4.8 Article

Biomimetic Soft Polymer Microstructures and Piezoresistive Graphene MEMS Sensors Using Sacrificial Metal 3D Printing

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 1, Pages 1094-1104

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c21295

Keywords

3D printing; additive manufacturing; MEMS; flow sensor; pressure sensor; embedded sensing; graphene; piezoresistivity; bioinspiration; microfluidics

Funding

  1. Materials innovation institute M2i [S16044]
  2. University of Groningen
  3. [ITEA-2018-17030]

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The study introduces a novel processing method for fabricating complex, bioinspired PDMS structures, including two flexible piezoresistive microelectromechanical (MEMS) sensors integrated into an electric shaver. This method involves 3D printing a thin-walled sacrificial metallic mold, soft polymer casting, and acidic etching of the mold, allowing for the creation of intricate structures that are challenging to achieve with current techniques.
Recent advances in 3D printing technology have enabled unprecedented design freedom across an ever-expanding portfolio of materials. However, direct 3D printing of soft polymeric materials such as polydimethylsiloxane (PDMS) is challenging, especially for structural complexities such as high-aspect ratio (>20) structures, 3D microfluidic channels (similar to 150 mu m diameter), and biomimetic microstructures. This work presents a novel processing method entailing 3D printing of a thin-walled sacrificial metallic mold, soft polymer casting, and acidic etching of the mold. The proposed workflow enables the facile fabrication of various complex, bioinspired PDMS structures (e.g., 3D double helical microfluidic channels embedded inside high-aspect ratio pillars) that are difficult or impossible to fabricate using currently available techniques. The microfluidic channels are further infused with conductive graphene nanoplatelet ink to realize two flexible piezoresistive microelectromechanical (MEMS) sensors (a bioinspired flow/tactile sensor and a dome-like force sensor) with embedded sensing elements. The MEMS force sensor is integrated into a Philips 9000 series electric shaver to demonstrate its application in smart consumer products in the future. Aided by current trends in industrialization and miniaturization in metal 3D printing, the proposed workflow shows promise as a low-temperature, scalable, and cleanroom-free technique of fabricating complex, soft polymeric, biomimetic structures, and embedded MEMS sensors.

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