Article
Physics, Multidisciplinary
Zuyuan Wang, Hojin Kim, Maria Secchi, Maurizio Montagna, Eric M. Furst, Bahram Djafari-Rouhani, George Fytas
Summary: The vibrational eigenmodes of dumbbell-shaped polystyrene nanoparticles were studied using Brillouin light spectroscopy. The experimental spectra were recorded and theoretically calculated. Unlike spherical particles, the eigenmodes of dumbbells exhibit either single or double degeneracy due to their axial symmetry. A new low-frequency peak observed in the BLS spectrum was attributed to the out-of-phase vibration of the two lobes. The quantization of acoustic modes in these molecule-shaped dumbbell particles changes as the separation between the lobes increases.
PHYSICAL REVIEW LETTERS
(2022)
Article
Chemistry, Physical
Rayan Chatterjee, Santidan Biswas, Victor V. Yashin, Michael Aizenberg, Joanna Aizenberg, Anna C. Balazs
Summary: Interpenetrating and random copolymer networks are important for various industrial applications. A theoretical model has been developed for the controlled growth of these networks, allowing for customization of their swelling and elastic properties through adjustments in monomer and crosslinker concentrations or chemical choices. This process can produce gels with a range of mechanical properties to meet the materials requirements of different applications.
Article
Polymer Science
Feng Li, Harm-Anton Klok
Summary: Polyhomologation of ylide monomers by organoboron initiators is a powerful C1 polymerization method that provides access to linear polyolefins. Oxidative hydrolysis of polyolefins gives hydroxyl chain end functional polymers, enabling further functionalization and exploration of new polymer architectures.
EUROPEAN POLYMER JOURNAL
(2022)
Article
Polymer Science
Davey C. Hoekstra, Michael G. Debije, Albert P. H. J. Schenning
Summary: This study reports the formation of triple-shape-memory liquid crystalline-interpenetrating polymer network (LC-IPN) actuators based on a hybrid acrylate-oxetane LC mixture. Polymer films with two distinct glass-transition temperatures are created through the orthogonal polymerization of oxetane and acrylate liquid crystals, allowing for one-way triple-shape-memory actuation and two-way bending actuation with a broad temperature window. The results demonstrate the combination of shape memory polymers with liquid crystal-based soft actuators, showcasing advanced stimuli-responsive properties.
Article
Chemistry, Multidisciplinary
Valentin A. Bobrin, Sung-Po Chen, Carlos Fitzgerald Grandes Reyes, Bing Sun, Chun Ki Ng, Youry Kim, Damian Purcell, Zhongfan Jia, Wenyi Gu, Jason W. Armstrong, Julie McAuley, Michael J. Monteiro
Summary: The water-borne spray-on coating is reported to completely inactivate viral particles and degrade their RNA, targeting a wide range of viruses including SARS-CoV-2 and its variants, influenza A, and others. The nanoworm technology presents a powerful control measure for viral inactivation and is environmentally friendly, with the potential for broad application in future pandemics.
Article
Materials Science, Multidisciplinary
Kseniia N. Bardakova, Bato Ch. Kholkhoev, Ivan A. Farion, Evgenii O. Epifanov, Olga S. Korkunova, Yuri M. Efremov, Nikita V. Minaev, Anna B. Solovieva, Peter S. Timashev, Vitaliy F. Burdukovskii
Summary: This study introduces new photosensitive compositions based on aromatic heterochain polymers for DLP printing, with thermal post-curing and supercritical carbon dioxide post-processing to enhance mechanical properties and thermal stability. The research shows that thermal post-treatment significantly increases the tensile strength of the materials, leading to a potential use in aerospace, robotics, and sensorics.
