Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning

Accurate Prediction for Dynamic Hybrid Local and Charge Transfer Excited States from Optimally Tuned Range-Separated Density Functionals

(2019) Yanrong Jiang et al.   Journal of Physical Chemistry C

Near-infrared quadrupolar chromophores combining three-coordinate boron-based superdonor and -acceptor units

(2019) Tom Stennett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Optimization of Aqueous Stability versus π‐Conjugation in Tetracationic Bis(triarylborane) Chromophores: Applications in Live‐Cell Fluorescence Imaging

(2019) Stefanie Griesbeck et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Effect of Branching on One‐ and Two‐Photon Absorption, Cell Viability and Localization of Cationic Triarylborane Chromophores with Dipolar vs. Octupolar Charge Distributions for Cellular Imaging†

(2019) Stefanie Griesbeck et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triarylborane‐Based Helical Donor–Acceptor Compounds: Synthesis, Photophysical, and Electronic Properties

(2019) Xiangqing Jia et al.   CHEMISTRY-A EUROPEAN JOURNAL

A quadrupolar bis‐triarylborane chromophore as a fluorimetric and chirooptic probe for simultaneous and selective sensing of DNA, RNA and proteins

(2019) Željka Ban et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heavy Atom Effect of Bromine Significantly Enhances Exciton Utilization of Delayed Fluorescence Luminogens

(2018) Shifeng Gan et al.   ACS Applied Materials & Interfaces

Optically Triggered Planarization of Boryl-Substituted Phenoxazine: Another Horizon of TADF Molecules and High-Performance OLEDs

(2018) Deng-Gao Chen et al.   ACS Applied Materials & Interfaces

High-Performance Dibenzoheteraborin-Based Thermally Activated Delayed Fluorescence Emitters: Molecular Architectonics for Concurrently Achieving Narrowband Emission and Efficient Triplet-Singlet Spin Conversion

(2018) In Seob Park et al.   ADVANCED FUNCTIONAL MATERIALS

Touch-sensitive mechanoluminescence crystals comprising a simple purely organic molecule emit bright blue fluorescence regardless of crystallization methods

(2018) Kai Zhang et al.   CHEMICAL COMMUNICATIONS

Fusing triphenylphosphine with tetraphenylborate: introducing the 9-phosphatriptycene-10-phenylborate (PTB) anion

(2018) Marcus W. Drover et al.   CHEMICAL COMMUNICATIONS

Trifluoromethane modification of thermally activated delayed fluorescence molecules for high-efficiency blue organic light-emitting diodes

(2018) Masayuki Yokoyama et al.   CHEMICAL COMMUNICATIONS

Spin-Vibronic Mechanism for Intersystem Crossing

(2018) Thomas J. Penfold et al.   CHEMICAL REVIEWS

Molecular Design of Deep Blue Thermally Activated Delayed Fluorescence Materials Employing a Homoconjugative Triptycene Scaffold and Dihedral Angle Tuning

(2018) Wenliang Huang et al.   CHEMISTRY OF MATERIALS

Boron-based donor-spiro-acceptor compounds exhibiting thermally activated delayed fluorescence (TADF)

(2018) Marco Stanoppi et al.   DALTON TRANSACTIONS

An Air-Stable Organoboron Compound, Dithienooxadiborepine: Preparation and Functionalization

(2018) Qifan Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Torsional Bias as a Strategy To Tune Singlet–Triplet Gaps in Organic Diradicals

(2018) Justin R. DeFrancisco et al.   Journal of Physical Chemistry C

Design of Conformationally Distorted Donor–Acceptor Dyads Showing Efficient Thermally Activated Delayed Fluorescence

(2018) Gereon A. Sommer et al.   Journal of Physical Chemistry Letters

Diboron compound-based organic light-emitting diodes with high efficiency and reduced efficiency roll-off

(2018) Tien-Lin Wu et al.   Nature Photonics

Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand

(2018) Shota Konishi et al.   ORGANOMETALLICS

Emergence of White Organic Light-Emitting Diodes Based on Thermally Activated Delayed Fluorescence

(2018) Peng Xiao et al.   Applied Sciences-Basel

Thermally Activated Delayed Fluorescence (TADF) Path toward Efficient Electroluminescence in Purely Organic Materials: Molecular Level Insight

(2018) Xian-Kai Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Computational Design of Thermally Activated Delayed Fluorescence Materials: The Challenges Ahead

(2018) Yoann Olivier et al.   Journal of Physical Chemistry Letters

Efficient donor-acceptor-donor borylated compounds with extremely small ΔEST for thermally activated delayed fluorescence OLEDs

(2018) Chih-Chieh Tsai et al.   ORGANIC ELECTRONICS

Rational design of near-infrared absorbing organic dyes: Controlling the HOMO-LUMO gap using quantitative molecular orbital theory

