and mass transport during reactions. The synthesis methods, morphology, and applications of these hybrids are reviewed, with challenges and prospects discussed for future development.
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
(2023)
Article
Materials Science, Multidisciplinary
Munmun Basak, Md. Lutfor Rahman, Md. Farid Ahmed, Bristy Biswas, Nahid Sharmin
Summary: A comprehensive analysis of the calcination effect on nano-sized cobalt ferrite particles synthesized by co-precipitation technique was conducted. The results showed a strong relationship between crystallite size, particle size, and magnetic properties with calcination temperature.
MATERIALS CHEMISTRY AND PHYSICS
(2021)
Article
Materials Science, Ceramics
J. G. R. Hernandez-Arteaga, Hiram Joazet Ojeda-Galvan, J. Alanis, M. C. Rodriguez-Aranda, E. G. Villabona-Leal, E. Mendoza-Mendoza, Nicolas A. Ulloa-Castillo, M. Quintana, Hugo R. Navarro-Contreras, A. G. Rodriguez
Summary: CeO2 nanotubes were synthesized via a hydrothermal method and their morphological evolution under heat treatment in air was studied, showing significant changes in catalytic activity. The resulting material exhibited superior catalytic performance, with potential applications in water remediation for degrading textile dyes.
CERAMICS INTERNATIONAL
(2022)
Article
Materials Science, Multidisciplinary
Ala Manohar, V. Vijayakanth, S. V. Prabhakar Vattikuti, Ki Hyeon Kim
Summary: Supercapacitors, with their long cycle life, significant power storage capacity, and quick recharge ability, have gained great interest from scientists. Recent research has identified transition metal oxides as the best material for flexible supercapacitors. Characterization studies using XRD, FE-SEM, EDS mapping, ESR, and BET have shown that synthesized Ni-doped MgFe2O4 nanoparticles, with a typical size range of 8-11 nm, exhibit exceptional performance as pseudocapacitors. The Ni0.35Mg0.65Fe2O4 electrode, coded as NM3, demonstrated a specific capacitance of 119.04 F/g at a current density of 1.1 A/g in 1 M KOH solution, outperforming NM1 and NM2 electrodes. EIS analysis confirmed the excellent electrochemical properties of these nanoparticles, suggesting their potential for supercapacitor applications.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Biotechnology & Applied Microbiology
Kepeng Huang, Longlong Wang, Mingke Li, Tongtong Mi, Jiale Zhang, Jun Liu, Xuemei Yi
Summary: This study focuses on using corn stalks as a pore-forming agent to create porous ceramics with Second Aluminum Dross (SAD). The results indicate that corn stalks react with oxygen at high temperatures to form micron-sized pores and leave nano-sized pores through water vapor in the colloid channel. The resulting porous ceramics have a loose and uniform structure with a large specific surface area and pore volume.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2023)
Review
Chemistry, Analytical
Arun Thirumurugan, Ananthakumar Ramadoss, Shanmuga Sundar Dhanabalan, Sathish-Kumar Kamaraj, Natarajan Chidhambaram, Suyambrakasam Gobalakrishnan, Carolina Venegas Abarzua, Yerko Alejandro Reyes Caamano, Rednam Udayabhaskar, Mauricio J. Morel
Summary: MXene is a new emerging material with wider physicochemical characteristics for various applications. The formation of hybrid composites with other materials makes MXene interesting for multifunctional applications. The selection of magnetic nanomaterials for MXene composites is important for utilizing magnetic characteristics.
Article
Materials Science, Multidisciplinary
P. Sowjanya, N. Pavan Kumar, Arout Chelvane, M. V. Ramana Reddy
Summary: This study synthesized cobalt substituted nickel ferrites using sol gel technique and investigated the effects of cobalt substitution on the structure, surface morphology, optical properties, and magnetostrictive behavior of the samples. The results showed that cobalt substitution increased the remanance and coercivity values, decreased the Curie temperature values, and enhanced the magnetostrictive properties.
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Shilpa Taneja, Preeti Thakur, Blaise Ravelo, Atul Thakur
Summary: A composition of rare earth Samarium doped Ni-Zn-Bi nanoferrite with a cubic structure was synthesized using a citrate precursor technique. The prepared samples had a crystallite size in the range of 18-26nm and exhibited agglomeration. The nanoferrites showed high resistivity and complex dielectric constant values, indicating their suitability for high-frequency applications.
