Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 311, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molliq.2020.113277
Keywords
Corrosion inhibitor; ZIF-8 derivative; Copper; EIS; Potentiodynamic polarization
Funding
- National Natural Science Foundation of China [51871105]
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A zeolitic imidazole framework-8 (ZIF-8) derivative was synthesized and developed as the corrosion inhibitor of copper in 0.5 mol/L NaCl solution, and its inhibition performance was investigated by electrochemical measurement and surface analysis. Results show that the ZIF-8 derivative could effectively inhibit copper from corrosion, and the inhibition efficiency was 87.2% at an optimal ZIF-8 derivative concentration of 45 mg/L. The corrosion inhibition mechanism of the ZIF-8 derivative could be explained as follows: the amino functional groups and the pi-system formed by aromatic rings of the ZIF-8 derivative were tightly adsorbed on the copper substrates, which systematically formed a hydrophobic film, thereby effectively inhibiting the corrosion caused by aggressive ions. (C) 2020 Elsevier B.V. All rights reserved.
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