Article
Chemistry, Multidisciplinary
Marin Nikolic, Alessia Cesarini, Emanuel Billeter, Fabian Weyand, Pavel Trtik, Markus Strobl, Andreas Borgschulte
Summary: This study investigates the working conditions of commercial Ni-mischmetal hydride batteries using non-destructive and high-resolution methods. By combining neutron radiography and tomography with electrical monitoring of the state of charge, the exchange and transport of hydrogen can be tracked in real time. The study reveals that the charging state of the battery affects the generation of hydrogen gas.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Yaolin Xu, Fokko M. Mulder
Summary: Magnesium is attracting research interest as an anode material for Ni-MH batteries due to its lightweight, cost-effectiveness, and high theoretical capacity. Challenges such as poor hydrogen sorption kinetics and passivation from aggressive electrolytes have been addressed by using non-alloyed but catalyzed magnesium and adding TiF3 as a catalyst. Promising electrochemical performance has been achieved, with potential for further improvements.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Hai-Ru Li, Ceng Zhang, Wan-Biao Ren, Ying-Jin Wang, Tao Han
Summary: Based on density functional theory, this paper investigates the electronic properties and hydrogen storage properties of M2B7 (M = Be, Mg, Ca) clusters systematically. It is found that the global minimal structures of Be2B7, Mg2B7, and Ca2B7 are heptagonal biconical structures, with the alkaline earth metals located at the top. The M2B7 clusters exhibit good hydrogen storage capabilities, exceeding the hydrogen storage target set by the US Department of Energy in 2017. The clusters can achieve reversible adsorption of H2 molecules at normal temperature and pressure, making them a promising new nano hydrogen storage material.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Yanchong Yu, Yanquan Ji, Shaohua Zhang, Shuai Wang, Yiwan Chen, Baosheng Liu, Yanghuan Zhang
Summary: In this study, Mg-Ni-Y alloy was prepared and it was found that the Ni element can improve the thermodynamic properties of the alloy. Increasing Ni content helps to enhance the hydrogen absorption and desorption kinetics of the alloy.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Electrochemistry
Hang Lu, Yanan Guo, Qing Wang, Anyi Zhang, Yuan Li, Ning Xi, Xiaomei Zhu, Shumin Han, Lu Zhang
Summary: La-Mg-Ni-based alloys with a novel AB(4)-type superlattice structure are proposed as potential anode materials for Ni/MH batteries. The formation of the AB(4)-type phase during annealing and its effect on electrochemical characteristics are studied. The presence of the AB(4)-type phase leads to a higher discharge capacity at both low and high rates, as well as improved cycling stability and tolerance at low temperatures.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Rui Shi, Haoxing Yan, Jiguang Zhang, Haiguang Gao, Yunfeng Zhu, Yana Liu, Xiaohui Hu, Yao Zhang, Liquan Li
Summary: A simple, cost-effective method of water treatment is proposed to produce highly reactive and air-stable bulk Mg-Ni-based hydrides in this study. The method can significantly decrease the dehydrogenation temperature and allow the hydrides to be stored under ambient conditions without losing activity, providing an alternative approach to design low-cost, highly active metal hydrides.
Article
Nanoscience & Nanotechnology
Parisa Edalati, Abbas Mohammadi, Yongtao Li, Hai-Wen Li, Ricardo Floriano, Masayoshi Fuji, Kaveh Edalati
Summary: This study investigates the use of high-entropy alloys as new anode materials for Ni-MH batteries, with findings showing optimal Ti/Zr ratios for the highest storage capacity and fastest activity. High-entropy alloys demonstrate potential as anode materials for Ni-MH battery applications.
