Article
Materials Science, Multidisciplinary
Karolina A. Ledwa, Leszek Kepinski, Miroslawa Pawlyta
Summary: The catalyst consisting of Pd0.05-xCe0.95O2-y nanoparticles and PdO particles showed high catalytic activity and structural stability in the propane oxidation reaction. The catalyst exhibited high reducibility of ceria at low temperatures and could be easily regenerated after catalytic reaction.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Nanoscience & Nanotechnology
Lohit Sharma, Stephen C. Purdy, Katharine Page, Srinivas Rangarajan, Hien Pham, Abhaya Datye, Jonas Baltrusaitis
Summary: A series of Al2O3-supported Fe-containing catalysts were synthesized and studied, with varying iron surface densities. It was found that in sulfided form, iron was present as dispersed species, showing the highest activity and selectivity within a certain range of loadings.
ACS APPLIED NANO MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Atsuko Tomita, Takeshi Miki, Yutaka Tai
Summary: Ce doping and pretreatment of Pt/Al2O3 catalysts were studied for catalyzing propane oxidation after aging. A small amount of Ce doping enhanced the dispersion of Pt nanoparticles and inhibited sintering, leading to improved oxidation activity. Ce species with less than 3.6 wt% were highly dispersed and critical for promoting propane oxidation.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Organic
E. G. Chepaikin, G. N. Menchikova, S. I. Pomogailo, O. P. Tkachenko, L. M. Kustov
Summary: The paper introduces a method for synthesizing a heterogeneous catalyst with single Pd sites on γ-Al2O3 surface. The method involves the heterogenization of a Pd complex with a hydroxyquinone, followed by hydrogenolysis, reduction, and removal of the ligand. The catalyst exhibited high activity (242 mol of product per g-at Pd per hour) in propane oxidation.
PETROLEUM CHEMISTRY
(2023)
Article
Chemistry, Physical
Natalia Diaz Montenegro, William S. Epling
Summary: The methane oxidation and oxygen storage capacity of a bilayer Pt/Pd/Al2O3 over a Mn0.5Fe2.5O4 spinel catalyst under periodic conditions were studied before and after SO2 exposure. Improvement in CH4 oxidation conversion was observed under periodic conditions compared to steady-state conditions before sulfur exposure. After sulfur exposure, a loss in CH4 oxidation performance and oxygen storage capacity of the spinel material was observed, but regeneration methods under periodic conditions led to improved CH4 conversion.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Engineering, Chemical
Xue Cai, Zitong Zhang, Lili Cai, Xiaoyan Tian, Wending Chu, Weishen Yang
Summary: This study investigates the catalytic performance of Cr2O3/Al2O3 catalysts with different loadings and calcination processes in the dehydrogenation of propane. The results show that the catalysts calcined by air achieved higher propane conversion, while those calcined by H2/Ar exhibited better anticoking ability and resistance against deactivation. The difference in catalytic performance is attributed to the nature of Cr species, the dispersion, and the surface acidity.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Chemistry, Physical
Masato Machida, Shundai Iwashita, Tetsuya Sato, Hiroshi Yoshida, Junya Ohyama, Masao Yoshioka, Shiro Miwa, Takeshi Hashishin
Summary: This study found that Rh catalysts supported on Al2O3-based oxides lose their catalytic activity when exposed to high-temperature oxidizing environments. The diffusion of Rh3+ ions into the support structure causes substantial thermal deactivation. However, the layered structure of LaMgAl11O19 hinders the diffusion of Rh3+, preserving the catalytic activity.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Masato Machida, Shundai Iwashita, Tetsuya Sato, Hiroshi Yoshida, Junya Ohyama, Masao Yoshioka, Shiro Miwa, Takeshi Hashishin
Summary: When Rh catalysts supported on Al2O3-based oxides are exposed to a high-temperature oxidizing environment, they lose their three-way catalytic activity due to the diffusion of Rh3+ into the support structure. The diffusion of Rh3+ is suppressed in the layered structure of hexaaluminate, which effectively blocks further penetration and preserves their reduction to active metallic Rh nanoparticles.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Physical
Nadadur Veeraraghavan Srinath, Alessandro Longo, Hilde Poelman, Ranjith K. Ramachandran, Ji-Yu Feng, Jolien Dendooven, Marie-Francoise Reyniers, Vladimir V. Galvita
Summary: The application of a 1 nm thick alumina coating on PtGa catalysts was found to prevent sintering of metal nanoparticles, enhancing catalyst stability. Increasing coating thickness was directly related to reduced sintering extent. Additionally, the coating reduced carbon formation and slowed down catalyst deactivation rate.
