Role of Attractive Interactions in Structure Ordering and Dynamics of Glass-Forming Liquids

A key question in glass physics is what the origin of slow glassy dynamics is. The liquid structure is a natural candidate; however, an apparently severe counterexample has been known. Two model glass-forming liquids, with the standard Lennard-Jones interaction potential and its Weeks-Chandler-Andersen variation without the attractive tail, exhibit very similar structures at the two-body level but drastically different dynamical behaviors in the supercooled states. Here we look at the liquid structure through a (many-body) structural order parameter Theta characterizing the packing capability of local particle arrangements. We show that the structures of these two systems seen by Theta are actually very different at a many-body level, but, quite surprisingly, the macroscopic structure (Theta)-dynamics (tau(a)) relationships commonly follow a Vogel-Fulcher-Tanunann-like function. Furthermore, the mutual information analysis reveals strong local structure-dynamics correlations. Therefore, we conclude that attractive interactions affect the liquid structure in a nonperturbative manner, but a general structural origin of slow dynamics holds for these systems.