Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 36, Pages 15276-15281Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c08283
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Funding
- National Natural Science Foundation of China (NSFC) [21602130]
- Shanghai Jiao Tong University
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A highly branch- and enantioselective 1,4-enynes synthesis from readily available terminal alkynes and racemic allylic carbonates by Sonogashira type synergistic Rh and Cu catalysis under neutral conditions has been developed. Aliphatic and aromatic terminal alkynes with various functional groups could be used directly. An inner-sphere reductive elimination C(sp)-C(sp(3)) bond formation mechanism is supported by the stoichiometric reaction.
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