4.8 Article

Thermo-Adaptive Block Copolymer Structural Color Electronics

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 31, Issue 11, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202008548

Keywords

block copolymer photonic crystals; flexible structural color electronics; thermal sensing displays; thermal structural color patches; thermo‐ adaptive photonic crystal

Funding

  1. Creative Materials Discovery Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2018M3D1A1058536]
  2. National Research Foundation of Korea (NRF) - Korean government (MEST) [2020R1A2B5B0300269711]
  3. KIST Institutional Program [2Z05900-19-P096]
  4. National Research Council of Science & Technology (NST), Republic of Korea [21A01023] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  5. National Research Foundation of Korea [4199990514159, 2020R1A2B5B03002697] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Utilizing a mixture of thermo-responsive polymer and ionic liquid as materials, flexible electronic devices with variable colors are developed, which can be applied in displays, sensors, and other fields.
Flexible electronics that enable the visualization of thermal energy have significant potential for various applications, such as thermal diagnosis, sensing and imaging, and displays. Thermo-adaptive flexible electronic devices based on thin 1D block copolymer (BCP) photonic crystal (PC) films with self-assembled periodic nanostructures are presented. By employing a thermo-responsive polymer/non-volatile hygroscopic ionic liquid (IL) blend on a BCP film, full visible structural colors (SCs) are developed because of the temperature-dependent expansion and contraction of one BCP domain via IL injection and release, respectively, as a function of temperature. Reversible SC control of the bi-layered BCP/IL polymer blend film from room temperature to 80 degrees C facilitates the development of various thermo-adaptive SC flexible electronic devices including pixel arrays of reflective-mode displays and capacitive sensing display. A flexible diagnostic thermal patch is demonstrated with the bi-layered BCP/IL polymer blend enabling the visualization of local heat sources from the human body to microelectronic circuits.

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