Journal
PETROLEUM SCIENCE AND TECHNOLOGY
Volume 38, Issue 22, Pages 992-997Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/10916466.2020.1802484
Keywords
Asphaltenes; EPR spectroscopy; heavy oil; IR spectroscopy; oxidation
Funding
- government assignment for FRC Kazan Scientific Center of Russian Academy of Sciences
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In this work, variations of heavy oil asphaltenes' oxidation reactions under different conditions were investigated. By IR spectroscopy was shown a predominant destruction of occluded and adsorbed compounds in asphaltenes when using KIO(3)and NaIO(4)as oxidizing agents. In the case of CH3COOH/H(2)O(2)and KMnO(4)was determined the destruction of asphaltenes supermolecules with a formation of carboxyl groups. EPR spectroscopy demonstrated decrease of content of vanadyl complexes spin per gram of oxygenates 0.5-2 times in comparison with initial asphaltenes, which indicates the separation of occluded metalloporphyrins. Content of free stable radicals in high molecular products increased in 2-4 times.
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