4.4 Article

Demonstration of variable angle super-heterodyne dynamic light scattering for measuring colloidal dynamics

Journal

COLLOID AND POLYMER SCIENCE
Volume 299, Issue 2, Pages 259-268

Publisher

SPRINGER
DOI: 10.1007/s00396-020-04669-6

Keywords

Light scattering; Super-heterodyning; Colloids; Diffusion; Instrumentation

Funding

  1. Projekt DEAL
  2. Deutsche Forschungsgemeinschaft (DFG) [Pa459/18-2]
  3. Inneruniversitare Forschungsforderung der Johannes Gutenberg-Universitat, Mainz
  4. Deutsche Akademische Austauschdienst (DAAD)
  5. Duitsland Instituut Amsterdam (DIA)
  6. DFG [DFG/GSC 266]

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The study demonstrates a prototype light scattering instrument that combines frequency domain approach with the versatility of a standard homodyne setup for investigations over a large range of scattering vectors. By comparing with reference experiments in correlation-time space, the novel approach is shown to determine diffusion constants and hydrodynamic radii with high precision and accuracy. Possible future applications are briefly discussed.
We demonstrate a prototype light scattering instrument combining a frequency domain approach to the intermediate scattering function from Super-Heterodyning Doppler Velocimetry with the versatility of a standard homodyne dynamic light scattering goniometer setup for investigations over a large range of scattering vectors. Comparing to reference experiments in correlation-time space, we show that the novel approach can determine diffusion constants and hence hydrodynamic radii with high precision and accuracy. Possible future applications are discussed shortly.

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