4.7 Article

BeCaZnO quaternary alloy: thin films and ultraviolet photodetectors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 857, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.157567

Keywords

BeCaZnO alloy Films; Co-substitution; UV photodetectors; Pulsed laser deposition

Funding

  1. National Key R&D Program of China [2019YFB1503500]
  2. National Natural Science Foundation of China [51572073,11574074,11774082, 11975093]
  3. Natural Science Foundation of Hubei Province [2019CFA006, 2018CFB700]
  4. Program for Science and Technology Innovation Team in Colleges of Hubei Province [T201901]
  5. Wuhan Application Foundation Frontier Project [2018010401011287]

Ask authors/readers for more resources

The study successfully grew BeCaZnO quaternary alloy films, developed planar photoconductive-type UV photodetectors, and identified 525 degrees C as the suitable growth temperature. Compared to ZnO-based photodetectors, BeCaZnO photodetectors exhibited lower dark current and faster photoresponse speed.
Enlightened by the quaternary alloy of BeMgZnO, we attempted the first study of BeCaZnO quaternary alloy in this work. We succeeded in the growth of single-phase BeCaZnO alloy films by pulsed laser deposition, and developed planar photoconductive-type ultraviolet (UV) photodetectors using BeCaZnO as the active layer. The structure, morphology, and optical bandgap of the alloy films were studied as a function of the substrate temperature, which revealed 525 degrees C as the suitable growth temperature. BeCaZnO-based photodetectors were then fabricated and systematically investigated using current-voltage, spectral photoresponse, and time-dependent photoresponse characterizations. At a bias voltage of 5 V, the device based on BeCaZnO film grown at 525 degrees C showed a low dark current of 0.49 nA with a cut-off wavelength at similar to 400 nm. The peak responsivity of the device was 0.34 A/W located around 330 nm, and the specific detectivity approached 1.53 x 10(11) cm . Hz(1/2)/W (Jones). Compared with ZnO-based photodetectors, the BeCaZnO photodetectors possessed a significantly lower dark current and faster photoresponse speed. Our work indicates that BeCaZnO alloys are highly promising for future applications in optoelectronic devices such as UV photodetectors. (C) 2020 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Physical

Realizing simultaneously excellent energy storage and discharge properties in AgNbO3 based antiferroelectric ceramics via La3+ and Ta5+ co-substitution strategy

Yuqi Zhou, Shuaibing Gao, Jie Huang, Meng Shen, Shenglin Jiang, Yunbin He, Qingfeng Zhang

Summary: In this study, novel La3+ and Ta5+ co-substituted AgNbO3 ceramics were developed, which enhanced antiferroelectric phase stability and refined polarization-electric field loops by decreasing the tolerance factor, reducing the polarizability of B-site cations, and increasing local structure heterogeneity. The addition of La3+ and Ta5+ also reduced grain sizes and increased the band gap, contributing to increased energy storage capacity. The resulting (Ag0.88La0.04)(Nb0.96Ta0.04)O3 ceramics demonstrated a high recoverable energy density of 6.79 J/cm3 and large efficiency of 82.1%, surpassing many recently reported AgNbO3 based ceramics in overall energy storage properties.

JOURNAL OF MATERIOMICS (2023)

Article Chemistry, Physical

Ab initio study of two-dimensional MgAl2Se4 and MgIn2Se4 with high stability, high electron mobility, and high thermoelectric figure of merit

Wenyu Fang, Kuan Kuang, Xinglin Xiao, Haoran Wei, Yue Chen, Mingkai Li, Yunbin He

Summary: Two-dimensional materials, MgAl2Se4 and MgIn2Se4, possess low thermal conductivity and high electrical properties, showing potential applications in nanoelectronics and thermoelectric devices.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Nanoscience & Nanotechnology

High-Performance Self-Driven Solar-Blind Ultraviolet Photodetectors Based on HfZrO2/β-Ga2O3 Heterojunctions

Shuang Yan, Gaochen Yang, Huanfeng He, Qi Liu, Qingqi Peng, Jian Chen, Mingkai Li, Yinmei Lu, Yunbin He

Summary: In this study, Hf0.5Zr0.5O2/beta-Ga2O3 heterojunction-based self-driven solar-blind UV photodetectors were constructed by combining ferroelectric Hf0.5Zr0.5O2 material with Ga2O3. The optimized device with a HfZrO2 layer thickness of 10 nm showed remarkable responsivity and detectivity, outperforming single Ga2O3-based devices. The device's performance could be adjusted by varying the poling states of HfZrO2 and showed significant enhancement in the upward poling state.

