Oxidation of Olefins to Carbonyl Compounds: Modern View of the Classical Reaction

“Golden Age” of Homogeneous Catalysis Chemistry of Alkynes: Dimerization and Oligomerization of Alkynes

(2020) O. N. Temkin   KINETICS AND CATALYSIS

Kinetic model of ethylene oxidation by p-benzoquinone in solutions of cationic palladium(ii) complexes in a binary acetonitrile—water solvent

(2019) G. E. Efremov et al.   RUSSIAN CHEMICAL BULLETIN

The Mechanism and Kinetic Models of the Catalytic Oxidation of Ethylene by p-Benzoquinone in Aqueous–Acetonitrile Solutions of Pd(II) Cationic Complexes

(2018) I. V. Martynov et al.   KINETICS AND CATALYSIS

Mechanism of Catalytic Oxidation of Styrenes with Hydrogen Peroxide in the Presence of Cationic Palladium(II) Complexes

(2017) Katherine L. Walker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Liquid–liquid and liquid–liquid equilibrium for ternary system water–acetonitrile–cyclohexene at 298.15 K

(2016) Anastasia Frolkova et al.   FLUID PHASE EQUILIBRIA

Hypervalent Iodine as a Terminal Oxidant in Wacker-Type Oxidation of Terminal Olefins to Methyl Ketones

(2016) Dipali A. Chaudhari et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation

(2016) Kelly E. Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

tert-Butyl Nitrite: Organic Redox Cocatalyst for Aerobic Aldehyde-Selective Wacker–Tsuji Oxidation

(2016) Xiao-Shan Ning et al.   ORGANIC LETTERS

Mechanism of Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes with a Nitrite Co-Catalyst

(2015) Yuan-Ye Jiang et al.   ACS Catalysis

Palladium-Catalyzed anti-Markovnikov Oxidation of Terminal Alkenes

(2014) Jia Jia Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thesyn/anti-Dichotomy in the Palladium-Catalyzed Addition of Nucleophiles to Alkenes

(2014) Pavel Kočovský et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron(III) Sulfate as Terminal Oxidant in the Synthesis of Methyl Ketones via Wacker Oxidation

(2014) Rodney A. Fernandes et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Controlled Wacker-Type Oxidation: Facile Access to Functionalized Aldehydes

(2014) Zachary K. Wickens et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Markovnikov hydration of α-olefins and the other pathways to n-alcohols

(2014) O. N. Temkin   KINETICS AND CATALYSIS

Wacker-Type Oxidation and Dehydrogenation of Terminal Olefins Using Molecular Oxygen as the Sole Oxidant without Adding Ligand

(2014) Yu-Fei Wang et al.   ORGANIC LETTERS

Kinetic isotope effects for oxidation reaction of olefins by p-quinones in water-acetonitrile solutions of cationic and chloride anionic palladium complexes

(2014) D. S. Zakharova et al.   RUSSIAN CHEMICAL BULLETIN

Synthesis of methyl ketones from terminal olefins using PdCl2/CrO3 system mimicking the Wacker process

(2014) Rodney A. Fernandes et al.   TETRAHEDRON

Practical and General Palladium-Catalyzed Synthesis of Ketones from Internal Olefins

(2013) Bill Morandi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst

(2013) Zachary K. Wickens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzedortho-Selective CH Deuteration of Arenes: Evidence for Superior Reactivity of Weakly Coordinated Palladacycles

(2013) Sandy Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxypalladation Precedes the Rate-Determining Step in the Wacker Oxidation of Ethene

(2013) Venkataramana Imandi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Wacker-Type Oxidation of Internal Alkenes using Pd(Quinox) and TBHP

(2013) Ryan J. DeLuca et al.   JOURNAL OF ORGANIC CHEMISTRY

Terminal Olefins to Linear α,β-Unsaturated Ketones: Pd(II)/Hypervalent Iodine Co-catalyzed Wacker Oxidation–Dehydrogenation

(2013) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Greening the Wacker process

(2013) Mukund G. Kulkarni et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Oxidation of Unsaturated Hydrocarbons Using Molecular Oxygen

