4.3 Review

Novel architectures of boron

Journal

STRUCTURAL CHEMISTRY
Volume 31, Issue 6, Pages 2105-2128

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11224-020-01606-9

Keywords

Boron clusters; Boron fullerenes; Boron sheets; Supertetrahedral boron; Superoctahedral boron

Funding

  1. Ministry of Science and Higher Education of the Russian Federation (Southern Federal University) [08522020-0019]

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The review presents results of the recent studies of non-typical forms of boron derivatives, including flat hexagonal boron, boron fullerenes, supertetrahedral boron, and superoctahedral boron. The approaches to the design of these systems based on combination of stable structural units, as well as methods aimed at compensating the electronic deficit of non-standard boron structures are analyzed.

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