Article
Engineering, Chemical
Juntao Gao, Yingying Liu, Tian Xia, Liping Sun, Hui Zhao, Bo Wei, Qiang Li
Summary: In this study, Sr0.5Bi0.4Ca0.1FeO3-delta (SBCF) and Sr0.5Bi0.5FeO3-delta (SBF) oxides were investigated as oxygen electrodes for solid oxide fuel cells (SOFCs). SBCF showed lower polarization resistance and better chemical stability, suggesting its potential as an electrode for SOFCs.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Review
Electrochemistry
Zhiheng Li, Mengran Li, Zhonghua Zhu
Summary: Acceleration of the oxygen reduction reaction at the cathode is crucial for low-temperature solid oxide fuel cells. Understanding the interactions between surface and bulk of the cathode materials is important for electrode kinetics and overall efficacy. Future research directions include investigating the role of oxygen vacancy, rational modulation of surface-bulk interactions, and the use of advanced fabrication techniques.
ELECTROCHEMICAL ENERGY REVIEWS
(2022)
Article
Thermodynamics
Juntao Gao, Dan Ma, Hui Zhao, Qiang Li, Zhe Lu, Bo Wei
Summary: Fe-based pervoskite oxides Bi0.5Sr0.5Fe1_xZrxO3_delta (BSFZx, x = 0, 0.05, 0.10 and 0.15) doped with cation Zr were synthesized and investigated as cathodes for SOFCs. The BSFZ0.10 cathode exhibited the lowest Rp values and the highest electrocatalytic performance, making it a promising candidate for oxygen-conducting SOFCs.
Article
Chemistry, Physical
Haibo Hu, Yi Lu, Xinghong Zhou, Jun Li, Xiaoyu Wang, Xifeng Ding
Summary: A La/Nb co-doped perovskite has been developed as a promising cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs), exhibiting excellent ORR activity and CO2 tolerance.
JOURNAL OF POWER SOURCES
(2022)
Article
Engineering, Environmental
Yuan Zhang, Junbiao Li, Heping Xie, Zhipeng Liu, Suling Shen, Ying Teng, Daqin Guan, Shuo Zhai, Yufei Song, Wei Zhou, Bin Chen, Meng Ni, Zongping Shao
Summary: By utilizing a CO2-induced reconstruction strategy, a BaCO3 shell with both oxygen incorporative and robust properties was successfully built on a self-assembled composite cathode made of BaFeO3-delta perovskite. The resulting cathode exhibited enhanced ORR activity, durability, and thermomechanical compatibility.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Xiaona Zhang, Tian Xia, Qiang Li, Liping Sun, Lihua Huo, Hui Zhao
Summary: The highly active and CO2-tolerant Pr0.94Ba0.7Ca0.3CO2O5+delta (P0.94Ba0.3C) cathode has shown low polarization resistance and excellent long-term stability for solid oxide fuel cells operating below 700 degrees C. Its CO2 tolerance has also been demonstrated, making it a promising candidate for SOFCs operating at lower temperatures.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Nanoscience & Nanotechnology
Zhongqiu Li, Bo Guan, Fang Xia, Jiuyuan Nie, Wenyuan Li, Liang Ma, Wei Li, Lingfeng Zhou, Yi Wang, Hanchen Tian, Jian Luo, Yan Chen, Matthew Frost, Ke An, Xingbo Liu
Summary: A new series of HEPs are investigated as cathode materials for SOFCs, achieving both chromium tolerance and high performance. The A-site elements have a significant influence on overall performance, and using the three most active elements simultaneously leads to the best candidate. Excellent Cr tolerance has been observed, with degradation of only 0.25%/kh during operation.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Jiayi Chen, Xin Gao, Xiaodong Chen, Zheng Zhen, Ya Chen, Xiantai Zeng, Lifeng Cui
Summary: This review summarizes the recent research progress on the electrochemical performance and CO2 reduction mechanism of perovskite oxide-based cathodes in solid oxide electrolysis cells (SOECs). The potential solutions to degradation and the effects of different modification methods on the performance of perovskite cathodes are also discussed.