MATERIALS RESEARCH BULLETIN
(2022)
Article
Materials Science, Characterization & Testing
Ramazan Durgun, Serkan Abali
Summary: Porcelain tiles are prepared by calcining ceramic powders at different temperatures and sintering them at different temperatures. The study investigates the effects of powder calcination temperature and sintering temperature on the physical properties and structure of the tiles. The results show that a powder calcination temperature of 900 degrees C is critical for achieving low porosity and high strength structures.
Review
Chemistry, Multidisciplinary
Dongqin Yu, Haochen Zhang, Jinsong Ren, Xiaogang Qu
Summary: Hydrogen-bonded organic frameworks (HOFs) are an emerging class of porous materials with significant biocompatibility and chemical functionalities, which distinguish them from other porous materials in the biotechnology and biomedical field. However, the research on HOFs is still in its early stages, with the major challenges being the stability and structural diversity in vivo.
CHEMICAL SOCIETY REVIEWS
(2023)
Review
Chemistry, Multidisciplinary
Dongqin Yu, Haochen Zhang, Jinsong Ren, Xiaogang Qu
Summary: Hydrogen-bonded organic frameworks (HOFs) are highly crystalline porous materials with significant biocompatibility and rich chemical functionalities. They have the potential for application in biotechnology and biomedical fields, but current research is still in the early stages and faces challenges regarding stability and structural diversity under physiological conditions.
CHEMICAL SOCIETY REVIEWS
(2023)
Article
Plant Sciences
Asma Jabeen, Sanjay Chadha, Shabir Hussain Wani, Muhammad Saqlain Zaheer, Hesham F. Alharby, Sameera A. Alghamdi, Hafiz Haider Ali, Yasir Niaz, Abdulrahman Alasmari, Mohamed Sakran
Summary: The lack of research on the development of high quality cabbage hybrids in the public sector using combining ability estimates, gene action and heterosis motivated the study. In 2019, 30 F1 hybrids were created between 15 cytoplasmic male-sterile lines and 2 testers following a line x tester design. The performance and characteristics of the parent lines and F1 hybrids were evaluated in a randomized block design during the 2019-2020 season. The study revealed that certain parental lines and specific cross combinations showed promising results in terms of combining ability and heterosis.
PAKISTAN JOURNAL OF BOTANY
(2023)
Article
Chemistry, Multidisciplinary
Saira Riaz, Muhammad Ikram, Sadia Naz, Anum Shahzadi, Walid Nabgan, Anwar Ul-Hamid, Ali Haider, Junaid Haider, Ali Al-Shanini
Summary: This study demonstrates the incorporation of graphene oxide (GO) into polyacrylic acid (PAA)-doped SnO2 quantum dots (QDs) through a coprecipitation approach. The catalytic and antibacterial properties of GO/PAA-SnO2 QDs were evaluated, and the optical properties, surface morphologies, crystal structures, elemental compositions, and d-spacings of the QDs were examined. The results showed that GO/PAA-SnO2 exhibited improved catalytic efficacy and strong antibacterial activity against Escherichia coli (E. coli), making it a promising catalyst and potential inhibitor of bacterial enzymes.
Article
Chemistry, Multidisciplinary
Syeda Kinza Fatima, Ansumana Sangi Ceesay, Muhammad Saqib Khan, Rizwana Sarwar, Muhammad Bilal, Jalal Uddin, Anwar Ul-Hamid, Ajmal Khan, Nadia Riaz, Ahmed Al-Harrasi
Summary: This study investigated the use of graphene quantum dot (GQD)-incorporated TiO2 nanocomposites for the photocatalytic treatment of reactive yellow 145 (RY145) dye. Results showed that the 15GQD-TiO2 nanocomposite achieved a 99.3% discoloration of RY145 dye in 30 minutes under visible light irradiation. The study also found that GQDs and TiO2 played a vital role in the generation of electrons and holes during the photocatalytic process.
Article
Chemistry, Multidisciplinary
Shair Baz, Muhammad Ikram, Ali Haider, Anum Shahzadi, Anwar Ul-Hamid, Walid Nabgan, Junaid Haider, M. Imran, Thamraa Alshahrani, Francisco Medina, Muhammad Imran
Summary: In this study, vanadium oxide (V2O5) and carbonspheres (Cs)-doped NiO2 nanostructures were synthesized and characterized using various spectroscopic and microscopic techniques. The doped nanostructures exhibited a redshift in absorption and a decreased band gap energy compared to the pristine sample. Transmission electron microscopy revealed nonuniform nanorods with various nanoparticles, and a higher agglomeration was observed upon doping. The V2O5/Cs-doped NiO2 nanostructures showed superior catalytic activity and significant antibacterial efficacy, as well as strong binding affinity with enzymes involved in folate metabolism.
