Journal
DALTON TRANSACTIONS
Volume 45, Issue 43, Pages 17123-17131Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt02141g
Keywords
-
Categories
Funding
- Ariel University
Ask authors/readers for more resources
A cationic Pd(II) complex containing syn-(Me,Me)bimane as a ligand was prepared and fully characterized. This complex represents the first well-defined case of a bimane scaffold coordinated to a metal center. The strongly-fluorescent syn-bimane chelates the Pd(II) center via its carbonyl oxygen atoms, affording a non-fluorescent complex. The crystal structure of this complex shows that the coordinated bimane departs from planarity, with its bicyclic framework bent about the N-N bond. Spectroscopic evidence demonstrates that bimane coordination is reversible in solution.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available