ADVANCED MATERIALS TECHNOLOGIES
(2022)
Article
Green & Sustainable Science & Technology
Muhammad Ahmad Mudassir, Shazia Kousar, Muhammad Ehsan, Muhammad Usama, Umer Sattar, Muhammad Aleem, Irum Naheed, Osama Bin Saeed, Mehmood Ahmad, Hafiz Favad Akbar, Muhammad Aizaz Ud Din, Tariq Mahmood Ansari, Haifei Zhang, Irshad Hussain
Summary: Porous carbons are highly sought-after materials for energy and environmental applications, but most preparation methods result in blocked pores. Emulsion-based approaches have shown promise in creating hierarchically-organized porous carbon materials with large pores and multidimensional transport pathways, opening up possibilities for a wide range of applications.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Chemistry, Multidisciplinary
Yuhan Jiang, Masato Kibune, Masatoshi Tosaka, Shigeru Yamago
Summary: The practical synthesis of structurally controlled hyperbranched polymers (HBPs) by organotellurium-mediated radical polymerization (TERP) in water under emulsion conditions is reported. The method allows for the controlled synthesis of HBPs with diverse branch structures and tunable polymer properties by changing the monomers used.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Materials Science, Multidisciplinary
Sheng Jie Yuan, Zhong Quan Peng, Min Zhi Rong, Ming Qiu Zhang
Summary: Interlocked networks fabricated from liquid crystalline epoxy and amorphous polyurethane were used to prepare oriented crosslinked liquid crystalline polymers (LCPs), resulting in improved strength in orthogonal directions and retained self-healing capability. This method is of great significance for the practical applications of crosslinked LCPs in modern microelectronics and communication technology.
APPLIED MATERIALS TODAY
(2022)
Article
Chemistry, Inorganic & Nuclear
Deepika Rani, Kuldeep Kumar Bhasin, Monika Singh
Summary: This study reported the first non-porous MOF material with an interpenetrating ladder structure for iodide sensing, exhibiting a unique double nucleophilic substitution reaction mechanism. The supramolecular structure of Co-bpe MOF was stabilized by strong hydrogen bonding. The material showed a significant color change in the presence of iodide, with a detection limit of 2.7 x 10(-7) M.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Physical
Seo Won Song, Hongdeok Kim, Seoyoon Shin, Seongjin Jang, Jong Hyuk Bae, Changhyun Pang, Joonmyung Choi, Ki Ro Yoon
Summary: Flexible zinc-air batteries with gel polymer electrolyte (GPE) are considered promising for next-generation wearable devices due to their high energy density, low cost, safety, and environmental friendliness. However, the evaporation of liquid component in GPE significantly reduces battery performance and lifespan. To address this issue, a hierarchically porous PVA/PAA hybrid GPE is developed, which improves electrolyte uptake and retention properties, and enhances ionic conductivity. The hybrid GPE demonstrated excellent cycling stability, rate characteristics, and power output in zinc-air batteries, showing their feasibility for powering wearable smart watches.
ENERGY STORAGE MATERIALS
(2023)
Article
Polymer Science
Jin Qu, Xinru Ma, Guohao Miao, Yu Yang, Junping Zheng, Xiaofei Liu
Summary: This study investigates the structure and oil displacement performance of the oil-based supramolecular system based on polyacrylamide, and further discusses its oil displacement mechanism. The results show that the viscosity of the system increases significantly, improving the mobility ratio and swept volume. The ability of the system to remove crude oil from surfaces is enhanced, and the mathematical relationships are discussed. The oil displacement efficiency of the system in different dispersion media is explored using nonhomogeneous multistage bifurcation microchannels, supporting its practical application in oil fields.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Yukari Sakurayama, Tsunenobu Onodera, Yasuyuki Araki, Takehiko Wada, Hidetoshi Oikawa
Summary: Porous zirconia medium (PZrM) has been successfully fabricated using polystyrene microparticles (MPs) as templates, with rhodamine B (RhB) loaded inside as an optical amplifying medium. Experimental determination of lasing thresholds (I-th) revealed a close relationship with pore sizes and added amount of PZrM powder, providing insights into the superior random laser oscillation properties of PZrM as a porous scatterer over Zr MPs.
Article
Polymer Science
Chi Zhang, Ke Jiang, Yong Zhang, Jirong Wang, Zhigang Xue
Summary: This article presents a facile method for the fabrication of a double network polymer electrolyte (DN-PE) with improved mechanical strength and interfacial compatibility for lithium-ion batteries. The DN-PE is formed in situ through a lithium salt-accelerated thiol-Michael addition and lithium salt-catalyzed radical polymerization. The DN-PE exhibits stable cycling performance and high discharge specific capacity in lithium-based cells.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Yawei Wang, Yang Zeng, Jinbin Zhu, Chao Yang, Huanan Huang, Xiudong Chen, Ruirui Wang, Ping Yan, Shunhang Wei, Mingxian Liu, Dazhang Zhu
Summary: In this study, dual-aerogels with semi-interpenetrating polymer network structure were prepared and used as precursors for hierarchical porous carbons. Polyvinyl alcohol served as the template for macropores and provided three-dimensional structure, while KOH increased the formation of micropores and mesopores, resulting in a larger specific surface area. By controlling the mass ratio of resorcinol to PVA, the pore structure and surface area can be tailored to optimize the electrochemical performance.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Materials Science, Paper & Wood
Tao Zhang, Yan Zhao, Michael S. Silverstein
Article
Chemistry, Multidisciplinary
Michael S. Silverstein
ISRAEL JOURNAL OF CHEMISTRY
(2020)
Article
Polymer Science
Rotem Horowitz, Melissa Lamson, Orit Cohen, Travis B. Fu, Julia Cuthbert, Krzysztof Matyjaszewski, Michael S. Silverstein
Summary: PolyHIPEs are macroporous polymers synthesized within high internal phase emulsions, stabilized using stars and crosslinked with polyhedral silsesquioxane (POSS) to produce shape memory polymer foams.
