4.6 Review

Materials for lithium recovery from salt lake brine

Journal

JOURNAL OF MATERIALS SCIENCE
Volume 56, Issue 1, Pages 16-63

Publisher

SPRINGER
DOI: 10.1007/s10853-020-05019-1

Keywords

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Funding

  1. Japan Society for the Promotion of Science [20H00288, 26420721]
  2. Qaidam Salt Chemical Joint Fund of National Natural Science Foundation of China-People's Government of Qinghai Province [U1607117]
  3. Anhui Province International Science and Technology Cooperation Program [1704e1002213]
  4. Natural Science Foundation of Anhui Province [1808085ME145]
  5. Grants-in-Aid for Scientific Research [20H00288] Funding Source: KAKEN

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The paper provides a comprehensive overview of Mg2+/Li+ separation materials and methods in lithium recovery from salt lake brines, covering global demand for lithium resources, various separation techniques, and future directions. Strategies for developing novel methods with high separation selectivity, stability, low cost, and environmentally friendly characteristics are discussed as key to advancing the field.
Rapid developments in the electric industry have promoted an increasing demand for lithium resources. Lithium in salt lake brines has emerged as the main source for industrial lithium extraction, owing to its low cost and extensive reserves. The effective separation of Mg(2+)and Li(+)is critical to achieving high recovery efficiency and purity of the final lithium product. This paper summarizes Mg2+/Li(+)separation materials and methods in the field of lithium recovery from salt lake brines. The review begins with an introduction to the global distribution and demand for lithium resources, followed by a description of the materials used in various separation techniques, including precipitation, adsorption, solvent extraction, nanofiltration membrane, electrodialysis, and electrochemical methods. A comparison, analysis, and outlook of such methods are comprehensively discussed in terms of principles, mechanisms, synthesis/operation, development, and industrial applications. We conclude with a presentation of challenges and insights into the future directions of lithium extraction from salt lake brines. A combination of the advantages of various materials is the most logical step toward developing novel methods for extracting lithium from brines with high separation selectivity, stability, low cost, and environmentally friendly characteristics.

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