Article
Materials Science, Multidisciplinary
Chih-Chieh Wang, Shang-Min Lee, Yun-Hao Huang
Summary: Various nitrogen-doped 3-D porous carbon networks were prepared using a hydrothermal treatment of lotus leaves with urea and dicyandiamide as nitrogen sources. These nitrogen-doped networks demonstrated improved discharge capacity, capacity retention, and rate performance as interlayers in lithium sulfur batteries. The enhanced performance was attributed to the presence of more defects, increased lithium ion diffusivity, reduced charge transfer resistance, and a suitable pore size distribution that enabled the capture of more soluble lithium polysulfide.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Engineering, Environmental
Yongqiang He, Junpeng Xue, Min Yang, Tao Huang, Xiaohong Xia, Yuxi Chen, Hongbo Liu
Summary: In this study, multiple active sites decorated porous hollow carbon nanospheres were synthesized through a one-step large scalable carbonization method, demonstrating superior performance for potassium ion batteries.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Nanoscience & Nanotechnology
Fangcai Zheng, Kainian Chu, Yang Yang, Zhiqiang Li, Lingzhi Wei, Yang Xu, Ge Yao, Qianwang Chen
Summary: The optimal interlayer spacing of around 0.38 nm for N, O codoped carbon nanofibers was found to enhance the potassium-storage performances significantly, providing reversible capacity of 627 mAh g(-1) after 200 cycles, excellent rate capability, and ultrastable cycling stability. The study also revealed the interplay between optimal interlayer spacing and active sites induced by N, O heteroatoms in facilitating the intercalation-adsorption mechanism for storing K+ in carbonaceous materials.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Dongyuan Lei, Jinkui Li, Mingwu Xiang, Zirui Zhao, Shixun Yang, Zhe Hu, Mingwei Yuan, Junming Guo, Yi Xia, Wei Bai
Summary: In this study, a material composed of nitrogen-doped porous carbon derived from waste passiflora edulis peel (PINPC) and three-dimensional hollow carbon cloth interlayer (3DHCI) was designed. The PINPC effectively adsorbs polysulfides, while the high conductivity of 3DHCI accelerates the conversion reaction of polysulfides. The resulting sulfur cathode composites exhibit excellent electrochemical performances and can be easily regulated to have a high sulfur content.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Jiefeng Zheng, Yuanji Wu, Yong Tong, Xi Liu, Yingjuan Sun, Hongyan Li, Li Niu
Summary: This study investigates the application of nitrogen-doped mesoporous carbon spheres in potassium-ion batteries, showing that optimized conditions lead to excellent electrochemical performance with high rate capacity and cycling stability. The capacitive-controlled effects play a dominant role in the total storage mechanism of the MCS as anode material.
NANO-MICRO LETTERS
(2021)
Article
Electrochemistry
Yafei Zhang, Wenrui Wei, Chunliu Zhu, Zongying Gao, Jing Shi, Minghua Huang, Shuai Liu, Huanlei Wang
Summary: This study reports a hard template-assisted strategy for designing a class of carbonaceous materials with impressive rate capability and cycling performance as anodes for potassium-ion batteries (PIBs). The materials exhibit high nitrogen/sulfur content, high surface area, and interconnected honeycomb-like structure, which play significant roles in boosting potassium ion storage.
ELECTROCHIMICA ACTA
(2022)
Article
Metallurgy & Metallurgical Engineering
Wen Zhang, Ye Liu, Zhong-qiang Ye, Min Yang, Qi Luo, Jing Dai, Qian-fu Wang, Li Liu
Summary: In this work, porous nitrogen-doped FeP/C nanofibers were synthesized and showed excellent electrochemical performance as an electrode material for potassium-ion batteries.
