Journal
ELECTROANALYSIS
Volume 32, Issue 9, Pages 2036-2044Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201900767
Keywords
Electrochemically reduced graphene nanoribbons; Electrochemical sensor; Dopamine; Screen printed electrode; Uric acid
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In this research, the graphene oxide nanoribbons (GONRs) were substantially synthesized by the oxidative longitudinal unzipping of the multi-walled carbon nanotubes (MWCNTs). Then, a direct electrochemical technique was employed for reducing GONRs adsorbed on the screen printed carbon electrode (SPCE). Electrochemical reduction effectively eliminated the oxygen-containing groups in the GONRs and produced the electrochemically reduced graphene nanoribbons (ERGNRs). Field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD) were employed to characterize the materials. The modified SPCE with ERGNRs (ERGNRs/SPCE) displayed acceptable electrocatalytic characteristics towards the oxidation of dopamine (DA) and uric acid (UA) and applied to the simultaneous determination of these two analytes. ERGNRs/SPCE has a peak potential difference of 245 mV between DA and UA. The anodic peak currents of DA and UA were linear within the concentration ranges between 0.5 and 300.0 mu M and 1.0 to 400.0 mu M in phosphate buffer (pH=7.0) respectively. The detection limit of the technique for DA is 0.15 mu M (S/N=3) and for UA is 0.3 mu M (S/N=3). The proposed approach has been applied to the determination of DA and UA in real samples and generated acceptable outputs.
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