Article
Chemistry, Physical
Ehtisham Umar, Muhammad Ikram, Ali Haider, Anum Shahzadi, Anwar Ul-Hamid
Summary: In this study, the doping-dependent properties of hydrothermally prepared WO3 nanocomposite with barium (Ba) and chitosan (CS) were investigated. Different concentrations of Ba (3%, 6%, and 9%) were added into the CS-WO3 nanocomposite. Ba/CS doping improved the catalytic and antimicrobial activity of WO3 by controlling particle size and overcoming the recombination rate issues. The synthesized nanostructures showed high catalytic activity in degrading MB dye and exhibited antimicrobial activity against E. coli pathogens.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Physical
Md. Hasive Ahmad, Md. Rajbanul Akhond, Md. Jahidul Islam, Mizanur Rahaman, Rabeya Binta Alam, Anwar Ul-hamid, Muhammad Rakibul Islam
Summary: A Co3O4 decorated MoS2 nanoflower (MoS2/Co3O4) was synthesized successfully by a simple hydrothermal method. The effect of Co3O4 on the structural, optical, and electronic properties of MoS2 nanoflowers was investigated experimentally and theoretically. Various characterization techniques were employed to study the surface morphologies, structural properties, chemical constitution, and optical properties of the nanocomposites.
SURFACES AND INTERFACES
(2023)
Article
Chemistry, Multidisciplinary
Atiya Ayub, Muhammad Ikram, Ali Haider, Iram Shahzadi, Anwar Ul-Hamid, Anum Shahzadi, Mohammed M. Algaradah, Ahmed M. Fouda, Walid Nabgan, Muhammad Imran
Summary: The research aims to enhance catalytic and antimicrobial activity by doping Y/Cs into La2O3, reducing charge carrier recombination rates. Various concentrations of Y and a fixed amount of Cs were successfully doped into La2O3 nanostructures using coprecipitation technique. Advanced techniques were utilized to determine the structural properties and antibacterial efficacy of the synthesized ternary catalyst.
Article
Chemistry, Multidisciplinary
Mohsin Shabbir, Muhammad Imran, Ali Haider, Iram Shahzadi, Wakeel Ahmad, Anwar Ul-Hamid, Walid Nabgan, Anum Shahzadi, Ali Al-Shanini, Murefah Mana Al-Anazy, Mohamed Adam, Muhammad Ikram
Summary: The catalytic activity and bactericidal activity of alpha-MoO3 and Sm-g-C3N4-doped alpha-MoO3 composites prepared through coprecipitation were evaluated. The composites showed high crystallinity, and charge transfer between alpha-MoO3 and g-C3N4 resulted in the generation of superoxide and hydroxyl radicals. The catalytic activity against Rhodamine B was highest in basic medium, and the doped sample exhibited strong bactericidal efficacy against Escherichia coli. In silico studies indicated that the generated nanorods may inhibit DNA gyrase and DHPS enzymes.
Article
Chemistry, Multidisciplinary
Muhammad Ikram, Rizwan Karim, Ali Haider, Anum Shahzadi, Mohammed M. Algaradah, Anwar Ul-Hamid, Walid Nabgan, Ahmed M. Fouda, Salamat Ali
Summary: This research presents a novel synthesis of CeO2 nanostructures doped with a fixed amount of capping agent (PAA) and different concentrations of silver (Ag). The Ag/PAA doped CeO2 demonstrated excellent catalytic and antibacterial efficacy. In particular, the 0.03 concentration of Ag/PAA doped CeO2 showed significant catalytic reduction (98.9%) of rhodamine B dye in an acidic medium and exhibited a substantial inhibition zone (3.75 mm) against Escherichia coli.
Article
Chemistry, Multidisciplinary
Muhammad Ikram, Muhammad Shazaib, Ali Haider, Anum Shahzadi, Shair Baz, Mohammed M. Algaradah, Anwar Ul-Hamid, Walid Nabgan, Hisham S. M. Abd-Rabboh, Salamat Ali
Summary: Bi2O3 quantum dots (QDs) doped with different concentrations of graphitic carbon nitride (g-C3N4) and a fixed amount of carbon spheres (CS) were synthesized using a co-precipitation technique. The presence of monoclinic structure of the sample was confirmed by XRD analysis. Various functional groups and characteristic peaks of (Bi-O) were identified by FTIR spectra. The morphology of Bi2O3 QDs showed agglomeration with higher amounts of g-C3N4. Notably, the (6 wt%) g-C3N4/CS-doped Bi2O3 exhibited considerable antimicrobial potential against E. coli.
