Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 142, Issue 30, Pages 12921-12924Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.0c05033
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Funding
- ERC [320869, 682144]
- Leverhulme Trust [RPG-2017-032]
- EPSRC [EP/L015838/1, EP/L015722/1]
- Oxford-Radcliffe Scholarship [EP/L015838/1, EP/L015722/1]
- Swiss National Science Foundation [P300P2_177829]
- Swiss National Science Foundation (SNF) [P300P2_177829] Funding Source: Swiss National Science Foundation (SNF)
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Cyclo[18]carbon (C-18, a molecular carbon allotrope) can be synthesized by dehalogenation of a bromocyclocarbon precursor, C18Br6, in 64% yield, by atomic manipulation on a sodium chloride bilayer on Cu(111) at 5 K, and imaged by highresolution atomic force microscopy. This method of generating C-18 gives a higher yield than that reported previously from the cyclocarbon oxide C24O6. The experimental images of C-18 were compared with simulated images for four theoretical model geometries, including possible bond-angle alternation: D18h cumulene, D-9h polyyne, D-9h cumulene, and C-9h polyyne. Cumulenic structures, with (D-9h) and without (D-18h) bond-angle alternation, can be excluded. Polyynic structures, with (C-9h) and without (D-9h) bond-angle alternation, both show a good agreement with the experiment and are challenging to differentiate.
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