4.7 Article

MOF assisted synthesis of a Ho2O3/CNT nanocomposite photocatalyst for organic pollutants degradation

Journal

CERAMICS INTERNATIONAL
Volume 46, Issue 11, Pages 19084-19091

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.04.242

Keywords

Ceramics; Holmium oxide; Photocatalyst; Organic pollutants

Funding

  1. Scientific and Science and Technology Research Program of Chongqing Municipal Education Commission [KJQN201903408, KJQN201803307]

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In this work, a holmium oxide (Ho2O3/CNT) photocatalysts were successfully synthesized through a MOF assisted route for the first time. The effects of the morphology and purity on the photocatalytic behavior of the products, were investigated by determining various physicochemical properties. The Ho2O3/CNT nanocomposite was systematically analyzed by powder X-ray diffraction (P-XRD), transmission electron microscopy (TEM), ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy studies. The Ho2O3 derived from a MOF assisted synthetic route using Ho(NO3)(3)center dot 5H(2)O and terephthalic acid with a 1:1 M ratio at a temperature of 750 degrees C for 3 h prove the most advantageous, 98% degradation of 20 mg/L aqueous tetracycline pollutant was observed within 60 min. The elevated photocatalytic activity was mainly attributable to the unique synthetic route, improved crystallinity, wide UV-light absorption rate and excellent adsorption capabilities of CNT, as well as enhanced oxygen deficiency. The photocatalytic results confirm that the Ho2O3/CNT nanocomposite is an efficient photocatalyst for the degradation of toxic tetracycline pollutant and is thus suitable for use in environmental remediation.

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