MATERIALS TODAY PHYSICS
(2023)
Article
Chemistry, Physical
Ben Ma, Zhaohui Chen, Zhuang Lin, Lin Cheng, Yingke Zhou
Summary: This study investigates the effects of Mg doping on the performance of Mn-Cr spinel oxide cathodes in solid oxide fuel cells (SOFCs). Both experimental results and density functional theory (DFT) calculations show that Mg doping can optimize the electronic structure of the spinel oxide, increase the oxygen vacancy concentration, and improve the electrical conductivity and catalytic activity. The Mg-doped Mn-Cr spinel oxide cathode exhibits superior performance with high area-specific polarization resistance and maximum power density.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Yongli Pei, Haocong Wang, Jian Gong, Zixiang Yan, Lanlan Xu, Xiaojuan Liu, Xiaochen Gao, Fanzhi Meng, Jian Meng
Summary: This study investigates the influence of Co and Hf co-doping on the performance of BaFeO3-delta based perovskite oxide as cathode materials for solid oxide fuel cells (SOFC). The results show that the co-doped material exhibits excellent catalytic activity, CO2 stability, and electrochemical performance.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Nanoscience & Nanotechnology
Feifei Dong, Zhan Lin, Zilin Ma, Lu Li, Qirui Ye, Biaokui Dongyang, Wenying Yang
Summary: In this study, a new perovskite-based BaFeO3-delta (BF) matrix, Ba0.75Sr0.25Fe0.875Y0.125O3-delta (BSFY), is proposed as a highly active cathode for IT-SOFCs. The BSFY electrode exhibits a significantly lower area-specific resistance and higher peak power density compared to the BF counterpart, and demonstrates resistance against CO2 contaminants.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Applied
Feifei Dong, Zhenghui Gao, Bingkai Zhang, Lu Li, Ziqi Kong, Zilin Ma, Meng Ni, Zhan Lin
Summary: A novel cobalt-free perovskite oxide, Ba0.75Sr0.25Fe0.875Ga0.125O3-delta (BSFG), has been developed as an efficient oxygen reduction electrode for solid oxide fuel cells (SOFCs), demonstrating exceptional electrochemical performance at 600 degrees C. The stable crystalline structure and favorable thermal expansion behavior contribute to the short-term performance stability of the cathode.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
Materials Science, Ceramics
Junmeng Jing, Ze Lei, Ziho Wu, Zhongxu Wang, Haorui Yu, Zhibin Yang, Suping Peng
Summary: This study investigates the oxygen vacancy engineering on cobalt-free Ba0.95La0.05FeO3-delta (BLF) by nickel substitution, which promotes the generation of oxygen vacancies and enhances catalytic activity, leading to improved electrochemical performance of proton-conducting solid oxide fuel cells (H+-SOFCs).
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
(2022)
Article
Engineering, Multidisciplinary
Hongxia Gu, Meigui Xu, Yufei Song, Chuan Zhou, Chao Su, Wei Wang, Ran Ran, Wei Zhou, Zongping Shao
Summary: A new perovskite SrCo0.8Ti0.1Ta0.1O3-delta (SCTT) with high electrical conductivities, appropriate oxygen vacancy concentrations, and high bulk diffusion capability has been developed, showing favorable oxygen reduction reaction (ORR) activity at intermediate temperatures. The SCTT material exhibits high peak power density and durability in solid oxide fuel cells and protonic ceramic fuel cells, potentially accelerating the commercialization of IT-SOFC technology.
COMPOSITES PART B-ENGINEERING
(2021)
Article
Materials Science, Ceramics
Idris Temitope Bello, Na Yu, Shuo Zhai, Yufei Song, Siyuan Zhao, Chun Cheng, Zhenbao Zhang, Meng Ni
Summary: This study investigates the effects of lattice contraction and expansion on the performance and CO2 tolerance of Ba0.5Sr0.5Co0.7Fe0.3O3-delta (BSCF) air electrode material. Strategic substitution of Fe-B-site cations with transition metals achieves lattice contraction and expansion. The lattice-contracted BSCFC5 cathode exhibits the best performance and enhanced CO2 tolerance.
CERAMICS INTERNATIONAL
(2022)
Article
Environmental Sciences
Hexing Wang, Wenyun Li, Jiaqi Yang, Yuanping Wang, Hongyi Du, Minghui Han, Linji Xu, Shuping Liu, Jianping Yi, Yue Chen, Qingwu Jiang, Gengsheng He
Summary: This study investigated the effects of gestational exposure to PFASs on fetal growth by examining DNA methylation in placenta tissue of pregnant women. The results showed that PFOS was negatively associated with LINE-1 methylation, and the mixture of PFASs was negatively associated with LINE-1 methylation and NR3C1 methylation. PFOA, PFNA, PFDA, and the PFASs mixture were negatively associated with head circumference. Stratified analysis by newborns' sex found that PFOA, PFNA, and the PFASs mixture were negatively associated with LINE-1 methylation in males, and LINE-1 methylation was negatively associated with ponderal index in females. Interactions between newborns' sex and PFOS/PFOA on IGF2 and LINE-1 methylation were statistically significant. These findings suggest that intrauterine exposure to PFASs affects placental DNA methylation and reduces fetal growth, which may be modified by sex.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Energy & Fuels
Biao Xie, Hanyang Zhang, Wenming Huo, Renfang Wang, Ying Zhu, Lizhen Wu, Guobin Zhang, Meng Ni, Kui Jiao
Summary: Gaining a deeper and clearer understanding of the transport mechanism in proton exchange membrane (PEM) fuel cells is crucial for their commercialization. This study investigates the water transition mechanism in the catalyst layer of PEM fuel cells from a macro-scale performance model perspective. Various operating conditions and water transition mechanisms are analyzed, and a self-adaptive mechanism is proposed and validated. The results show that the proposed method has good adaptability and fidelity for multi-condition simulation, which is an urgent requirement for PEM fuel cell research and development.