ACS APPLIED MATERIALS & INTERFACES (2023)

Article Materials Science, Multidisciplinary

Ultrahigh energy density and excellent discharge properties in Ce4+and Ta5+co-modified AgNbO3 relaxor antiferroelectric ceramics via multiple design strategies

Shuaibing Gao, Yue Huang, Ying Jiang, Meng Shen, Haitao Huang, Shenglin Jiang, Yunbin He, Qingfeng Zhang

Summary: In this study, Ce4+ and Ta5+ co-modified (Ag0.96Ce0.01)(Nb1-xTax)O3 relaxor antiferroelectric (AFE) ceramics were designed to improve the energy storage properties of silver niobate (AgNbO3). The co-doping strategy not only suppressed the ferrielectric behavior and enhanced the relaxor degree, but also improved the breakdown strength and discharge properties of the ceramics. The resulting ceramic exhibited an ultrahigh recoverable energy density, large power density, and stable discharge capacity over a wide temperature range.

ACTA MATERIALIA (2023)

Article Materials Science, Ceramics

Bandgap narrowing and polarization enhancement in (K,Na,Li)(Nb,Sb,Ta)O3+x% Fe2O3 lead-free ceramics for photovoltaic applications

Jian Chen, Jiaxing Mao, Zihui Wang, Yanhui Dong, Jinming Guo, Mingkai Li, Yi Zhang, Yinmei Lu, Yunbin He

Summary: In this work, lead-free ceramics with narrow bandgaps and large remanent polarization are obtained via Fe2O3 doping. The optimized ceramic possesses a narrow bandgap of 1.74 eV and a large remanent polarization of 27.05 muC/cm2. Furthermore, a switchable photovoltaic effect is observed in the ceramic-based device.

JOURNAL OF ADVANCED CERAMICS (2023)

Article Physics, Applied

Correlation of metal-to-insulator transition and strain state of VO2 thin films on TiO2 (110) substrates

Hao Lu, Lei Li, Zhiwu Tang, Maji Xu, Yonghui Zheng, Martin Becker, Yinmei Lu, Mingkai Li, Pai Li, Zaoli Zhang, Peter J. J. Klar, Yunbin He

Summary: We explore the possibility of tuning the metal-to-insulator transition (MIT) of crystalline VO2 thin films by strain engineering. Thin VO2 films on TiO2 (110) substrates are almost fully strained up to thicknesses of about 20 nm and exhibit tensile strain along the c axis of the (high-temperature) metallic rutile phase leading to an increase in the MIT temperature by as much as 30 & DEG;C in comparison to the almost fully relaxed 300 nm-thick VO2 film. The strain gradient within the thicker samples leads to a continuous serial switching of layered regions of the VO2 film from the insulating to the metallic state with increasing temperature.

APPLIED PHYSICS LETTERS (2023)

Article Chemistry, Physical

First-principles study of the rectifying properties of Au/SnO2 interface

Yue Chen, Wenyu Fang, Fengxin Liu, Kuan Kuang, Xinglin Xiao, Haoran Wei, Mingkai Li, Yunbin He

Summary: Based on first-principles calculations, the properties and characteristics of Au contacts on different SnO2 interfaces were investigated. The Schottky barrier height (SBH) was found to strongly depend on the interface structure and the presence of oxygen vacancies (VO) in the SnO2 layer. Additionally, doping with low-valence elements can alter the contact properties. The modulation effect of SBH is mainly caused by the rearrangement of interfacial potentials and results in different SBH values.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Physical

MgO (100) as an affordable support for heteroepitaxial growth of high-quality β-Ga2O3 thin films and related highly-sensitive solar-blind UV photodetectors

Pan Huang, Lufeng Chen, Daotian Shi, Qi Liu, Jian Chen, Mingkai Li, Yinmei Lu, Jinming Guo, Yunbin He

Summary: In this study, high-quality beta-Ga2O3 thin films were heteroepitaxially grown on MgO(100) substrates using pulsed laser deposition, and highly-sensitive solar-blind ultraviolet photodetectors were achieved. The beta-Ga2O3 films were single-phase, (100)-oriented, and atomically-smooth with unique columnar nanodomains of 8-12 nm width.

APPLIED SURFACE SCIENCE (2023)

Article Materials Science, Multidisciplinary

Narrow-Bandgap Mixed 0D/1D Bismuth Bromide Perovskite Hydrate Enabled by Aromatic Ditertiary Ammonium Spacer

Junnian Chen, Xingfu Xiao, Yue Chen, Mingkai Li, Wenyu Fang, Zixian Yu, Biqi He, Tianyou Zhai, Yunbin He

Summary: This study reports a method of modulating the structural distortion by steric hindrance effects to change the morphology of bismuth bromide chains. By interacting with bismuth bromide, N,N,N & PRIME;,N & PRIME;-tetramethyl-1,4-phenylenediammonium (TMPD)(2+) is used to template regular BiBr5 chains, resulting in a narrow-bandgap mixed 0D/1D (TMPD)(2)(Bi2Br10H2O)-H-. This finding offers new insights into developing narrow-bandgap perovskite hydrates for practical optoelectronic applications.

