Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 362, Issue 18, Pages 3851-3856Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000754
Keywords
copper catalysis; thiocyanation; 1,5-hydrogen atom transfer; alkyl C(sp(3))-H activation
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Funding
- National Natural Science Foundation of China [21801250]
- Fundamental Research Funds for the Central Universities [18CX02141A]
- Shandong Provincial Natural Science Foundation [ZR2019QB002]
- China University of Petroleum (East China)
- Zhejiang University of Technology
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A method for site-selective intermolecular C(sp(3))-H thiocyanation of aliphatic sulfonamides is developed using cheap trimethylsilyl isothiocyanate (TMSNCS) as the thiocyanation reagent, catalyzed by simple Cu(I)/phenanthroline complex. The mild, and modular protocol allows remote C(sp(3))-H thiocyanation in promising yields with a broad substrate scope.
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