Review
Chemistry, Multidisciplinary
Fushan Feng, Haiyuan Zhang, Shaoqi Chu, Qinqin Zhang, Chao Wang, Guangjian Wang, Fang Wang, Liancheng Bing, Dezhi Han
Summary: Propene is a crucial chemical raw material and its demand is continuously increasing in the propene downstream industry. Propane dehydrogenation (PDH) process is an attractive alternative to efficiently produce high-purity propene compared to traditional catalytic cracking and steam cracking of naphtha. This review summarizes the recent progress on traditional catalysts, emerging non-noble metal catalysts, and carbon catalysts for PDH, discussing key research issues and development directions. It provides a theoretical and technical foundation for developing novel high-efficiency PDH catalysts.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2023)
Article
Engineering, Environmental
Sanja Marinovic, Tihana Mudrinic, Biljana Dojcinovic, Tanja Barudzija, Predrag Bankovic, Tatjana Novakovic
Summary: This study focused on the synthesis and application of porous cobalt-doped alumina catalysts in the degradation of tartrazine. It was found that CoA-500 exhibited the highest efficiency among the investigated catalysts. The degradation reaction followed pseudo-first order kinetics under different temperature conditions.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Environmental
Emad N. Al-Shafei, D. Robert Brown, Sai P. Katikaneni, Hameed Al-Badairy, Oki Muraza
Summary: The study investigated propane dehydrogenation assisted by CO2 using zirconia and titania catalysts. The increase of CO2 ratio led to higher propylene selectivity, while increasing the CO/H-2 ratio was important for olefins yield and catalytic stability. The presence of CO2 played an important role in enhancing propane dehydrogenation.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Chemistry, Physical
Namgi Jeon, Jungmok Oh, Akhil Tayal, Beomgyun Jeong, Okkyun Seo, Sujin Kim, Iljun Chung, Yongju Yun
Summary: Co-based catalysts on Al2O3 support with different compositional distribution of Co species were prepared by heat-treating the precursor under O2, Ar, and H2 atmospheres. The H2-treated catalyst showed superior PDH performance due to higher Co surface concentration and higher ratio of tetrahedral Co2+ in Co-Al2O4. Both tetrahedral Co2+ and metallic Co were found to be active for PDH, with the former showing higher selectivity.
JOURNAL OF CATALYSIS
(2021)
Article
Chemistry, Physical
Roghayeh Bardool, David P. Dean, Hien N. Pham, Abhaya K. Datye, Sona Raeissi, Mohammad Reza Rahimpour, Jeffery T. Miller
Summary: In this study, Ga/gamma-Al2O3 catalysts were evaluated for propane dehydrogenation (PDH). The results showed that the selectivity of propylene decreased with increasing propane conversion. It was found that propylene is a primary product, while light gas by-products are secondary products. The study also confirmed that the same light gas products can be produced by a direct reaction of propylene.
