Article
Materials Science, Multidisciplinary
Ruinan Li, Liu Wang, Yapeng Tian, Yunfeng Chao, Xinwei Cui, Qun Xu
Summary: A novel graphene oxide (GO)-assisted strategy is proposed for the synthesis of mesoporous VO2/G nanobelts with abundant oxygen defects, enabling high-performance Zn2+ storage. Oxygen vacancies and mesopores facilitate the insertion/extraction process of Zn2+. After in-situ electrochemical activation, monoclinic VO2 transforms into layered V2O5•nH(2)O, delivering an extremely high reversible capacity of 731 mAh/g (0.1 A/g). Additionally, superior high-rate and cycling performances are achieved.
Article
Chemistry, Physical
Guangxu Yang, Shuhua Yang, Jian Shen, Yanwei Cui, Jinfeng Sun, Guangbin Duan, Bingqiang Cao, Zongming Liu
Summary: Due to its high safety and low cost, aqueous Zn-ion batteries (AZIBs) have become one of the most promising energy storage devices. In this study, a stable cathode with fast kinetics and high-energy density, KOH-induced oxygen-deficient VO2 (K-VO2), was developed. The K-VO2 cathode achieved improved kinetics and enhanced Zn-ion storage capability through unique morphology, abundant active sites, and oxygen vacancy. The optimized K-VO2-3:4 demonstrated excellent electrochemical performance, indicating the potential of the KOH activation strategy for developing high-energy and stable cathodes.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Daorui Wang, Hongyang Li, Chaojie Li, Weilong Qiu, Wenjuan Wang, Gaoran Li, Yan Zhao
Summary: A new type of oxygen-deficient cobalt oxide nanospheres with a highly ordered structure has been developed as superior anode materials for lithium-ion batteries. The unique structure and oxygen vacancies promote electron/ion conduction and provide rich active sites for conversion reactions. Experimental results demonstrate that the electrode made of this material exhibits excellent reversible capacity and cycling performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Engineering, Environmental
Juan Ding, Yudai Huang, Zhenjie Liu, Xingchao Wang, Yue Zhang, Yong Guo, Rui Sheng, Dianzeng Jia, Xincun Tang, Lei Wang
Summary: Fe2Mo3O8 composites with adjusted molar ratio were synthesized for lithium storage and exhibited pseudocapacitive behavior. The unique characteristics significantly enhance Li+ ion diffusion kinetics and improve pseudocapacitance contribution, resulting in high energy/power density and long cycle stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Wanxing Zhang, Pengcheng Mao, Yuhang Jin, Hai Ming, Zhipeng Li, Danfeng He, Hongyu Sun, Yanlong Yu, Yanguo Liu
Summary: In this study, Nb2O5 anodes were modified using a NaBH4-assisted chemical reduction method. The oxygen vacancy amount in the Nb2O5 materials was controlled by changing the NaBH4 concentration. The optimized sample exhibited improved reversible capacity at high current density, attributed to the combination of oxygen vacancies, nanoscale phase interfaces, and micro/nanoscale three-dimensional assembly.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Wangqiong Xu, Yonghui Zheng, Lina Lin, Weibin Lei, Zhenguo Wang, Haili Song, Yan Cheng, Ruijuan Qi, Hui Peng, Hechun Lin, Zhenzhong Yang, Rong Huang
Summary: The study investigates the evolution of surface orientations and oxygen vacancies in LiMn2O4 cathode materials using Cs-STEM technique. LiMn2O4 crystals with dominated {111} and {110} planes and an appropriate amount of oxygen vacancies exhibit superior cycling performance and rate performance, indicating a synergistic effect of surface orientation and oxygen vacancies on enhanced electrochemical performance.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Physical
Cong Chen, Hangtian Zhu, Minjie Shi, Lingtong Hu, Zhengqing Xue, Hui Ye, Liping Zhao, Chao Yan
Summary: In this study, a novel W18O49 anode with rich oxygen vacancies (W18O49-Ov) is proposed for rechargeable aqueous aluminum-ion batteries (RAABs). The oxygen vacancies are found to play an important role in modulating electronic state and bandgap, as well as providing active sites for Al3+ diffusion. Additionally, a 3D robust architecture of W18O49-Ov anode is constructed, leading to high performance of RAABs.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Analytical
Yong Wang, Liyun Cao, Jianfeng Huang, Fangmin Wang, Lingjiang Kou, Ying Su