Article
Engineering, Environmental
Muhammad Ayesha, Muhammad Imran, Ali Haider, Iram Shahzadi, Sawaira Moeen, Anwar Ul-Hamid, Walid Nabgan, Anum Shahzadi, Thamraa Alshahrani, Muhammad Ikram
Summary: This research presents the synthesis of polyvinylpyrrolidone (PVP) and chitosan (CS) coated magnetite (Fe3O4) nanoparticles (NPs) through co-precipitation technique. The objective was to investigate the catalytic and antibacterial efficacy of CS/PVP-Fe3O4 and PVP/CS-Fe3O4 using molecular docking analysis. The findings showed that the coating of PVP and CS reduced the particle size of Fe3O4, increasing catalytic and antibacterial potency.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Tonmoye Sarkar Shathi, Md. Abdur Rahman, Md. Ataur Rahman, Md. Nasiruddin, Md. Abdul Alim Al-Bari, Sagar Pande, Tadahiro Komeda, Md. Anwar Ul-Hamid, Hasan Ahmad, Md. Rabiul Karim
Summary: Functional polymer-coated inorganic composite particles have attracted significant attention for their potential biomedical applications. In this study, carboxyl and amine functionalized PGMA-coated ZnP particles were successfully synthesized, leading to improved stability and surface functionality. The resulting composite particles showed promising drug-delivery capabilities against multi-drug-resistant bacterial infections.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Physical
Maria Mukhtar, Muhammad Mubeen, Anwar Ul-Hamid, Sule Erten Ela, Azhar Iqbal
Summary: Combining halide perovskite NCs with graphene to design heterostructures shows promise for energy applications, optoelectronics, and photocatalysis. Understanding interfacial charge transfer (CT) dynamics is crucial for the optoelectronic applications of perovskite NC-graphene heterostructures. This study investigates the influence of different surface functionalities of graphene on CT dynamics in FAPbBr(3) NCs attached to functionalized graphene heterostructures. Functionalized graphenes, such as graphene oxide (GO) and amino acids (alanine, tyrosine, and cysteine) functionalized GO, were synthesized and their heterostructures with NCs resulted in quenching of the FAPbBr(3) NCs' photoluminescence (PL). The study demonstrates that the rate of CT and charge transfer efficiency strongly depend on the nature of the functionalizing moieties, with cysteine-functionalized graphene showing the highest hole transfer efficiency.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Muhammad Mubeen, Noor ul Ain, Muhammad Adnan Khalid, Maria Mukhtar, Bushra Naz, Zumaira Siddique, Anwar Ul-Hamid, Azhar Iqbal
Summary: In this article, the band gap of ternary ZnCdS quantum dots (QDs) is tuned by changing the concentration of the capping ligand, mercaptoacetic acid (MAA). The functionalization of QDs controls their size and band gap, resulting in a blue shift in the absorption and photoluminescence (PL) spectra. The combination of MAA-functionalized QDs and ensulizole sunscreen exhibits a very high energy transfer efficiency (E) of approximately 70%.
Article
Chemistry, Multidisciplinary
Saira Riaz, Muhammad Ikram, Sadia Naz, Anum Shahzadi, Walid Nabgan, Anwar Ul-Hamid, Ali Haider, Junaid Haider, Ali Al-Shanini
Summary: This study demonstrates the incorporation of different concentrations of graphene oxide (GO) into polyacrylic acid (PAA)-doped SnO2 quantum dots (QDs) and examines their catalytic and antibacterial effects. The QDs' optical properties, surface morphologies, crystal structures, elemental compositions, and d-spacings were analyzed. X-ray diffraction patterns revealed the tetragonal configuration of SnO2 and reduced crystallinity upon dopants. Electronic spectra identified a blue shift and a reduction in band gap energy with GO and PAA incorporation. Fourier transform infrared spectra confirmed the presence of functional groups during the synthesis process. The GO/PAA-SnO2 QDs exhibited enhanced catalytic activity and strong bactericidal efficacy against Escherichia coli (E. coli) at higher GO concentrations. Molecular docking studies predicted their potential as inhibitors of beta-lactamase E. coli and DNA gyrase E. coli.