Article
Polymer Science
Aurelie Ohana Benaddi, Orit Cohen, Krzysztof Matyjaszewski, Michael S. Silverstein
Summary: PolyHIPEs are porous polymers synthesized within high internal phase emulsions, with their properties being influenced by polymerization mechanism, initiator solubility, RAFT agent to initiator ratio, and crosslinking comonomer content. The use of surface-active RAFT agent can significantly enhance the structure of PolyHIPE. Substituting RAFT for FRP can lead to significant changes in thermal, mechanical, and uptake behaviors.
Editorial Material
Polymer Science
Michael S. Silverstein
Article
Polymer Science
Adi Horowitz, Gil Shaul, Michael S. Silverstein
Summary: This paper describes the generation of carbonaceous monoliths with hierarchically porous structures and nitrogen functionalities using a combination of hydrogel synthesis and hydrothermal carbonization. Different activation methods lead to variations in specific surface area and residual mass, while nitrogen-rich monomers result in different N/C ratios in the carbon monoliths. The hierarchically porous structures and chemical structures of these monoliths can be fine-tuned by modifying the composition and processing conditions of the high internal phase emulsions (HIPEs).
POLYMER INTERNATIONAL
(2021)
Article
Materials Science, Multidisciplinary
Inna Berezovska, Katya Kapilov, Prachi Dhavalikar, Elizabeth Cosgriff-Hernandez, Michael S. Silverstein
Summary: PolyHIPEs are highly porous polymers synthesized within high internal phase emulsions, while Pickering HIPEs are an alternative stabilization strategy using solid nanoparticles. The successful design of an HIPE stabilization system based on a combination of nanoparticles and reactive surfactants generates the desired surface functionality and low leachable content.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2021)
Article
Polymer Science
Inna Berezovska, Rajashekharayya A. Sanguramath, Michael S. Silverstein
Summary: Low-density macroporous monoliths based on unmodified beta-cyclodextrin were synthesized using emulsion templating, with high beta-CD contents (up to 63 wt%) and BPA adsorption capacities up to 117.7 mg g(-1).
JOURNAL OF POLYMER SCIENCE
(2022)
Article
Polymer Science
Sima Israel, Michal Levin, Sapir Oliel, Dahiana Mayer, Idan Lerner, Michael S. Silverstein
Summary: Hierarchically porous polymers were generated by combining emulsion-templated macroporous polymers with simultaneous Friedel-Crafts hyper-cross-linking and porogen removal. Different structures of polymer networks were synthesized to control the micro/meso-porosity and thermal stability of the materials.
Article
Polymer Science
Natalie Rosen, Hila Toledo, Michael S. Silverstein
Summary: PolyHIPEs encapsulated calcium chloride hexahydrate (CCHH) within elastomeric, emulsion-templated polymers, demonstrating the successful encapsulation of molten salt hydrates. The addition of a nucleating agent reduced supercooling and modifying the external phase enhanced HIPE stability. The resulting system showed high encapsulation efficiency, low supercooling, and negligible phase transformation.
Article
Materials Science, Multidisciplinary
Orit Cohen, Kristina Vetlitsyna-Novikova, Hila Toledo, Michael S. S. Silverstein
Summary: PolyHIPEs with high internal phase emulsion (HIPEs) templates were synthesized using PIM-like linear polymers. The addition of cross-linking comonomer resulted in monoliths with low density and highly interconnected structures. These polyHIPEs showed high adsorption capacity for cationic dyes.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Rachele Castaldo, Inna Berezovska, Michael S. Silverstein, Gennaro Gentile
Summary: PolyHIPEs templated with HCLRs exhibit advanced sorbent systems due to the synergistic combination of the adsorption capabilities of micro/mesoporous HCLRs and the absorption capacities of polyHIPEs. The amino-functionalized HCLRs significantly enhance the specific surface areas and sorption capacities of polyHIPEs for polar VOCs and CO2. The addition of HCLRs does not negatively affect the high uptake of organic solvents by polyHIPEs, and regenerability above 99% is achieved in five sorption cycles.
