Journal
APPLIED CATALYSIS A-GENERAL
Volume 602, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2020.117743
Keywords
NO decomposition; Ba3Y4O9; Co-doping effect
Categories
Funding
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan through the Japan Society for the Promotion of Science (JSPS) [16H06293, 19H00821]
- Grants-in-Aid for Scientific Research [19H00821] Funding Source: KAKEN
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Direct decomposition of NO on Ba3Y4O9 doped with Cu and Sc was studied and it was found that co-doping of Sc and Cu into Ba3Y4O9 was effective for increasing both lattice stability and NO decomposition activity. In particular, Ba3Y3Sc0.6Cu0.4O9 (10 % Cu and 15 % Sc doping) catalyst showed N-2 and O-2 yield of 90 % and 99 %, respectively, in NO decomposition reaction at 700 degrees C. Comparing with the pristine and single-metal doped system, the optimized catalyst showed superior long-term stability and increased activity under O-2, and water vapor co-existence conditions because of the increased stability of crystal structure, improved lattice oxygen mobility and weakened oxygen adsorption on the surface. TPD and in-situ FT-IR results suggested that the co-doping effect was assigned to the easier removal of surface NO2- or NO3- species which blocks the active site to NO decomposition.
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