Urchin-like TiO2 structures decorated with lanthanide-doped Bi2S3 quantum dots to boost hydrogen photogeneration performance

The formation of heterojunctions between wide- and narrow-bandgap photocatalysts is commonly employed to boost the efficiency of photocatalytic hydrogen generation. Herein, the photoactivity of urchin-like rutile particles is increased by decorating with pristine as well as Er- or Yb-doped Bi2S3 quantum dots (QDs) at varied QD loadings (1-20 wt%) and doping degrees (1-15 mol%), and the best hydrogen evolution performance is achieved at Er and Yb contents of 10 mol%. Specifically, a hydrogen productivity of 1576.7 mu mol g(cat)(-1) is achieved after 20-h irradiation for TiO2 decorated by 10 mol% Yb-doped Bi2S3 QDs. Theoretical calculations show that the introduction of defects into the Bi2S3 lattice through Er/Yb doping promotes the creation of new energy levels and facilitates the transport of photogenerated charges during photocatalysis.