4.6 Article

Efficient Depolymerization of Cellulosic Paper Towel Waste Using Organic Carbonate Solvents

Journal

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 8, Issue 34, Pages 13100-13110

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c04102

Keywords

green solvent; propylene carbonate; ethylene carbonate; lignocellulose valorization; waste management; sustainable biorefinery

Funding

  1. Hong Kong International Airport Environmental Fund (Phase 2)
  2. PolyU Project of Strategic Importance

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Efficient depolymerization of lignocellulosic biomass is a prerequisite for sugar production and its subsequent upgradation to fuels and chemicals. Organic carbonate solvents, i.e., propylene carbonate (PC), ethylene carbonate (EC), and dimethyl carbonate (DMC), which are low in toxicity and biodegradable, were investigated as green co-solvents (PC/H2O, EC/H2O, DMC/H2O, solvent ratio 1:1) for depolymerization of cellulosic paper towel waste. PC/H2O and EC/H2O enhanced the depolymerization of paper towel waste and improved the total sugar yield (up to similar to 25 C mol %) compared to H2O only (up to similar to 11 C mol %) under mild reaction conditions (130 degrees C, 20 min). The higher performance of PC/H2O and EC/H2O can be attributed to higher availability of reactive protons in the catalytic system that facilitates efficient acid hydrolysis of recalcitrant cellulosic fibers. Moreover, a substantial buildup of in-vessel pressure by CO2 release during the microwave-assisted reaction because of decomposition of PC or EC might have accelerated the conversion of paper towel wastes. PC and EC are prospective solvents for lignocellulosic biomass conversion considering their green features and notable catalytic performance, which have a good potential for substituting conventional organic solvents such as dimethyl sulfoxide (DMSO) and tetrahydrofuran (THF) that are often considered hazardous in terms of health, safety, and environmental implications.

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