JOURNAL OF CENTRAL SOUTH UNIVERSITY
(2023)
Article
Electrochemistry
Gaohui Ding, Zhiqiang Li, Lingzhi Wei, Ge Yao, Helin Niu, Changlai Wang, Fangcai Zheng, Qianwang Chen
Summary: This study used a S-doping strategy to expand the interlayer distance of carbon materials and optimize doping sites, resulting in a sample NSCRs with high reversible capacity and ultra-long cycling stability. Theoretical simulation and full-cell performance confirmed the potential of NSCRs in sodium ion batteries.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Physical
Cheng Ma, Zhufeng Zheng, Xianfeng Jia, Xiaojun Liu, Jitong Wang, Wenming Qiao, Licheng Ling
Summary: By synthesizing nitrogen-doped interconnected hollow carbon nanocages, this research achieved a high sulfur loading of 80wt% and high capacity sulfur cathode in lithium sulfur batteries with excellent initial capacity, rate performance, and long lifespan.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Yiwei Sun, Huanlei Wang, Wenrui Wei, Yulong Zheng, Lin Tao, Yixian Wang, Minghua Huang, Jing Shi, Zhi-Cheng Shi, David Mitlin
Summary: The utilization of sulfur-rich graphene nanoboxes in potassium ion battery and potassium ion capacitor anodes demonstrates exceptional rate capability, high reversible capacity, and outstanding cycling stability, along with revealing insights into the reversible energy storage mechanism and kinetic properties.
Article
Chemistry, Multidisciplinary
Chong Xu, Wang Yang, Guang Ma, Sai Che, Yun Li, Yan Jia, Ni Chen, Guoyong Huang, Yongfeng Li
Summary: This study successfully synthesized a series of edge-nitrogen enriched porous carbon nanosheets (ENPCNs) to address the drawbacks of anode materials in sodium-ion batteries (SIBs). Among them, ENPCNs-800 exhibited excellent capacity, rate performance, and cycle life, possibly improved by edge-nitrogen doping and enlarged carbon interlayer distance.
Article
Materials Science, Multidisciplinary
Qian Yu, Ting Dong, Ruyun Qiu, Huanwen Wang
Summary: In this study, a sulfur and nitrogen dual-doped carbon nanofiber (S-NCNF) membrane was successfully synthesized as a novel anode material for Sodium-ion capacitors (SICs), which can improve the efficiency of sodium ion insertion and electron transport. The obtained S-NCNF electrode exhibits high sodium-storage capacity, superior rate performance, and long cycle life, demonstrating high energy and power densities in the fabricated SIC.
MATERIALS RESEARCH BULLETIN
(2021)
Article
Chemistry, Physical
Di Zhang, Bo Niu, Yanan Li, Zhaojin Li, Huan Wang, Qiujun Wang, Fei Yuan, Zhilin Hu, Bo Wang
Summary: Graphene materials have been found to be effective anodes for potassium-ion batteries due to their safety, low cost, and environmental friendliness. However, the repeated insertion/extraction of large-sized K-ions into/from the electrode at low voltage regions often leads to volume expansion and poor cycle stability. To address this issue, researchers have synthesized S-doped hard carbon material (NSHCM2) using biomass and thiourea, which has been found to expand the distance between carbon layers and create more defects, resulting in improved structure stability and reversible capacity. The optimized NSHCM2 electrode exhibits a high capacity of 294 mAh g-1 at 200 mA g-1 and excellent cycling stability of 220 mAh g-1 at 2000 mA g-1 over 5000 cycles. This simple and effective synthesis route enables durable and fast potassium storage.
SOLID STATE IONICS
(2023)
Article
Electrochemistry
Lan Chen, Xuqi Lin, Jingguo Gao, Mingzhong Zou, Yongcong Huang, Guiying Zhao, Jiaxin Li
Summary: Potassium-ion batteries (KIBs) are attractive alternatives to lithium-ion batteries, but achieving fast charge/discharge ability and long-cycle life for carbon-based anodes remains a challenge. By preparing porous and N-doping carbon nanofibers (P-NCNFs), the performance of KIBs can be enhanced.
ELECTROCHIMICA ACTA
(2022)
Article
Chemistry, Applied
Yanli Song, Zhifeng Wang, Yajing Yan, Weimin Zhao, Zhumabay Bakenov
Summary: A composite sulfur cathode with high sulfur loading demonstrated stable and excellent charge/discharge capacity performance, showing great potential for improving the electrochemical performance of Li-S batteries.
MICROPOROUS AND MESOPOROUS MATERIALS
(2021)