4.4 Review

Research Progress on Photocatalytic Reduction of Cr(VI) in Polluted Water

Journal

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 94, Issue 4, Pages 1142-1155

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20200317

Keywords

Cr(VI) removal; Photocatalytic reduction; Photocatalyst

Funding

  1. Natural Science Foundation of Jiangxi Province, China [20181BAB216006]
  2. National Natural Science Foundation of China [51672194, 51702241, 51872210]
  3. Program for Innovative Teams of Outstanding Young and Middle-aged Researchers in the Higher Education Institutions of Hubei Province [T201602]
  4. Key Program of Natural Science Foundation of Hubei Province, China [2017CFA004]

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With the rapid industrial growth leading to an increase in wastewater containing hexavalent chromium, the photocatalytic reduction of Cr(VI) has become a method of interest due to its advantages of environmental friendliness, high utilization of solar energy, and low chemical reagent dosage. Various catalysts are being developed to improve the efficiency of Cr(VI) removal during the photocatalytic reduction process.
More and more wastewater containing hexavalent chromium (Cr(VI)), which causes increasingly threatening environmental events including death of plants or organisms, soil inactivation and canceration of human organs, has been caused by rapid industrial growth. Various methods, such as photocatalytic reduction, physical adsorption, electrochemical and photo-electrochemical approaches have been proposed to detoxify/ remove Cr(VI) contained in wastewater. Quite significantly, photocatalytic Cr(VI) reduction grabs increasing attention with many advantages, including environmental friendliness, no sludge, low secondary pollution risk, high utilization of solar energy and low dosage of chemical reagents. For the purpose of improving the Cr(VI) removal efficiency during the photocatalytic reduction process, various kinds of catalysts were developed. In this mini-review, the photocatalytic reduction of Cr(VI) by ion doping photocatalysts, faceted photocatalysts, and heterostructure photocatalysts are briefly introduced. Furthermore, some suggestions for modifying photocatalysts to enhance their photocatalytic performance on Cr(VI) reduction are put forward.

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