Journal
NANO-MICRO LETTERS
Volume 12, Issue 1, Pages -Publisher
SHANGHAI JIAO TONG UNIV PRESS
DOI: 10.1007/s40820-020-00509-y
Keywords
CsPbI2Br; Inverted perovskite solar cells; Effective passivation; V-oc loss; Stability
Funding
- National Natural Science Foundation of China [61974150, 51773213]
- Zhejiang Provincial Natural Science Foundation of China [LQ19E030008]
- Key Research Program of Frontier Sciences, CAS [QYZDB-SSW-JSC047]
- Zhejiang Province Science and Technology Plan [2018C01047]
- Fundamental Research Funds for the Central Universities
- National Youth Top-notch Talent Support Program
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Developing high-efficiency and stable inverted CsPbI2Br perovskite solar cells is vitally urgent for their unique advantages of removing adverse dopants and compatible process with tandem cells in comparison with the regular. However, relatively low opening circuit voltage (V-oc) and limited moisture stability have lagged their progress far from the regular. Here, we propose an effective surface treatment strategy with high-temperature FABr treatment to address these issues. The induced ions exchange can not only adjust energy level, but also gift effective passivation. Meanwhile, the gradient distribution of FA(+)can accelerate the carriers transport to further suppress bulk recombination. Besides, the Br-rich surface and FA(+)substitution can isolate moisture erosions. As a result, the optimized devices show champion efficiency of 15.92% withV(oc)of 1.223 V. In addition, the tolerance of humidity and operation get significant promotion: maintaining 91.7% efficiency after aged at RH 20% ambient condition for 1300 h and 81.8% via maximum power point tracking at 45 degrees C for 500 h in N-2. Furthermore, the unpackaged devices realize the rare reported air operational stability and, respectively, remain almost efficiency (98.9%) after operated under RH 35% for 600 min and 91.2% under RH 50% for 300 min. Graphic
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