Stereoselective access to [5.5.0] and [4.4.1] bicyclic compounds through Pd-catalysed divergent higher-order cycloadditions

Pd-Catalyzed Enantioselective [6+4] Cycloaddition of Vinyl Oxetanes with Azadienes to Access Ten-Membered Heterocycles

(2018) Ya-Nong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric [8+3] Annulation Reactions of Tropones or Azaheptafulvenes with meso-Aziridines

(2018) Jianlin Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Total Synthesis of Cyclocitrinol

(2018) Junyang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent synthetic studies towards natural products via [5 + 2] cycloaddition reactions

(2018) Xin Liu et al.   Organic Chemistry Frontiers

Catalytic Asymmetric [4+2]-Cycloadditions Using Tropolones: Developments, Scope, Transformations, and Bioactivity

(2018) Niels Hammer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic 6+4 Cycloadditions via Zwitterionic Intermediates: Chemo-, Regio-, and Stereoselectivities

(2018) Peiyuan Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

(2018) Barry Trost et al.   SYNTHESIS-STUTTGART

Higher-order cycloaddition reactions: A computational perspective

(2018) Teresa A. Palazzo et al.   TETRAHEDRON

Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation

(2017) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic stereoselective [8+2] and [6+4] cycloadditions

(2016) Rasmus Mose et al.   Nature Chemistry

Hydrogen-Atom Transfer Reactions

(2016) Liang Wang et al.   Topics in Current Chemistry

Natural Products with Anti-Bredt and Bridgehead Double Bonds

(2014) Jeffrey Y. W. Mak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Type II Intramolecular [5+2] Cycloaddition: Facile Synthesis of Highly Functionalized Bridged Ring Systems

(2014) Guangjian Mei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Cleavage of Ether CO Bonds by Pincer Iridium Complexes

(2014) Michael C. Haibach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective synthesis of ε-lactones or spiro-heterocycles through NHC-catalyzed annulation: divergent reactivity by catalyst control

(2014) Min Wang et al.   CHEMICAL COMMUNICATIONS

Biomimetic Synthesis of (+)-Ledene, (+)-Viridiflorol, (−)-Palustrol, (+)-Spathulenol, and Psiguadial A, C, and D via the Platform Terpene (+)-Bicyclogermacrene

(2014) Duc N. Tran et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion

(2014) Puneet Kumar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(I)-Catalyzed Regio- and Stereoselective [6 + 3] Cycloaddition of Azomethine Ylides with Tropone: An Efficient Asymmetric Access to Bridged Azabicyclo[4.3.1]decadienes

(2014) Huai-Long Teng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed [6 + 3] Cycloaddition of Tropone with Azomethine Ylides: A Practical Access to Piperidine-Fused Bicyclic Heterocycles

(2014) Honglei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric [8+2] Cycloaddition: Synthesis of Cycloheptatriene-Fused Pyrrole Derivatives

(2013) Mingsheng Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed [8+3] cycloaddition of tropones with 1,1-cyclopropanediesters

(2013) Rubén Tejero et al.   CHEMICAL COMMUNICATIONS

14-Step Synthesis of (+)-Ingenol from (+)-3-Carene

(2013) L. Jorgensen et al.   SCIENCE

Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes

(2010) Fuyuhiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isocyanates: Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (π-Allyl)palladium

(2010) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Catalyzed Inverse-Electron-Demand Diels−Alder Reaction of Tropones

(2009) Pingfan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Access to a Welwitindolinone Core Using Sequential Cycloadditions

(2009) Barry M. Trost et al.   ORGANIC LETTERS

Density Functionals with Broad Applicability in Chemistry

(2008) Yan Zhao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Asymmetric Decarboxylative Lactamization of γ-Methylidene-δ-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantioenriched Lactams

(2008) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Bicyclo[4.3.1]decadienes and Bicyclo[3.3.2]decadienes via [6 + 3] Trimethylenemethane Cycloaddition with Tropones

(2008) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY