4.5 Article

Isoconversional nonisothermal kinetic analysis of municipal solid waste, refuse-derived fuel, and coal

Journal

ENERGY SCIENCE & ENGINEERING
Volume 8, Issue 10, Pages 3728-3739

Publisher

WILEY
DOI: 10.1002/ese3.778

Keywords

coal; isoconversional; model free; MSW; waste

Categories

Funding

  1. University of the Punjab and Lahore Waste Management Company Pakistan
  2. TU-Wien University Library through its Open Access Funding Program

Ask authors/readers for more resources

The thermal characteristics and kinetic behavior of various solid wastes, including refuse-derived fuel (RDF) and municipal solid waste (MSW), were investigated as a potential renewable energy source, in comparison with low-rank coal. The experimental data were obtained in nonisothermal conditions through TGA analysis at specific heating rates. In addition to thermal characteristics of solid fuels, four isoconversional (model-free) kinetic methods: a: Kissinger-Akahira-Sunose (KAS), b: Flynn-Wall-Ozawa (FWO), c: Friedman, and d: Vyazovkin were applied to calculate activation energies. In case of solid wastes, it is possible to say that the trend of activation energies of all isoconversional methods remains almost same in the selected region of conversion (0.1-0.6 and 0.7-0.9). Whereas in case of coal, Friedman model exhibits lower and inconsistent values of activation energy than others selected isoconversional methods. The experimental and modeling results revealed that that solid wastes (RDF and MSW) can be promising alternative energy sources to encounter energy crisis and uncontrolled waste disposal issues.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Multidisciplinary

Fabrication of Isomorphously Substituted W-MFI Membrane with High Performance for Ethanol Separation from Water

Hammad Saulat, Jianhua Yang, Song Wensen, Waseem Raza, Gaohong He

Summary: Isomorphous substitution of tungsten (W) in the MFI membrane improves hydrophobicity and achieves high selectivity for ethanol, making it a promising candidate for catalysts or separation membranes with wide applications.

CHEMISTRY-AN ASIAN JOURNAL (2022)

Article Chemistry, Applied

Sustainable fabrication of large-scale tubular LTA zeolite membranes by a simple wet gel conversion

Lei Wang, Jianhua Yang, Waseem Raza, Jinqu Wang, Jinming Lu, Yan Zhang, Gaohong He

Summary: The sustainable fabrication of LTA zeolite membranes on macroporous alpha-Al2O3 tubes was achieved with a simple wet gel conversion method that significantly reduced gel consumption. The membranes showed good permeation flux and separation factor for ethanol/water dehydration, and the method demonstrated potential for large-scale production with reduced raw materials consumption and waste production.

MICROPOROUS AND MESOPOROUS MATERIALS (2022)

Article Electrochemistry

Zn-doped MnO2 ultrathin nanosheets with rich defects for high performance aqueous supercapacitors

Jianghua Wu, Waseem Raza, Peng Wang, Arshad Hussain, Yangbin Ding, Jian Yu, Yanyan Wu, Jie Zhao

Summary: A one-pot and energy-saving method was developed to manufacture defective manganese oxide materials. The insertion of zinc ions improves manganese oxide conductivity, resulting in a significant increase in the number of defects in the lattice, providing abundant active sites for energy storage.

ELECTROCHIMICA ACTA (2022)

Article Engineering, Environmental

Polyetherimide membrane with tunable porous morphology for safe lithium metal-based batteries

Arshad Hussain, Andleeb Mehmood, Adil Saleem, Muhammad K. Majeed, Waseem Raza, Rashid Iqbal, Sajid Rauf, Ali Saad, Yonggui Deng, Geng Luo, Kai Zong, Liu Wei, Jun Shen, Dongqing Liu, Xingke Cai

Summary: A simple phase inversion technique is used to design and fabricate porous PEI membranes as separators in LMBs, which exhibit better electrochemical performance and higher safety compared to commercial PP membranes.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Environmental Sciences

Experimental design by response surface methodology for efficient cefixime uptake from hospital effluents using anion exchange membrane

Muhammad Ali Khan, Nadeem Raza, Suryyia Manzoor, Ramsha Shuja, Hina Raza, Muhammad Imran Khan, Mudassar Azam, Abdallah Shanableh

Summary: The study evaluates the performance of a quaternary ammonium poly (2, 6-dimethyl-1,4-phenylene oxide) and polyvinyl alcohol (QPPO/PVA) based anion exchange membrane for the removal of cefixime, a third generation cephalosporin antibiotic, from hospital effluents. The membrane’s surface morphology is analyzed using scanning electron microscopy. Experimental parameters are optimized using Response Surface Methodology to determine the maximum uptake capacity (qe). The results indicate that the membrane effectively removes cefixime, with negligible traces remaining in the treated water samples.

