4.6 Article

Oxygen-Rich Activated Carbon Fibers with Exceptional Cu(II) Adsorptivity and Recycling Performance

Journal

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 59, Issue 29, Pages 13088-13094

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.0c01918

Keywords

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Funding

  1. National Natural Science Foundation of China [51473088]
  2. National Key Research and Development Plan of China [2016YFC0301402]
  3. Key Research and Development Plan of Shandong [2018GGX102029, 2017CXGC0409]

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Activated carbon fiber felts (ACFFs) have abundant micropores and excellent physical adsorption properties but have a lower adsorptivity for Cu(II). A novel reactivation process, which introduced sonication in the traditional chemical-activation process, was utilized to prepared oxygen-enriched ACFFs with high surface oxygen content, high specific surface area, and high Cu(II) adsorptivity. In addition, the sonication-assisted pickling regeneration process is researched to realize the cyclic utilization of oxygen-rich ACFFs. Ultimately, the oxygen content, specific surface area, and micropore volume of the oxygen-rich ACFFs can reach 24.21%, 2674.7 m(2).g(-1), and 0.9593 cm(3).g(-1) respectively. The Cu(II) adsorption value of oxygen-rich ACFFs can reach 35.24 mg.g(-1) which is 6.94 times that of pristine felts. Its regeneration rate can always be greater than 100% after five adsorption- regeneration cycles by the sonication-assisted pickling regeneration process.

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