SCRIPTA MATERIALIA
(2022)
Article
Chemistry, Physical
Wenbin Jiang, Cheng Tan, Jianling Huang, Liuzhang Ouyang, Min Chen, De Min, CanHui Liao, RenHeng Tang, Min Zhu
Summary: A hyper-stoichiometric AB(5.09) alloy with Sm doping is designed to achieve high power performance in Ni-metal hydride batteries. The addition of Sm results in a decrease in maximum capacity and hydride stability, but an increase in cycling stability. The alloys exhibit good high-rate discharge performance due to the formation of the Ni2MnAl catalytic phase, with further improvements in high-rate dischargeability and specific power after Sm doping.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Physical
Yafei Zhang, Pingping Liu, Xiaoling Zhu
Summary: The H-2 adsorption characteristics of Li-decorated siliconene were predicted using DFT, showing that double-sided siliconene can store up to 12 H(2) molecules and release them gradually at a suitable desorption temperature of 281 K, making it a promising candidate for hydrogen storage applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
K. C. Bhamu, Jin Suk Chung, Sung Gu Kang
Summary: In this study, a compound for liquid organic hydrogen carrier (LOHC) applications was designed and its dehydrogenation reaction was investigated. The compound was found to be dynamically and chemically stable, and N-substitution was suggested to lower the dehydrogenation energy.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Xiangyang He, Wei Xiong, Li Wang, Baoquan Li, Jin Li, Shujuan Zhou, Jiaxuan Li, Huizhong Yan
Summary: This paper investigates the evolution law of different phases in La-Y-Ni-based hydrogen storage alloys and synthesizes three single-phase alloys. The results demonstrate that La2Y4Ni21 alloy has the highest hydrogen storage capacity and all the target alloys exhibit excellent electrochemical activation ability and cycle stability. These findings provide theoretical guidance and technical support for the development of La-Y-Ni-based hydrogen storage alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Review
Green & Sustainable Science & Technology
Hossein Salehi, Samane Maroufi, Sajjad S. Mofarah, Rasoul Khayyam Nekouei, Veena Sahajwalla
Summary: The recycling of nickel-metal hydride batteries (NiMHBs) has gained attention due to the demand for critical metals and environmental legislation. The majority of rare earth elements (REEs) in NiMHBs are discarded in landfills, causing global concern. Extracting REEs through urban mining is one strategy to address this issue. This study provides a comprehensive review on strategies and technologies for REEs recovery from spent NiMHBs, along with challenges, shortcomings, and potential future directions.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2023)
Article
Chemistry, Physical
Brahamananda Chakraborty, Pranoy Ray, Nandini Garg, Srikumar Banerjee
Summary: Titanium-modified Psi-Graphene has been shown to have high stability, 100% recyclability, and high hydrogen storage capacity with suitable desorption temperature, making it a potential material for hydrogen storage in the future clean, green hydrogen economy.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Chengjing Mi, Yanping Huang, Fengtao Chen, Kui Wu, Weiyan Wang, Yunquan Yang
Summary: DFT calculations were used to study the catalytic dehydrogenation of methylcyclohexane on Ni-Pt(111) catalyst, which showed weaker binding strength between species and surface metal atoms compared to Pt(111). Pt was identified as the main active component in stable adsorption configurations on Ni-Pt(111).
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Terry D. Humphries, Mark Paskevicius, Ali Alamri, Craig E. Buckley
Summary: Thermal batteries are efficient for storing renewable energies, utilizing reversible thermochemical reactions to drive a heat engine. Studies on the SrH2-2Al system have shown promising properties for high efficiency operation, which could enhance technological applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Environmental Sciences
Amina Laouid, Amine Alaoui Belghiti, Krzysztof Wisniewski, Abdelowahed Hajjaji, Bouchta Sahraoui, Anna Zawadzka
Summary: In this study, the photoluminescence properties of Znq(2) thin films co-doped with different concentrations of DCM were experimentally investigated. The results confirm that the doping affects the intensity of DCM's photoluminescence and demonstrates a complete energy transfer from Znq(2) to DCM. Additionally, the real-time measurement of the sample's lifetime shows differences among the samples. Thus, doping influences the optical properties of Znq(2) and has potential for optoelectronic applications.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Inorganic & Nuclear
El Mahdi Bouabdalli, Mohamed El Jouad, Samira Touhtouh, Abdelowahed Hajjaji
Summary: Phosphate glasses have unique properties that make them applicable in various fields. This study investigated the impact of europium dopant on the structural properties of glass through molecular dynamics simulations, revealing good solubility of europium in the glass matrix.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
(2023)
Article
Polymer Science
Imane Salhi, Jacques Jay, Fouad Belhora, Abdelowahed Hajjaji
Summary: This study presents the design and fabrication of an experimental set-up for measuring the thermal conductivity of low-thickness polymers at room temperature. The instrument, developed using electrical resistance as a heater and limited components, is affordable and lightweight. Error analysis and reproducibility analysis demonstrate that the instrument is reliable in making thermal conductivity measurements, with an average error of +/- 7%.