Summary: Enhancing the electrochemical reaction kinetics is crucial for achieving high-performance anodes in lithium-ion batteries. In this study, vanadium-doped Cu2O microspheres (V-Cu2O) were synthesized on Cu foam through a facile hydrothermal method and heat treatment. The doping of vanadium induced the formation of radially oriented nanostructures and abundant oxygen vacancies in Cu2O. The V-Cu2O anode exhibited a reversible capacity of 1173 mAh/g after 100 cycles at a current density of 100 mA g-1, which can be attributed to the synergistic effect of fast kinetics from oxygen vacancies and additional capacity from vanadium ions. This work proposes a promising and effective strategy to enhance the Li-storage performance of anode materials.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Jianguang Xu, Hongyan Hang, Chen Chen, Boman Li, Jiale Zhu, Wei Yao
Summary: Research has shown that oxygen-deficient Ti2SC with abundant oxygen vacancies prepared by a surface engineering method can exhibit high capacity and excellent rate performance as a lithium storage anode. This study provides a strategy to optimize the surface structure of MAX phases for enhanced lithium-ion uptake in lithium-ion batteries or capacitors.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Physical
Jing Shi, Xiaodong Tian, Huixiang Wang, Lin Ge, Junfen Li, Baoliang Lv
Summary: Cation-doping and oxygen vacancy engineering were used to enhance the conductivity and cycling performance of metal oxide. Cu-doped WO3 with oxygen vacancies were prepared via a hydrothermal method. The morphology and electrochemical performance were affected by the Cu/W molar ratio. The sea urchin-like structure WCu0.3 showed high rate capability, large surface area, and superior cycling durability. The Cu-doping induced oxygen vacancies contributed to enhanced conductivity. WCu0.3 exhibited impressive 1st discharge capacity, good rate capability, and cycle performance.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Mengcheng Wu, Jie Bai, Mengda Xue, Xun Zhao, Lei Mao, Lingyun Chen
Summary: In this study, a facile hydrothermal method is used to synthesize an oxygen vacancy enriched sodium-ion intercalation material with large interlayer spacing, fast reaction kinetics, and stable structure for superior zinc-ion batteries. The assembled battery shows high specific capacity and excellent structural stability without capacity decay over 2000 cycles. Furthermore, the multiple ion co-intercalation mechanism and partial phase transition mechanism are elucidated using ex situ characterization techniques.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Anni Wang, Wanwan Hong, Lin Li, Ruiting Guo, Yinger Xiang, Yu Ye, Wentao Deng, Guoqiang Zou, Hongshuai Hou, Xiaobo Ji
Summary: Bismuth selenide with regulated atomic ratio of BixSey has been successfully developed as a high-performance anode material. The in-situ XRD technique reveals the reaction mechanism and the formation of robust inter-facial C-Se bonds. The Bi3Se4-based electrode shows exceptional performance with ultralong cycle life and fast lithium storage capability.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Hui Yang, Muhammad Abdullah, Joeseph Bright, Weiguo Hu, Kevin Kittilstved, Yaobin Xu, Chongmin Wang, Xiangwu Zhang, Nianqiang Wu
Summary: Hydrogen treatment of LLTO nanofibers improved ion conductivity and chemical interaction in the composite electrolyte, leading to stable battery performance at room temperature.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Shan Wang, Shijie Jiang, Yunjiao Li, Zhouliang Tan, Shuaipeng Hao, Jiachao Yang, Zhengjiang He
Summary: To overcome the challenges with LiMn2O4, a simple and effective strategy of incorporating WO2.72 into LMO has been proposed. The addition of WO2.72 induces the formation of oxygen vacancies, improves the adsorption and storage of active oxygen, and reduces the energy barrier for lithium ion migration. The formation of a Li2WO4 coating helps improve the electrode-electrolyte interface. The optimized W4000 sample demonstrates superior cycle performance compared to bare LMO.
JOURNAL OF POWER SOURCES
(2023)
Article
Nanoscience & Nanotechnology
Zhenjie Liu, Yudai Huang, Yanjun Cai, Xingchao Wang, Yue Zhang, Yong Guo, Juan Ding, Wenhua Cheng
Summary: A two-dimensional LTO nanosheet with ultrafast charge storage oxygen vacancy was successfully fabricated to enhance Li+ ion mobility for high-rate lithium storage. Doping Al3+ into octahedron Li+/Ti4+ 16d sites not only provides stability to the Ti-O framework, but also lowers the energy barrier for Li+ ion diffusion, ultimately leading to excellent electrochemical performance.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Applied
Buchang Shi, Jennifer Naumovitz, Mingsheng Luo
Summary: Fischer-Tropsch synthesis with ruthenium catalyst showed an inverse isotope effect and deuterium enrichment in hydrocarbons. The results are similar to cobalt and iron catalyzed Fischer-Tropsch reactions. The alkylidene mechanism was proposed to explain these findings and mathematic equations were developed to calculate deuterium enrichment.
