Journal
SCRIPTA MATERIALIA
Volume 186, Issue -, Pages 242-246Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2020.05.033
Keywords
High entropy alloys; Metals and alloys; Microstructure; Solidification; Liquid phase separation; Biomaterials
Categories
Funding
- KAKENHI [18H05254, 18K04750, 19H05172]
- Council for Science, Technology and Innovation (CSTI)
- Cross-Ministerial Strategic Innovation Promotion Program (SIP)
- Innovative Design/Manufacturing Technologies program (Establishment and Validation of the base for 3D Design Additive Manufacturing Standing on the Concepts of Anisotropy Customization) of the New Energy and Industrial Technology Development Organi
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TiZrHfYLa0.2 high-entropy alloys (HEAs) with dual hexagonal-closed-packed (HCP) structures were designed based on the concept of liquid phase separation (LPS) and segregation for enhancing the immiscibility of the constituent elements. The LPS leads to a particular solidification microstructure on the free surface side and Cu-hearth contacted area in the ingots. The dual HCP structures with equi-axis Ti-Zr-Hf dendrite and Y-La-rich interdendrite were observed at most regions of the arc-melted ingots. The mixing enthalpy among the constituent elements and predicted phase diagrams constructed by the Materials Project were effective for the alloy design of the HEAs with dual HCP structures. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd.
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