ADVANCED OPTICAL MATERIALS (2023)

Article Chemistry, Physical

Ultra-superior high-temperature energy storage properties in polymer nanocomposites via rational design of core-shell structured inorganic antiferroelectric fillers

Zhenhao Fan, Shuaibing Gao, Yunfei Chang, Dawei Wang, Xin Zhang, Haitao Huang, Yunbin He, Qingfeng Zhang

Summary: Current polymer nanocomposites for energy storage suffer from low discharged energy density and efficiency at high temperature. To solve this problem, polyetherimide (PEI) nanocomposites filled with core-shell structured nanoparticles are developed, which consist of a PLZST antiferroelectric core and an Al2O3 shell. The PLZST core provides a wide temperature range of low remnant electric displacement, improving the electric displacement-electric field loops of the nanocomposites. The Al2O3 shell with similar dielectric constant to the PEI matrix and high thermal conductivity enhances breakdown strength and suppresses conduction loss, resulting in an ultrahigh discharged energy density of 10.20 J cm(-3) at 150 degrees C and a large efficiency of 83.5%.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Materials Science, Multidisciplinary

Ferroelectric enhanced Ga2O3/BFMO-based deep ultraviolet photovoltaic detectors with dual electric fields for photogenerated carrier separation

Yingying Cheng, Jiaxing Mao, Hongyi Zhu, Yanhui Dong, Jian Chen, Mingkai Li, Yinmei Lu, Yunbin He

Summary: In this study, a strategy for constructing Ga2O3/BFMO heterojunction-based photodetectors was proposed to enhance responsivity and detectivity by utilizing the built-in electric field and ferroelectric depolarization electric field for carrier separation. The fabricated photodetector exhibited tunable performance under zero bias, with higher performance observed in the upward poling state and under weak light illumination.

JOURNAL OF MATERIALS CHEMISTRY C (2023)

Article Chemistry, Multidisciplinary

Broadband red emission from one-dimensional hexamethonium lead bromide perovskitoid

Biqi He, Kuan Kuang, Bing Xu, Junjie Tang, Sheng Cao, Zixian Yu, Mingkai Li, Yunbin He, Junnian Chen

Summary: A one-dimensional hybrid lead bromide perovskitoid based on hexamethonium has been developed for broadband red emission. The unique structure results in intriguingly red emission peaking at 692 nm, with a PLQY of around 6.24%. Spectroscopic and computational studies reveal the origin of the red emission.

CHEMICAL COMMUNICATIONS (2023)

Article Chemistry, Physical

Magnetic/optical assessments of RFeO3 (R=La, Pr, Nd, and Sm) ceramics: An experimental and theoretical discernment

J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia

Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

The effect of Ti-based surface layer on AlSi thin film as a high-performance anode for the lithium-ion battery

Xianxiang Lv, Jing Jin, Weiguang Yang

Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Bifunctional phosphate-modulated Cu2O/CeO2 redox heterojunction: A promising approach for proficient CO2 reduction

Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao

Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Engineering heterogeneous synergistic interface and multifunctional cobalt-iron site enabling high-performance oxygen evolution reaction

Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong

Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Highly efficiency blue emissive from Bi3+ions in zero-dimensional organic bismuth halide for white LED applications

Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang

Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Study on the wear resistance and mechanism of AlCrCuFe2NiTix high-entropy surfacing alloys

Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong

Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Facile synthesis of ternary g-C3N4/polyacrylic acid/CoFe2O4 nanocomposites for solar light irradiated photocatalytic and supercapacitor applications

M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu

Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Investigation on bio-synthesized Ni- and Al-doped cobalt ferrite using lemon juice as eco-fuel

Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad

Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Cu, Ni and Ag ions assisted preparation of nonpolar preferential oriented ZnO films with controlled morphology and optical properties

Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi

Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Characterization of magnetic FeCo particles with controlled bimetallic composition

Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang

Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Micro-alloying effects of Ta and B on nano-oxides and grain boundaries in 13CrWTi-ODS ferritic alloys

Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang

Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Nitrogen-doped reduced graphene oxide/black phosphorus quantum dot composites for electrocatalytic treatment of choroidal melanoma

Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang

Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Significantly enhanced magnetism in cobalt ferrite by manganese and terbium co-doping

Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu

Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

High-performance low-temperature solid oxide fuel cell with nanostructured lanthanum strontium cobaltite/yttria-stabilized zirconia cathode via advanced co-sputtering

Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee

Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)

Article Chemistry, Physical

Amorphous quaternary alloy nanoplates for efficient catalysis of hydrogen evolution reaction

Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu

Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.

JOURNAL OF ALLOYS AND COMPOUNDS (2024)