ACS APPLIED POLYMER MATERIALS
(2023)
Article
Materials Science, Biomaterials
Prachi Dhavalikar, Dana Jenkins, Natalie Rosen, Aparajith Kannapiran, Karim Salhadar, Orren Shachaf, Michael Silverstein, Elizabeth Cosgriff-Hernandez
Summary: This study explored the use of hydroxyapatite nanoparticles as an alternative stabilizer for emulsion-templated foams used as injectable bone grafts. It was found that a co-stabilization approach with both surfactant and nanoparticles can achieve large, interconnected pores and improved cell attachment. The concentration of hydroxyapatite nanoparticles and surfactant in the scaffolds affects the microarchitecture and cell behavior.
JOURNAL OF MATERIALS CHEMISTRY B
(2023)
Article
Polymer Science
Katya Kapilov-Buchman, Tslil Bialystocki, Danna Niezni, Luba Perry, Shulamit Levenberg, Michael S. Silverstein
Summary: PolyHIPEs are macroporous polymers templated within high internal phase emulsions (HIPEs), synthesized through urethane reactions between diisocyanates and oligomeric polyols in water-in-oil (w/o) HIPEs. The thermal transitions and mechanical properties of PolyHIPEs can be fine-tuned by adjusting the polyol macromolecular structure and molecular weight, as well as the urea content. The degradation of PolyHIPEs in 3 m NaOH demonstrated that PCL-based PUUs degrade more rapidly, and cells grown in PolyHIPEs adhered to walls, spread, and penetrated into porous structures.
Article
Polymer Science
Yuanzhang Jiang, Xuyi Wang, Yanting Han, Dakai Gong, Yingchun Gu, Lin Tan
Summary: In this study, FeCl3 and poly(acrylic acid) (PAA) were doped into waterborne polyurethanes (WPUs) to create multifunctional materials with self-healing and antimicrobial properties. WPU/Fe/PAA-5.5, containing 5.5 wt % PAA, exhibited excellent mechanical properties, strong self-healing capabilities, and an impressive antimicrobial rate of over 90%. These supramolecular films were also highly recyclable through hot-pressing.
Article
Polymer Science
Longyu Tian, Min Wang, Guangming Liao, Baoliang Liu, Sujuan Zhang, Yucheng Sun, Zhen Meng, Jintao Zhang, Zaijun Lu
Summary: Two kinds of benzoxazine monomers were synthesized and used to prepare polybenzoxazine anion exchange membranes (AEMs) with quaternary ammonium functionalization. The LQPBZ AEM exhibited better ion conductivity and alkaline stability.
Article
Polymer Science
Claire A. Lemarchand
Summary: This study investigates the shock behavior of three different polymers through molecular dynamics simulations. The results reveal specificities in the shock behavior of polymers, including deviations from the linear relation between shock velocity and particle velocity, as well as differences in shear stress relaxation behind the shock front. It is found that the deviation of the Hugoniot locus is related to the change in the relative contribution of bonding and non-bonding potential energies, while polymers with higher glass transition temperatures exhibit slower shear stress relaxation.
Article
Polymer Science
Zengquan Liu, Xiaochun Yin, He Zhang, Shuo Gao, Qinglin Kuang, Yanhong Feng
Summary: A powder solid-state extension (PSSE) technology was proposed to address the high melt viscosity issue of UHMWPE. By uniaxial extension and sintering in the solid state, a highly self-reinforced material was prepared. X-ray diffraction and scattering techniques were used to study the structural evolution during the PSSE process, and a solid-phase induced transformation model was established.
Article
Polymer Science
Zhike Li, Anyu Luo, Rui Zhou, Xin Li, Haiyan Li
Summary: A novel high temperature resistance IL@SiO2 nanocapsules were successfully prepared and their friction and wear properties in PA6 composites were studied. The addition of IL@SiO2 nanocapsules reduced the friction coefficient and wear rate without affecting the mechanical properties of PA6. The synergy between the IL core and SiO2 wall in the nanocapsules improved the self-lubricating performance of the PA6 composites.
Article
Polymer Science
Xin Liu, Xuhong Guo, Qi Liao
Summary: In this study, an algorithm for accurately estimating viscosity is developed using molecular dynamics simulations and the Green-Kubo formula. This algorithm can be applied to complex systems with long correlations, such as macromolecular and biological simulation systems.