JOURNAL OF CATALYSIS
(2023)
Article
Chemistry, Physical
Ryan Alcala, David P. Dean, Isha Chavan, Che-Wei Chang, Brandon Burnside, Hien N. Pham, Eric Peterson, Jeffrey T. Miller, Abhaya K. Datye
Summary: Catalyst stability, resistance to deactivation, and regeneration are major challenges for high temperature reactions. This study investigates Pt alloys for propane dehydrogenation (PDH) and finds that silica-supported catalysts show excellent selectivity but their regenerability is uncertain. Oxidation in air and treatment in hydrogen can restore the lost catalytic activity, and in situ temperature programmed oxidation reveals two types of coke formed on these catalysts: one on the metal nanoparticle surface and another on the silica support. This work suggests that periodic introduction of hydrogen may prolong the lifetime of PDH catalysts.
APPLIED CATALYSIS A-GENERAL
(2023)
Article
Chemistry, Analytical
Maciej Krawczyk, Ryszard Korbutowicz, Rafal Szukiewicz, Patrycja Suchorska-Wozniak, Maciej Kuchowicz, Helena Teterycz
Summary: In this study, a beta-Ga2O3 epitaxial layer with a highly developed surface was synthesized on gold electrodes on a Al2O3 substrate, and impregnated with gold nanoparticles to achieve p-type doping. The introduction of the Au nanoparticles led to an increase in conductivity and a reversal of the electric response to air containing DMS.
Article
Materials Science, Multidisciplinary
K. Trejgis, K. Ledwa, Leipeng Li, L. Marciniak
Summary: Temperature is a key physical quantity that determines physical phenomena, chemical reactions, and biological processes. Therefore, precise temperature measurement is crucial. A new method called single-band ratiometric luminescence thermometry, which is based on the absorption phenomenon, enables high-sensitivity temperature measurement even under demanding conditions. This study investigates the influence of material size on this method and finds that increasing the nanocrystal size expands the useful temperature range and achieves high relative sensitivities.
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Multidisciplinary
K. Trejgis, K. Ledwa, A. Bednarkiewicz, L. Marciniak
Summary: Luminescence thermometry is a remote temperature measurement technique with great application potential, but existing methods are often inaccurate, requiring further research to improve reliability. Single-band ratiometric luminescence thermometry shows promise with high sensitivity and precision, but more detailed studies are needed to understand its limitations and potential improvements.
NANOSCALE ADVANCES
(2022)
Article
Chemistry, Physical
K. Trejgis, K. Ledwa, A. Bednarkiewicz, L. Marciniak
Summary: Luminescence thermometry (LT) is a remote temperature monitoring technique that uses the single-band ratiometric (SBR) approach for temperature readout. The study investigates the thermometric properties of a single-band ratiometric thermometer based on nanosized NaYF4 and NaGdF4 fluorides doped with Eu3+ ions and reveals a high relative temperature sensitivity in the higher temperature range.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Nanoscience & Nanotechnology
Karolina Kniec, Karolina Anna Ledwa, Lukasz Marciniak
Summary: Coating luminescent nanoparticles with a SiO2 shell can improve their dispersibility, reduce toxicity, and facilitate biofunctionalization; However, it is important to ensure that the encapsulation process does not alter the thermometric properties of the nanoparticles; This study investigates the effect of SiO2 encapsulation on the thermometric properties of YAG:V3+,Nd3+ nanoparticles and finds that increasing the thickness of the SiO2 layer enhances the thermal stability of the luminescence while maintaining a thin shell for high relative sensitivity.
ACS APPLIED NANO MATERIALS
(2022)
Correction
Chemistry, Physical
K. Trejgis, K. Ledwa, A. Bednarkiewicz, L. Marciniak
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Optics
Aleksandra Pilch-Wr, Karolina Ledwa, Agata Kotulska, Artur Bednarkiewicz
Summary: In this study, Yb^3+ and Tm^3+ doped NaYF4 nanoparticles codoped with optically active Ce^3+ ions were synthesized and investigated. The relative emission intensity ratios of the nanoparticles were found to be significantly dependent on external stimuli such as temperature and excitation pulse length. The results showed potential applications for tuning emission and thermal properties in practical uses.