CHEMOSPHERE (2023)

Article Chemistry, Physical

Fast assembling MnO2-network electrode materials to achieve high performance asymmetric aqueous supercapacitors

Jianghua Wu, Yue Guo, Waseem Raza, Hajera Gul, Geng Luo, Yangbin Ding, Ying Li, Ying Lv, Jian Yu, Lasharl Najeeb Ur Rehman, Jie Zhao

Summary: Manganese dioxide (MnO2) is a promising material for supercapacitors due to its low cost and environmentally friendly nature. A one-pot, fast and cost-effective method was developed to assemble 3D MnO2 network electrode materials with high utilization rate and fast charge transfer capability. The resulting materials exhibited high specific capacitance and energy density, making them potential candidates for supercapacitor applications.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Engineering, Chemical

Novel 2D/2D BiOBr/Zn(OH)2 photocatalysts for efficient photoreduction CO2

Wenzhen Qin, Qi Yang, Hao Ye, Yu Xie, Zhen Shen, Yue Guo, Yonggui Deng, Yun Ling, Jian Yu, Geng Luo, Nadeem Raza, Waseem Raza, Jie Zhao

Summary: In order to enhance the photocatalytic performance of BiOBr, 2D Zn(OH)2 nanosheets were introduced on 2D BiOBr nanosheets to construct a 2D heterostructure in BiOBr/Zn(OH)2 composites by direct precipitation polymerization.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Engineering, Chemical

Regulating divalent metal species in aluminum-based layered double hydroxides to selectively promote photocatalytic CO production from CO2

Jie Zhao, Yun Lu, Debin Wu, Yuancheng Qin, Yu Xie, Yue Guo, Waseem Raza, Geng Luo, Muhammad Asim Mushtaq, Yangfei Wu, Xiaowan Mu, Yun Ling, Tayiba Ilyas, Qadeer Ul Hassan, Chenmei Gao

Summary: Photocatalysis has the potential to reduce CO2 greenhouse gases. Layered double hydroxides (LDHs) are promising photocatalysts with good catalytic activity, low synthesis cost, and large-scale preparation. This study focused on the effects of different divalent metal species on CO selectivity in aluminum-based LDHs and found that ZnAl-LDH exhibited better CO selectivity and CO yield compared to MgAl-LDH and NiAl-LDH. These findings provide a feasible strategy to improve the selectivity of CO photocatalytic reduction of CO2 by regulating divalent metal species in aluminum-based LDHs.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Chemistry, Multidisciplinary

Negatively Charged Holey Titania Nanosheets Added Electrolyte to Realize Dendrite-Free Lithium Metal Battery

Geng Luo, Dongqing Liu, Jie Zhao, Arshad Hussain, Waseem Raza, Yanyan Wu, Fude Liu, Xingke Cai

Summary: This work reports a self-adaptive electrode construction method to suppress dendrites growth on Li metal anode, which combines the advantages of electrolyte modulation and electrode structure design strategies. By preparing negatively charged titania nanosheets with densely packed nanopores, these holey nanosheets move spontaneously onto the anode under an electrical field, forming a mesoporous structure on the electrode surface. The resulting porous electrode has a large surface area with good lithiophilicity and can efficiently transfer lithium ions (Li+), promoting uniform deposition of Li metal. This work provides a new route for practical applications of Li-metal batteries.

