Journal
ORGANIC LETTERS
Volume 22, Issue 20, Pages 7920-7925Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02850
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Funding
- University of Toronto
- Natural Science and Engineering Research Council (NSERC)
- Kennarshore, Inc.
- NSERC
- Province of Ontario (OGS)
- Walter C. Summer Memorial Fellowship
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An ortho-amination, ipso-C-H arylation mediated by palladium/norbornene cooperative catalysis is reported. This reaction proceeds through a sequential intermolecular C-N bond formation process followed by intramolecular C-H activation of a tethered arene. The products, aminated phenanthridinones, were generated in moderate to good yields. This method is also applicable to the formation of dibenzazepinones.
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