Journal
INORGANIC CHEMISTRY
Volume 59, Issue 19, Pages 13972-13978Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c01641
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Funding
- Sorbonne Universite, CNRS
- ANR program [NUMEN ANR17-CE09-0037, UMR 7197, UMR 7574]
- CNRS [UMR 8233]
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Unlike the classical organometallic approach, we report here a synthetic pathway requiring no reducing sources or heating to produce homogeneous hexagonal-close-packed cobalt nanocrystals (Co NCs). Involving a disproportionation process, this simple and fast (6 min) synthesis is performed at room temperature in the presence of ecofriendly fatty alcohols to passivate Co NCs. Through a recycling step, the yield of Co NCs is improved and the waste generation is limited, making this synthetic route cleaner. After an easy exchange of the capping ligands, we applied them as unsupported catalysts in the stereoselective semihydrogenation of alkynes.
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