Journal
CATALYSTS
Volume 10, Issue 8, Pages -Publisher
MDPI
DOI: 10.3390/catal10080825
Keywords
homogeneous catalysis; sulfur; carbon dioxide; epoxides; cyclic carbonates; polycarbonates
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Funding
- Ministero dell'Istruzione dell'Universita e della Ricerca (MIUR, Roma, PRIN 2017-CO2 as only source of carbons for monomers and polymers: a step forwards circular economy-CO2 only)
- Universita degli Studi di Salerno
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Coupling of CO(2)with epoxides is a green emerging alternative for the synthesis of cyclic organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to provide a comprehensive overview of metal complexes having sulfur-containing ligands as homogeneous catalytic systems able to efficiently promote this transformation with a concise discussion of the most significant results. The crucial role of sulfur as the hemilabile ligand and its influence on the catalytic activity are highlighted as well.
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