Journal
COORDINATION CHEMISTRY REVIEWS
Volume 309, Issue -, Pages 21-35Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2015.10.008
Keywords
Half-sandwich; Carborane; Transition metal; Reactivity; Application
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Funding
- Eastern Scholar, Key Subject of Shanghai Municipal Education Commission, Shanghai Municipal Education Commission (Peak Discipline Construction Program)
- National Science Foundation of China [21102088, 21174081]
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This review describes the recent progress on the research of half-sandwich late transition metal complexes with functionalized carborane ligands. Continuous study on preparation of different types of carborane-based late transition metal complexes is of great interest because of their rich coordination mode, novel reactivity and promising applications in a variety of important fields. The synthetic pathways used for the preparation of half-sandwich complexes with [SS], [PP], [NP], [PS], [CN], [CS] coordination modes are summarized. Diverse reactivities (metal-metal bonding formation, insertion reaction and B-H activation) and catalytic activities (hydrogenation, olefin polymerization, H-2 activation, asymmetric reduction and cross-coupling reaction) are also discussed in this article. (C) 2015 Elsevier B.V. All rights reserved.
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