Article
Thermodynamics
Zengjia Guo, Qidong Xu, Meng Ni
Summary: Battery aging significantly affects the thermal characteristics and electrochemical performance of electric vehicle batteries. This research develops a realistic and generic model for the design of battery thermal management systems (BTMS) to ensure efficient and durable operation of batteries. The study shows that BTMS provides effective cooling to batteries in their initial working cycles but fails to control the battery temperature after aging. Furthermore, BTMS with Y direction mini-channels provides more effective cooling and achieves good electrochemical performance.
APPLIED THERMAL ENGINEERING
(2023)
Review
Engineering, Environmental
Jie Yu, Zheng Li, Tong Liu, Siyuan Zhao, Daqin Guan, Daifen Chen, Zongping Shao, Meng Ni
Summary: This article summarizes recent efforts and progress in regulating the electronic and morphological structures of CoxAy (A = P, S, Se)-based materials for the optimization of their catalytic performance. Methods such as phase control, defect engineering, nanostructure construction, heteroatom doping, and composite engineering are introduced to optimize the electronic configurations, increase active sites, and enhance the conductivity, etc. Furthermore, the underlying activity-structure relationships behind the boosted catalytic behavior of these materials are discussed in detail. Lastly, a perspective on the future exploration of CoxAy (A = P, S, Se)-based electrocatalysts is presented. This review provides valuable insights into the investigation of emerging materials in energy chemistry.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Zengjia Guo, Qidong Xu, Yang Wang, Tianshou Zhao, Meng Ni
Summary: This paper develops a realistic and generic model combining electrochemical reactions, capacity decay, and heat transfer for the design of battery thermal management system (BTMS). The multiphysics behaviors of HP-BTMS and MHP-BTMS under different working cycles are analyzed and compared. It is found that HP-BTMS and MHP-BTMS can provide good thermal management for batteries for only several working cycles. The optimized MHP-BTMS with X direction MHP, non-equidistant arrangements, and cold plates effectively controls the battery temperature even after 1250 cycles, preventing SEI formation and capacity decay.
Article
Thermodynamics
Zheng Li, Qijiao He, Chen Wang, Na Yu, Idris Temitope Bello, Meiting Guo, Meng Ni
Summary: Protonic ceramic fuel cells (PCFCs) were studied to investigate the effects of structural parameters on cogeneration performance. Increasing cell length and electrochemical reaction section (ERS) enhance the ethylene yield. The highest ethylene yield of 44% was obtained in a 10 cm PCFC at 973 K. By decreasing the ERS ratio, the current density can be enhanced up to 14% and reaches the highest value of 2235 A m(-2) in an 8 cm PCFC with a 30% ERS ratio. This model provides insights into the relationship between structural parameters and cogeneration performance in PCFC and can be applied to other hydrocarbon fuels.
Article
Engineering, Environmental
Yuan Zhang, Junbiao Li, Heping Xie, Zhipeng Liu, Suling Shen, Ying Teng, Daqin Guan, Shuo Zhai, Yufei Song, Wei Zhou, Bin Chen, Meng Ni, Zongping Shao
Summary: By utilizing a CO2-induced reconstruction strategy, a BaCO3 shell with both oxygen incorporative and robust properties was successfully built on a self-assembled composite cathode made of BaFeO3-delta perovskite. The resulting cathode exhibited enhanced ORR activity, durability, and thermomechanical compatibility.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Construction & Building Technology
Ping He, Jin Xue, Geoffrey Qiping Shen, Meng Ni, Shengwei Wang, Han Wang, Lijie Huang
Summary: Under the context of climate change, there is a call for a paradigm shift towards environmentally sensitive urban design. This study examines the impact of neighborhood layout heterogeneity on carbon emissions, considering five indicators and different renewable energy application ratios. Through multiple linear regression analysis, it is found that building density and shape heterogeneity significantly influence neighborhood carbon emissions. The heterogeneity of building height hinders carbon reduction efforts, while the heterogeneity of building shape improves carbon reduction through facade solar energy collection. However, there is a trade-off in decision-making when designing low-carbon neighborhoods due to the opposite effects of layout heterogeneity on solar energy collection and building energy consumption.
