Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 46, Pages 20480-20484Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202009960
Keywords
anions; copper; macrocycles; self-assembly; structure elucidation
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Funding
- EPSRC [EP/R010366/1]
- Royal Society [RGS\R1\191154]
- EPSRC [EP/R010366/1] Funding Source: UKRI
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The ligandsL(1)andL(2)form trinuclear self-assembled complexes with Cu2+(i.e. [(L-1)(2)Cu-3](6+)or [(L-2)(2)Cu-3](6+)) both of which act as a host to a variety of anions. Inclusion of long aliphatic chains on these ligands allows the assemblies to extract anions from aqueous media into organic solvents. Phosphate can be removed from water efficiently and highly selectively, even in the presence of other anions.
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