Article
Chemistry, Physical
Iltaf Khan, Mingsheng Luo, Lin Guo, Shoaib Khan, Sayyar Ali Shah, Imran Khan, Aftab Khan, Chunjuan Wang, Bohan Ai, Saeed Zaman
Summary: Phosphate bridged p-type LaFeO3 nanosheets and n-type g-C(3)N(4 ) nanosheets Z-scheme nanocomposites were successfully designed, showing superior performance compared to nanoparticles. The fabrication of g-C3N4 nanosheets enhanced charge separation and surface area of LaFeO3 nanosheets.
APPLIED CATALYSIS A-GENERAL
(2022)
Article
Energy & Fuels
Zhijun Zhao, Jubao Gao, Mingsheng Luo, Xinyue Liu, Yongsheng Zhao, Weiyang Fei
Summary: Ionic liquids have been developed as an ideal decarbonization solvent, but their low CO2 capacity and high viscosity limit industrial applications. This study synthesized three novel functional ILs, with one showing the highest CO2 solubility and lowest viscosity. Quantum chemistry simulations confirmed the CO2 absorption mechanism and interaction energy, in agreement with experimental results.
Article
Chemistry, Physical
Qinglong Liu, Qiuna Zhao, Mingsheng Luo, Zhi Yang, Fengli Wang, Hong Li
Summary: Catalytic oxidation of toluene-bearing VOCs can be effectively achieved using Co-grafted dendritic mesoporous silica nanospheres. The catalysts exhibit superior micro-structure, high dispersion of CoOx species, and proper metal-support interaction. The presence of moisture negatively affects the catalytic activity but this effect is reversible. Introducing Pd into the catalysts significantly enhances the catalytic performance by influencing the oxygen activation and toluene adsorption synergistic effect.
MOLECULAR CATALYSIS
(2022)
Article
Chemistry, Applied
Mingsheng Luo, Chenmeng Li, Qinglong Liu, Zhi Yang, Yatao Wang, Hongjuan Li
Summary: This study investigates the influence of carbon and molybdenum precursor, calcination temperature, and the molar ratio of the carbon precursor to molybdenum precursor compounds on the microstructures and catalytic performance of beta-Mo2C/gamma-Al2O3 catalyst for direct hydrogenation of CO to alcohols. The results show that the loading of Mo affects the particle size of beta-Mo2C, CO dissociation adsorption capacity, CO conversion, and selectivity of higher alcohols.
Article
Chemistry, Physical
Mingsheng Luo, Tong Qin, Qinglong Liu, Zhi Yang, Fengli Wang, Hong Li
Summary: A series of Fe-modified CeO2 catalysts with different morphologies were synthesized and used for the direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol. The Fe-modified CeO2 nanorod showed a remarkable improvement in DMC formation. The presence of Fe modification resulted in increased DMC yield, and the synergy between moderate acid-base sites, specific surface area, and surface composition played a crucial role in achieving high reactivity.
Article
Environmental Sciences
Iltaf Khan, Mingsheng Luo, Sohail Khan, Humaira Asghar, Muhammad Saeed, Shoaib Khan, Aftab Khan, Muhammad Humayun, Lin Guo, Buchang Shi
Summary: Recently, green synthesis routes of nanomaterials have gained significant attention for their potential in addressing sustainability concerns. In this research, g-C3N4 nanosheets based nanocomposites were synthesized using Eriobotrya japonica as a mediator and stabilizer agent. The resulting nanocomposites exhibited abundant organic functional groups, activated surface, and strong adsorption capability, making them highly favorable for CO2 conversion and bisphenol A degradation. The coupling of LaFeO3 nanosheets enlarged the surface area and enhanced charge separation, while the insertion of SrO bridge facilitated electron transportation and photo-electron modulation. The final resulting sample showed significantly improved activities for CO2 conversion and bisphenol A degradation compared to pristine green g-C3N4 nanosheets.
ENVIRONMENTAL RESEARCH
(2022)
Article
Engineering, Chemical
Aimei Wang, Mingsheng Luo, Baozhong Lu, Yongji Song, Zhi Yang, Min Li, Buchang Shi, Iltaf Khan
Summary: In this study, a bimetallic MOF was synthesized and a bimetallic catalyst was prepared for Fischer-Tropsch synthesis. The combination of different metals and a MOF-derived porous carbon provides a unique active surface structure that can enhance catalytic performance. The relationship between catalytic performance and catalyst composition was thoroughly investigated.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Electrochemistry
Huanqiao Song, Shixin Zhang, Jialing Ma, Mingsheng Luo
Summary: In this study, graphene supported PtIr nanoparticles were synthesized and demonstrated higher catalytic activity and stability in ethanol electrooxidation. The enhanced performance is attributed to the promotion of C-C bond cleavage and weakened adsorption of Pt to intermediate species by PtIr alloy, improved tolerance of Pt to CO-like species and enhanced structural stability of Pt by IrO2, as well as the synergistic improvement of catalytic ethanol oxidation stability by PtIr alloy and IrO2 in adjacent positions.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2022)
Article
Chemistry, Physical
Mingsheng Luo, Hong Li, Huanqiao Song, Changke Shao, Aimei Wang
Summary: The alkylation of phenol with methanol was studied using different methods to prepare a 5 wt% cerium-supported HZSM-5 catalyst. The results showed that the preparation method significantly affected the dispersion of cerium and the catalytic performance. The impregnation method yielded a catalyst with higher Lewis acid concentration, resulting in improved selectivity. The solid-phase ion-exchange method produced a catalyst with an appropriate B/L ratio and large specific surface area, leading to the highest phenol conversion.
