4.7 Article

Synergistic degradation of sulfamethoxazole in an oxalate-enhanced Fered-Fenton system: The critical heterogeneous solid-liquid interfacial mechanism and an insight in practical application

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 392, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2020.122268

Keywords

Fered Fenton; Electrochemical iron cycle; Homogeneous-heterogeneous reactions; Oxalate; Sulfamethoxazole

Funding

  1. National Natural Science Foundation of China [21677055, 21407052]
  2. Fundamental Research Funds for the Central Universities, HUST [2017KFXKJC004, 2016YXMS287]

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It was demonstrated in this study that appropriate concentrations of oxalate (Ox) would lead to greatly accelerated electro-generation of Fe2+ but obviously lower power consumption in the Fered-Fenton system. Depending on the Ti electrode with pristine TiO2 layer, effects of important parameters on the SMX degradation were investigated in the Fered-Fenton-Ox system. It was found that the heterogeneous interfacial electrochemically reduction of Fe-III was critical in the Fered-Fenton-Ox system relying on the surface hydroxyl bonding Fe-III-Ox and formation of Fe-O-Ti bonds. A heterogeneous-homogeneous reaction mechanism was therefore proposed. It included the heterogeneous interfacial electrochemical generation of Fe-II-Ox and the heterogeneous-homogenous Fenton oxidation of pollutants. The promotional role of Ox would be also homogenous and heterogeneous, i.e. maintaining ferric at higher pH and forming specific Fe-III-Ox complex as well as accelerating the solid-liquid interfacial heterogeneous iron cycle. Furthermore, a continuous-flow pilot study was conducted in treating a printing and dyeing industrial wastewater. As compared to conventional Fenton and Fered-Fenton systems, the Fered-Fenton-Ox system could achieve more efficient COD removal with a relative low cost/Delta COD, suggesting great advantages in its practical applications for treating real industrial complex wastewaters.

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