ENERGY AND BUILDINGS
(2023)
Article
Thermodynamics
Tonghui Cui, Jianzhong Zhu, Zewei Lyu, Han Minfang, Kaihua Sun, Yang Liu, Meng Ni
Summary: Coupling external heat sources effectively reduces energy consumption and improves the efficiency of the solid oxide electrolysis (SOEC) system. Three coupling scenarios are defined based on the internal heat demand and the temperature of external heat sources. The study analyzes the influence of critical parameters on system efficiency and provides insights for selecting optimal working conditions and guiding online control during system operation.
ENERGY CONVERSION AND MANAGEMENT
(2023)
Article
Chemistry, Physical
Zongmin Hu, Sheng Chang, Chun Cheng, Chen Sun, Jingrui Liu, Tingting Meng, Yimin Xuan, Meng Ni
Summary: Converting low-grade heat into electricity contributes to sustainability by improving energy efficiency and reducing thermal pollution. A new calcium-ion thermal charging cell (CTCC) with ultrahigh thermopower of 25.2 mV K-1 has been proposed by introducing the concept of calcium-ion batteries into a thermoelectric system. This work enriches the multivalent-ionbased thermocell classes for efficient heat-to-electricity conversion in sustainable energy utilization.
ENERGY STORAGE MATERIALS
(2023)
Review
Chemistry, Physical
Siyuan Wang, Miao Wang, Yunze Zhang, Hongsheng Wang, Hao Fei, Ruoqi Liu, Hui Kong, Ruijie Gao, Siyuan Zhao, Tong Liu, Yuhao Wang, Meng Ni, Francesco Ciucci, Jian Wang
Summary: The sluggish kinetics of the oxygen reduction reaction (ORR) limits the large-scale application of electrochemical energy devices. Metal oxide-supported metal catalysts (MOSMCs) are gaining interest due to their unique electronic configuration and corrosion resistance. MOSMCs can be modulated by engineering the metal oxide substrate and supported metal. This review comprehensively discusses the characterization, modulation strategies, and status of MOSMCs for ORR, and promotes rational design for electrochemical energy devices.
Article
Engineering, Environmental
Idris Temitope Bello, Daqin Guan, Na Yu, Zheng Li, Yufei Song, Xi Chen, Siyuan Zhao, Qijiao He, Zongping Shao, Meng Ni
Summary: This study proposes an approach based on the experimental design paradigm (EDP) to efficiently facilitate the development of cathode materials for protonic ceramic fuel cells (PCFCs). By employing a systematic statistical method, empirical models are generated to reveal the optimal composition and performance characteristics. The feasibility and practicality of the approach are demonstrated through experiments on two cathode materials. The EDP offers a reliable and practical alternative to conventional trial-and-error screening and machine learning methods for designing superior materials for solid-state electrochemical power generation systems.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Siyuan Zhao, Tong Liu, Yayu Zuo, Manhui Wei, Jian Wang, Zongping Shao, Dennis Y. C. Leung, Tianshou Zhao, Meng Ni
Summary: To achieve long-duration energy storage, a technological and economical battery technology is crucial. This study presents an all-around zinc-air flow battery that utilizes a decoupled acid-alkaline electrolyte to elevate the discharge voltage and a reaction modifier KI to lower the charging voltage. This battery exhibits long discharge duration, high power density, unprecedented energy efficiency, and outstanding fast charging ability, making it a promising option for long-duration energy storage and a catalyst for the development of other systems.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Thermodynamics
Qijiao He, Zheng Li, Dongqi Zhao, Jie Yu, Peng Tan, Meiting Guo, Tianjun Liao, Tianshou Zhao, Meng Ni
Summary: A 3D numerical model was developed to study the impact of practical operating temperature on the performance of vanadium redox flow batteries (VRFBs). The results showed that the operating temperature significantly influenced the optimal design of VRFBs. Increasing the inlet flow rate and state of charge, decreasing the electrode porosity and fiber diameter all improved battery performance, with the improvement being more pronounced at higher temperatures.
Article
Environmental Sciences
Linji Xu, Lin Li, Wei Lu, Yilu Gu, Huichuan Zhuang, Qiang He, Lei Zhu
Summary: This study presents an innovative approach to address the scarcity of carbon sources in the bio-treatment of rural domestic wastewater. The ferric sulfate modified sludge-based biochar (SBC) was found to enhance the degradation of particulate organic matter (POM) by providing active sites and functional groups. The findings suggest that ferric sulfate modified SBC holds potential for carbon degradation in rural domestic wastewater.
ENVIRONMENTAL RESEARCH
(2023)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)