Article
Polymer Science
Hao Pu, Yun-Lei Hou, Jing -Zhou Chen, Dong -Lin Zhao
Summary: The use of modified graphene improves the interfacial adherence of carbon fibers to epoxy resin, resulting in enhanced interfacial and bending properties of CF and matrix in CF/EP composites, as well as increased interlaminar shear strength and flexural strength.
Article
Polymer Science
Wei-Chung Ke, Jin-Wei Lin, Manohar Reddy Busireddy, Yueh-Hsing Lee, Jiun-Tai Chen, Chain-Shu Hsu
Summary: This study introduces a crosslinkable monomer, TAIC, to synthesize three crosslinked polyimide films, which exhibit improved thermal, mechanical, and dielectric properties. The introduction of TAIC enhances the tensile strength, reduces the dielectric constant and dielectric loss, and decreases the coefficient of thermal expansion of the polyimide films.
Article
Polymer Science
Alex Kwasi Kumi, Ruiling Fan, Ye Chen, Yumei Zhang
Summary: The difference in leaching of amylopectin from cellulose/amylopectin/1-butyl-3-methylimidazolium chloride ([Bmim][Cl]) blends during regeneration in water and aqueous ethanol has been studied. Molecular dynamics simulations showed that the dissolution and regeneration mechanisms of amylopectin in [Bmim][Cl] are similar to cellulose in ionic liquids. Water regeneration leads to weak electrostatic interactions, resulting in high leaching of amylopectin. In contrast, ethanol-water interactions enhance electrostatic interactions among amylopectin chains, limiting amylopectin leaching in aqueous ethanol.
Article
Polymer Science
Xi Zeng, Junwei Zhou, Junbiao Peng, Chunsheng Zhang, Danling Wang, Yihu Song, Qiang Zheng
Summary: This study utilizes an oligomer deep eutectic solvent (DES) based on polyethylene glycol to regulate the vulcanization kinetics of rubber. The results show that the DES can accelerate vulcanization at low temperatures without affecting the crosslinking density and Mullins effect.
Article
Polymer Science
Qianqian Yue, Yongfei Peng, Xingjian Liu, Aihua He, Huarong Nie
Summary: The addition of metal deactivators can effectively suppress the aging of TBIR, prolong its lifespan, and have no negative effects on its physical and processing properties. These research findings are of great importance for improving the stability and aging resistance of polymers.
Article
Polymer Science
J. Gomez-Caturla, J. Ivorra-Martinez, R. Tejada-Oliveros, V Moreno, D. Garcia-Garcia, R. Balart
Summary: This work focuses on the development of environmentally friendly PLA formulations by using different esters derived from geraniol as plasticizers. The results show that these esters have good compatibility with PLA, and they can effectively enhance the elongation and plasticity of PLA, reduce its glass transition temperature, and slightly improve its water absorption capabilities.
Article
Polymer Science
Dandan Li, Zhaohui Lu, Zhao Ke, Ke Xu, Fengna Dai, Youhai Yu, Guangtao Qian, Chunhai Chen
Summary: In this study, cross-linked PI aerogel membranes with low dielectric constant and high moisture resistance were prepared by co-polymerization and scraping coating technology. The incorporation of fluorinated blocks and benzimidazole ring structures resulted in novel PI aerogel membranes with fascinating dielectric properties and outstanding moisture resistance.
Article
Polymer Science
Zhaoyang Chu, Qing Zhang, Haihua Luo, Han Zhou, Fapei Zhang, Wei Chen, Wenhua Zhang
Summary: Multi-physical fields solution processing strategy is a universal and facile method for preparing various conjugated polymer films and high-performance devices. In this study, we employed a combined microfluidic flow and ultrasonication strategy (FU) for processing CP solutions, and found a pronounced synergetic effect in promoting the pre-ordering of chains in solution. The conformation order and anisotropy of the solution were revealed through various characterizations. A non-classical nucleation model for polymer crystallization in non-equilibrium solution processing was confirmed. The roles of microfluidic flow and ultrasonication in chain aggregation and crystallization were addressed through multi-physical simulations. Compared to pristine solutions, the FU strategy showed improved solution anisotropy and crystallization kinetics, resulting in higher crystallinity in films and increased mobilities in OFET devices. The FU processing strategy provides a universal approach for regulating chain conformation and aggregation in conjugated polymer solutions.