4.7 Article

Comparing the effect of single and mixture surfactants on the improvement in stability and thermal conductivity of CuO nanofluid: an experimental study

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 146, Issue 2, Pages 967-980

Publisher

SPRINGER
DOI: 10.1007/s10973-020-10056-8

Keywords

Nanofluid; Stability; Surfactant; Thermal conductivity; Zeta potential

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The present study investigated the effects of single and mixed surfactants on the stability and thermal conductivity of CuO nanofluid. It was found that nanofluid containing mixed surfactants exhibited higher stability, with the maximum stability observed at a 95:5 mixture of CTAB-SDS. Furthermore, the thermal conductivity of the most stable mixture surfactant showed varying performance compared to the single surfactant at different temperatures.
In the present study, the effect of single and mixed surfactants, including SDS and CTAB, on the stability and thermal conductivity of CuO nanofluid is studied. By using a standard two-step method, the nanofluids are prepared. The mass fraction of single surfactants and the CTAB-to-SDS mass fraction ratio of mixture surfactants are considered the parameters of this study. The visual sedimentation technique and zeta potential analysis are employed to evaluate the stability of nanofluid, and the DLS analysis is used to measure the mean diameter of particles. Also, the nanofluid's thermal conductivity coefficient is measured using the KD2 apparatus and compared with the theoretical models. The results show that the nanofluid containing mixed surfactants has more stability than that of the single one so that the maximum stability is observed at a 95:5 mixture of CTAB-SDS. Also, it is observed that the thermal conductivity of the most stable mixture surfactant is lower than the single one at lower temperatures (20, 25, 30 degrees C), while at higher temperatures (35, 40, 45 degrees C), the mixture surfactant demonstrates higher thermal conductivity than the single one. The increases in thermal conductivity of CuO-water nanofluid containing mixture surfactant at 35 degrees C, 40 degrees C, and 45 degrees C are 13.476%, 16.381%, and 16.432%, respectively.

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