SMALL (2023)

Article Chemistry, Physical

Morphology controlled synthesis of cobalt diselenide nanorods for highly efficient hydrogen evolution in alkaline and acidic media

Sumaira Nazar Hussain, Hajera Gul, Nadeem Raza, Fethi Albouchi, Munir Ahmad, Zeinhom M. El-Bahy, Maham Hussain, Waseem Raza, Ghulam Yasin

Summary: This article develops a facile synthesis process, based on self-templating CoSe2 nanorods on carbon cloth (CoSe2/CC), which serves as an efficient electrocatalyst for the hydrogen evolution reaction (HER) in both alkaline and acidic electrolytes. Compared to bare CoSe2, the CoSe2/CC catalyst exhibits significantly improved HER performance and kinetics. This research could lead to the rational design and fabrication of other transition-metal selenide nanostructured materials for efficient HER electrocatalysis.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Multidisciplinary

Exploring promising photovoltaic properties of dithiophene-based non-fullerene chromophores for efficient organic solar cells: A DFT approach

Iqra Shafiq, Muhammad Khalid, Nadeem Raza, Ataualpa A. C. Braga, Mohamed Khairy, Muhammad Adnan Asghar

Summary: This study investigates the optoelectronic properties of a series of new W-shaped dithiophene-based acceptor chromophores. The results show that these derivatives have narrow band gaps and visible light absorption characteristics. Among them, D2 and D4 show the best optoelectronic properties and can be used as excellent candidate materials.

SYNTHETIC METALS (2023)

Article Engineering, Environmental

Facile fabrication of cobalt doped manganese oxide with hierarchical porosity for peroxymonosulfate activation: Performance investigation, mechanistic insight to degrade organic pollutants in water and DFT study

Shahzad Afzal, Andleeb Mehmood, Lingyue Jin, Ke Pan, Munir Ahmad, Dandan Duan, Yang Wei, Waseem Raza, Tianwei Hao, Hafiz Muhammad Adeel Sharif, Muhammad Sohail, Fengyuan Chen

Summary: In this study, cobalt-doped dumbbell-shaped manganese oxide was successfully synthesized as an efficient catalyst to activate peroxymonosulfate for degrading organic pollutants in wastewater. The synthesized material has a green, facile, and low-temperature synthesis route and hierarchical porosity. The research reveals the excellent catalytic efficiency, recyclability, and activation mechanism of the Co-doped MnOx material. This study is of great importance for the development of advanced oxidation processes and multipurpose applications.

JOURNAL OF HAZARDOUS MATERIALS ADVANCES (2023)

Article Engineering, Environmental

Use of conductive polymer-supported oxide-based photocatalysts for efficient VOCs & SVOCs removal in gas/liquid phase

Zeeshan Ajmal, Yassine Naciri, Munir Ahmad, Abdelghani Hsini, Asmae Bouziani, Mohmed Laabd, Waseem Raza, Adil Murtaza, Anuj Kumar, Sami Ullah, Abdullah G. Al-Sehemi, Ahmed A. Al-Ghamdi, Abdul Qadeer, Asif Hayat, Ridha Djellabi

Summary: Volatile and semi volatile organic compounds (VOCs and SVOCs) are serious environmental pollutants causing diseases worldwide. Photocatalytic technology using conductive polymers (CPs) such as polyaniline (PANI), polypyrrole (PPy), and polythiophene (PTh), along with inorganic oxide semiconductors, shows great potential in removing VOCs and SVOCs due to their multifunctional properties and high efficiency.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2023)

Article Chemistry, Multidisciplinary

Study of modified biomass of Gossypium hirsutum as heavy metal biosorbent

Zeeshan Ali, Muhammad Sajid, Nadeem Raza, Younas Sohail, Muhammad Hayat, Suryyia Manzoor, Nasir Shakeel, Komal Aziz Gill, Ahmad A. Ifseisi, Mohd Zahid Ansari

Summary: This study successfully utilized modified cotton stem powder as a biosorbent for the efficient removal of toxic heavy metal ions from water. Acid and base treatment prior to deployment as a biosorbent improved the maximum uptake capacity. Different instrumental techniques were used to analyze the structure and morphology of the biosorbent. Optimal pH, biosorbent dose, and equilibrium time were determined through experiments.

ARABIAN JOURNAL OF CHEMISTRY (2023)

Article Environmental Sciences

Rice husk ash as a sustainable and economical alternative to chemical additives for enhanced rheology in drilling fluids

Ali Raza, Maham Hussain, Nadeem Raza, Waqas Aleem, Sheraz Ahmad, Sabih Qamar

Summary: Performance evaluation of drilling fluids is crucial for successful drilling projects. Rice husk ash (RHA) has been recognized as a promising alternative additive due to its renewable characteristics. The addition of RHA improves the rheological properties of drilling mud, but also increases filter loss and mud cake thickness. This study suggests that RHA can be a sustainable and cost-effective substitute to conventional chemical additives.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

No Data Available