(2012) Wanqing Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Nature of [PdCl2(C2H4)(H2O)] as an Active Species in the Wacker Process: New Insights from Ab Initio Molecular Dynamics Simulations

(2012) Gábor Kovács et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient and Highly Aldehyde Selective Wacker Oxidation

(2012) Peili Teo et al.   ORGANIC LETTERS

Imparting Catalyst Control upon Classical Palladium-Catalyzed Alkenyl C–H Bond Functionalization Reactions

(2011) Matthew S. Sigman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Zirconocene catalysts for olefin polymerization: A comparative DFT study of systems with Al- and B-containing activators

(2011) Leila Yu. Ustynyuk et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Reaction of O2with [(−)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H–L]+“Reductive Elimination” Pathway

(2011) Nattawan Decharin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aquaperoxovanadium(V) complexes: Quantum-chemical study

(2011) A. A. Markov et al.   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Primary Alcohols from Terminal Olefins: Formal Anti-Markovnikov Hydration via Triple Relay Catalysis

(2011) G. Dong et al.   SCIENCE

General palladium-catalyzed aerobic dehydrogenation to generate double bonds

(2011) Weiming Gao et al.   Chemical Science

The Wacker Process: Inner- or Outer-Sphere Nucleophilic Addition? New Insights from Ab Initio Molecular Dynamics

(2010) Aleix Comas-Vives et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Syntheses of α,β-Unsaturated Carbonyl Compounds through Palladium-Mediated Dehydrogenation of Ketones, ­Aldehydes, Esters, Lactones and Amides

(2010) Jacques Muzart   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods for the Preparation of 1,2-Diols, Aldehydes, and Ketones

(2010) Azhong Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Experimental and Computational Study of a Direct O2-Coupled Wacker Oxidation: Water Dependence in the Absence of Cu Salts

(2010) Brian J. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate

(2010) Amanda E. King et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetics of cyclohexene oxidation by p-quinones in aqueous-organic solutions of cationic palladium(II) complexes

(2010) O. N. Temkin et al.   KINETICS AND CATALYSIS

DFT study of dimethylzirconocene activation by one or two Al(C6F5)3 molecules, formation of ion pairs and their reactions with ethylene

(2010) Leila Yu. Ustynyuk et al.   MENDELEEV COMMUNICATIONS

The Mechanism of the Wacker Reaction: A Tale of Two Hydroxypalladations

(2009) John���A. Keith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acetaldehyde from Ethylene-A Retrospective on the Discovery of the Wacker Process

(2009) Reinhard Jira   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant

(2009) Keith M. Gligorich et al.   CHEMICAL COMMUNICATIONS

Ethylene carbonate as a unique solvent for palladium-catalyzed Wacker oxidation using oxygen as the sole oxidant

(2009) Jing-Lun Wang et al.   GREEN CHEMISTRY

Aldehyde Selective Wacker Oxidations of Phthalimide Protected Allylic Amines: A New Catalytic Route to β3-Amino Acids

(2009) Barbara Weiner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Diacetoxylation of Alkenes with Molecular Oxygen as Sole Oxidant

(2009) Azhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General and Efficient Catalyst System for a Wacker-Type Oxidation Using TBHP as the Terminal Oxidant: Application to Classically Challenging Substrates

(2009) Brian W. Michel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Comment on “Mechanism and Kinetics of the Wacker Process: A Quantum Mechanical Approach”

(2009) John A. Keith et al.   ORGANOMETALLICS

Preparation of σ- and π-Allylcopper(III) Intermediates in SN2 and SN2′ Reactions of Organocuprate(I) Reagents with Allylic Substrates

(2008) Erika R. Bartholomew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of a Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes:  Protonolysis of a Stable Palladium Alkyl Complex Is the Turnover-Limiting Step

(2008) Brian M. Cochran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Molecular Oxygen with a PdII-Hydride To Produce a PdII-Hydroperoxide: Experimental Evidence for an HX-Reductive-Elimination Pathway

(2008) Michael M. Konnick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Kinetics of the Wacker Process: A Quantum Mechanical Approach

(2007) S. Ali Beyramabadi et al.   ORGANOMETALLICS