Journal
DALTON TRANSACTIONS
Volume 45, Issue 25, Pages 10136-10140Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt02014c
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Funding
- National Natural Science Foundation of China [21271176, 21472196, 21521062, 21501183]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB 12010400]
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In response to the application of low electrochemical potentials, ruthenium-tris(bipyridine) complexes decorated with multiple electron-rich and redox-active amine substituents show reversible absorption and emission spectral changes in the deep-red to NIR region. The number of amine substituents strongly affects the electrochemical and spectroscopic properties and the spin density distributions of the complex in the one-electron-oxidized state.
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