Journal
DALTON TRANSACTIONS
Volume 45, Issue 35, Pages 13700-13708Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt00843g
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Funding
- Labex Arcane program [ANR-11-LABX-0003-01]
- ANR program [ANR-13-JS07-0012, ANR-12-BS07-0014-01]
- Agence Nationale de la Recherche (ANR) [ANR-13-JS07-0012] Funding Source: Agence Nationale de la Recherche (ANR)
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A series of dimethyldihydropyrene-appended metal complexes has been synthesized and thoroughly characterized using electrochemical and spectroscopic methods. The ring-opening reaction undergone by the dimethyldihydropyrene core under visible light irradiation proceeds much more efficiently when the metal complexes and the photochromic moiety are connected through a pyridinium-bridge vs a phenyl bridge. The clean electrochemical and photochemical responses of these hybrid systems make them good candidates for the conception of new multi-addressable photo- and redox-switches.
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