POLYMERS FOR ADVANCED TECHNOLOGIES
(2022)
Article
Environmental Sciences
El Mokhtar El Hafidi, Abdelhadi Mortadi, Abderrazzak Graich, El Ghaouti Chahid, Said Laasri, Reddad El Moznine, Mohammed Monkade
Summary: The main aim of this study was to develop and monitor an effective industrial wastewater treatment system using sand, fly ash, and hearth ash. The system successfully achieved significant reductions in COD, BOD5, suspended solids, and heavy metals. Impedance measurements across a frequency range of 100 to 1 MHz showed a strong correlation with conventional methods in determining electrical parameters.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2023)
Article
Chemistry, Physical
M. Rkhis, S. Laasri, S. Touhtouh, F. Belhora, E. K. Hlil, K. Zaidat, S. Obbade, A. Hajjaji
Summary: In this paper, the impact of mechanical treatment on the hydrogenation states of magnesium compounds was investigated using density functional theory (DFT). The results show that strain energy contributions can improve the thermodynamic and kinetic properties of preliminarily hydrogenated magnesium, providing better clues for the development of magnesium-based metal hydrides for hydrogen storage.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Physical
Mourad Rkhis, Said Laasri, Samira Touhtouh, El Kebir Hlil, Abdelowahed Hajjaji
Summary: The effect of strain engineering on the electrochemical properties of olivine-based LiMPO4 (M = Co and Ni) was investigated using DFT + U. The results showed that biaxial compressive strain improved the structural stability and reduced the open-circuit voltage of LiCoPO4 (LCP) and LiNiPO4 (LNP) systems. Moreover, the strain also promoted Li+ diffusion and increased electronic conductivity.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Physics, Applied
Fadimatou Ahmadou, Imane Bencheikh, Meryem Bensemlali, Karima Azoulay, Jamal Mabrouki, Hamid Nasrellah, Said Laasri, Rachid Slimani, Souad El Hajjaji
Summary: In recent years, researchers have been exploring the use of biomaterials from various sources for wastewater treatment. This study focuses on using Moringaoleifera pods and kernels powder for removing methylene blue dye from water. The adsorption process follows the pseudo-second-order model, and the adsorbents were characterized using FT-IR, XRD, and SEM. The optimization process determined the optimal conditions for MOPP and MOKP, achieving high removal efficiencies of 98.12% and 96.94% respectively. The chosen model was validated by experimental data, and ANOVA confirmed the high-efficiency adsorbent capacity of the materials.
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS
(2023)
Proceedings Paper
Materials Science, Multidisciplinary
Seddiq Sebbahi, Nouhaila Nabil, Amine Alaoui-Belghiti, Said Laasri, Samir Rachidi, Abdelowahed Hajjaji
Summary: A profound transformation of the global energy system is needed to meet the goals of the Paris Agreement. There is significant political and commercial momentum for clean hydrogen development, and the use of renewable energy sources in water electrolysis processes for hydrogen production is gaining momentum.
MATERIALS TODAY-PROCEEDINGS
(2022)
Article
Physics, Applied
Madiha Yessari, Najoua Fangachi, Imane Salhi, Mohamed Rguiti, Abdelowahed Hajjaji
Summary: Vibration-based energy harvesting is a growing field for generating low-power electricity in wireless electronic devices. This study proposes a piezoelectric vibration energy harvester based on a dual cantilever structure, and through finite element analysis and experimental validation, it is shown that the bandwidth is increased by 30 Hz and a certain amount of power is successfully generated.
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Otmane Sadek, Samira Touhtouh, Mourad Rkhis, Rania Anoua, Mohamed El Jouad, Fouad Belhora, Abdelowahed Hajjaji
Summary: In this study, titanium dioxide (TiO2) nanopowders with a crystal size of 49.3 nm in the anatase phase were successfully synthesized using the sol-gel method and titanium tetraisopropoxide (TTIP) as the precursor. The obtained powders were analyzed using FTIR, X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDX).
MATERIALS TODAY-PROCEEDINGS
(2022)
Proceedings Paper
Materials Science, Multidisciplinary
Abdelilah Tamin, Amine Alaoui-Belghiti, Said Laasri, Samira Touhtouh, Fouad Belhora, Mohamed Louzazni, Abdelowahed Hajjaji
Summary: In order to comply with international standards, treatments are necessary to deal with sulfur gas emissions. Recovering and treating these effluents can produce energy while protecting the environment. The activity of catalysts is attractive for energy production and the elimination of toxic contaminants. The simultaneous production of sulfur and water through catalytic oxidation of H2S is studied.
MATERIALS TODAY-PROCEEDINGS
(2022)