JOURNAL OF LUMINESCENCE
(2022)
Article
Chemistry, Multidisciplinary
Weronika Bodylska, Marzena Fandzloch, Rafal Szukiewicz, Anna Lukowiak
Summary: Ascorbic acid is an important biomolecule that affects the symptoms of many diseases. This study reports a metal-organic framework based on Cu2+ and Eu3+ ions, which can detect ascorbic acid in aqueous media.
Article
Chemistry, Multidisciplinary
Rafael. L. L. Oliveira, Marcin Pisarek, Karolina. A. A. Ledwa, Grzegorz Pasternak, Leszek Kepinski
Summary: This study focuses on the preparation and characterization of porous N-doped carbon derived from chitosan, which serves as a solid support for earth-abundant transition metal oxides. Fe2O3, CoO, NiO, and CuO nanoparticles are loaded onto the support and used as catalysts for the oxidation of primary alcohols using peroxydisulfate or peroxymonosulfate. Quenching tests suggest the presence of a significant contribution from a non-radical oxidation process.
REACTION CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
K. Elzbieciak-Piecka, K. Ledwa, L. Marciniak
Summary: This work proposes a new type of photothermal agent based on inorganic materials heavily doped with Cr3+ ions, which shows significant improvement in optical heating performance and may become an important alternative to currently used photothermal agents.
MATERIALS TODAY CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Sandra Zarska, Rafal Szukiewicz, Sergiu Coseri, Volodymyr Pavlyuk, Dorota Krasowska, Wojciech Ciesielski
Summary: This paper presents new selenium derivatives obtained by modifying the surface of carbon nanotubes. The synthesis was carried out in mild conditions, and the obtained products were characterized using various methods. The selenium derivatives of carbon nanotubes exhibited high selenium and phosphorus contents, reaching 14% and 4.2% respectively.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Nanoscience & Nanotechnology
Malgorzata Misiak, Orest Pavlosiuk, Marcin Szalkowski, Agata Kotulska, Karolina Ledwa, Artur Bednarkiewicz
Summary: Materials capable of emitting UV radiation under NIR excitation are highly desirable for various applications. This study investigates the size, structure, and luminescence properties of tetragonal LiY(Gd)F-4 nanocrystals doped with different concentrations of Gd3+ ions. The results demonstrate that low concentrations of Gd3+ ions can modify the size and up-conversion luminescence, while excess doping leads to the appearance of foreign phases and a significant decrease in luminescence intensity. The intensity and kinetics of Gd3+ up-converted UV emission are also analyzed. These findings provide a foundation for the development of optimized materials and applications based on LiYF4 nanocrystals.
Article
Chemistry, Inorganic & Nuclear
Rafael Lima Oliveira, Karolina A. Ledwa, Olga Chernyayeva, Sebastian Praetz, Christopher Schlesiger, Leszek Kepinski
Summary: A group of doped carbon materials were synthesized using starch as a carbon precursor, and ceria nanoparticles were embedded in these carbon structures to serve as catalysts for imine formation via oxidative coupling. The control of ceria nanoparticle size, presence of Ce3+ cations, and disorder in the ceria nanoparticle structure caused by support-ceria interaction led to an increase in oxygen vacancies and improved catalytic performance.
INORGANIC CHEMISTRY
(2023)
Correction
Chemistry, Multidisciplinary
K. Trejgis, K. Ledwa, A. Bednarkiewicz, L. Marciniak
Summary: In this study, a correction was made for a single-band ratiometric luminescent thermometer based on tetrafluorides operating entirely in the infrared region.
NANOSCALE ADVANCES
(2022)
Correction
Materials Science, Multidisciplinary
K. Trejgis, K. Ledwa, Leipeng Li, L. Marciniak
JOURNAL OF MATERIALS CHEMISTRY C
(2022)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