Article
Energy & Fuels
Changke Shao, Mingsheng Luo, Huanqiao Song, Shixin Zhang, Fengli Wang, Xinyue Liu, Zitian Huang
Summary: Great interest has been taken in the oxygen reduction reaction (ORR), which is a common cathode reaction in fuel cells and metal-air batteries, to improve the current energy structure and develop new green energy sources. The development of efficient and low-cost ORR catalysts is crucial due to the limitations of noble metal Pt as a catalyst. This study successfully synthesized CoNi-950 (Zn), a carbon-based oxygen reduction catalyst, and demonstrated its good catalytic performance. The proposed mechanism suggests that CoNi-950 (Zn) reduces O-2 through a four-electron transfer process in alkaline electrolytes. Evaluation: 8/10.
Article
Engineering, Chemical
Mingsheng Luo, Xinyue Liu, Zhijun Zhao, Fengli Wang, Changke Shao
Summary: Using honeysuckle as raw material, chlorogenic acid (CGA) was extracted with different alcohols. The relationship between each parameter and the response value was explored using the Box-Behnken method to optimize the process conditions. The best extraction results were obtained with a solid-to-liquid ratio of 1:20, an ultrasonic time of 40 min, an ultrasonic vibrator power of 240 W, and a CGA extraction rate of 2.98%. Experimental data showed that the extraction rate of CGA is related to the length of the alcohol carbon chain and the number of hydroxyl groups in the extractant. The results from this work can provide a technical basis for the safe and efficient production of CGA from honeysuckle.
Article
Chemistry, Physical
Fengli Wang, Mingsheng Luo, Qinglong Liu, Changke Shao, Zhi Yang, Xinyue Liu, Jiakun Guo
Summary: Chemical hydrogen storage is important for hydrogen fuel cell applications, and catalysts play a crucial role in developing effective hydrogen production processes. Platinum is a superior catalyst for decalin dehydrogenation, and modifying the support can enhance catalysis. The study systematically investigated the effects of different supports, preparation methods, and Mg/Al molar ratio on the material properties and catalytic performance of Pt catalysts. The results showed that the MgAl2O4 support was more suitable for improving Pt dispersion and forming smaller Pt nanoparticles. Pt/MgAl2O4 with a Mg/Al molar ratio of 0.5, prepared using the alcohol-heating method, exhibited superior performance, which was closely related to the Pt nanoparticle size and reaction state. The initial ratio of decalin to catalyst also played an important role in the activity and achieved optimal performance in the liquid-film state.
Article
Engineering, Chemical
Bohan Ai, Mingsheng Luo, Iltaf Khan
Summary: Environmental protection laws require effective and green solutions for water and air pollution, and perovskite photocatalytic materials have shown promise in this regard. In this study, CsSnBr3 perovskite coupled with ZIF-67 and decorated with noble metal Au was found to improve charge separation and light absorption, making the photocatalytic reaction more efficient. Characterization results confirmed the presence of cubic and tetragonal crystalline phases in the catalyst material, and degradation tests demonstrated the good photocatalytic activity of CsSnBr3 for organic pollutant degradation.
Article
Chemistry, Physical
Mingsheng Luo, Fengli Wang, Qinglong Liu, Wenda Li, Changke Shao, Xinyue Liu, Bohan Ai
Summary: In this study, MgAl2O4 carriers were synthesized using the alcohol-heating method, and the effects of Pt loading and Pt/Pd molar ratio on decalin dehydrogenation activity were investigated. The results showed that the size of Pt nanoparticles in the Pt/MgAl2O4 catalysts was closely related to the Pt loading, with 3 wt% being the optimum loading for decalin dehydrogenation. The PtPd bimetallic catalyst with a Pt/Pd molar ratio of 4:1 exhibited moderate interactions, resulting in enhanced catalytic performance. The superior catalytic performance of the 1 wt% Pt4Pd1/MgAl2O4 catalyst was mainly attributed to the synergistic effect of the bimetallic Pt-Pd nanoparticles.
REACTION KINETICS MECHANISMS AND CATALYSIS
(2023)