(2018) Ayush K. Narsaria et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Solid-State Emissive Triarylborane-Based [2.2]Paracyclophanes Displaying Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence

(2018) Meng-Yuan Zhang et al.   ORGANIC LETTERS

Phenanthroline-tBuOK Promoted Intramolecular C–H Arylation of Indoles with ArI under Transition-Metal-Free Conditions

(2018) Xiang-Huan Shan et al.   ORGANIC LETTERS

Charge-Transfer Emitting Triarylborane π-Electron Systems

(2017) Sheng-Yong Li et al.   INORGANIC CHEMISTRY

Facile Route to Quadruply Annulated Borepins

(2017) Kai Schickedanz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Up-Conversion Intersystem Crossing Rates in Organic Emitters for Thermally Activated Delayed Fluorescence: Impact of the Nature of Singlet vs Triplet Excited States

(2017) Pralok K. Samanta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Triarylborane-Based Materials for OLED Applications

(2017) Gulsen Turkoglu et al.   MOLECULES

Pyrimidine-based twisted donor–acceptor delayed fluorescence molecules: a new universal platform for highly efficient blue electroluminescence

(2017) In Seob Park et al.   Chemical Science

Recent developments in and perspectives on three-coordinate boron materials: a bright future

(2017) Lei Ji et al.   Chemical Science

Halogen-induced internal heavy-atom effect shortening the emissive lifetime and improving the fluorescence efficiency of thermally activated delayed fluorescence emitters

(2017) Yepeng Xiang et al.   Journal of Materials Chemistry C

CN-Containing donor–acceptor-type small-molecule materials for thermally activated delayed fluorescence OLEDs

(2017) Xudong Cao et al.   Journal of Materials Chemistry C

Photophysics of thermally activated delayed fluorescence molecules

(2017) Fernando B Dias et al.   Methods and Applications in Fluorescence

Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO-LUMO Separation by the Multiple Resonance Effect

(2016) Takuji Hatakeyama et al.   ADVANCED MATERIALS

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Water-Soluble Triarylborane Chromophores for One- and Two-Photon Excited Fluorescence Imaging of Mitochondria in Cells

(2016) Stefanie Griesbeck et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Importance of Vibronic Coupling for Efficient Reverse Intersystem Crossing in Thermally Activated Delayed Fluorescence Molecules

(2016) Jamie Gibson et al.   CHEMPHYSCHEM

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: towards the combined electrochemical-frustrated Lewis pair activation of H2

(2016) Robin J. Blagg et al.   DALTON TRANSACTIONS

Synthesis of 2-(lutidinyl)organoboranes and their reactivities against dihydrogen and pinacol borane

(2016) Junhao Zheng et al.   DALTON TRANSACTIONS

Substituent Directed Phototransformations of BN-Heterocycles: Elimination vs Isomerization via Selective B–C Bond Cleavage

(2016) Deng-Tao Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Luminescent Main-Chain Organoborane Polymers: Highly Robust, Electron-Deficient Poly(oligothiophene borane)s via Stille Coupling Polymerization

(2016) Xiaodong Yin et al.   MACROMOLECULES

Dimesitylarylborane-based luminescent emitters exhibiting highly-efficient thermally activated delayed fluorescence for organic light-emitting diodes

(2016) Yuichi Kitamoto et al.   ORGANIC ELECTRONICS

Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence

(2016) Marc K. Etherington et al.   Nature Communications

Thermally activated delayed fluorescence blue dopants and hosts: from the design strategy to organic light-emitting diode applications

(2016) Mallesham Godumala et al.   Journal of Materials Chemistry C

The Role of Local Triplet Excited States and D-A Relative Orientation in Thermally Activated Delayed Fluorescence: Photophysics and Devices

(2016) Fernando B. Dias et al.   Advanced Science

Metal–Organic and Organic TADF-Materials: Status, Challenges and Characterization

(2016) Larissa Bergmann et al.   Topics in Current Chemistry

A new way towards high-efficiency thermally activated delayed fluorescence devices via external heavy-atom effect

(2016) Wenzhi Zhang et al.   Scientific Reports

Triarylboron-Based Fluorescent Organic Light-Emitting Diodes with External Quantum Efficiencies Exceeding 20 %

(2015) Katsuaki Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Designs of Functional π-Electron Materials based on the Characteristic Features of Boron

(2015) Atsushi Wakamiya et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

High efficiency pure blue thermally activated delayed fluorescence molecules having 10H-phenoxaborin and acridan units

(2015) Masaki Numata et al.   CHEMICAL COMMUNICATIONS

A boron-doped helicene as a highly soluble, benchtop-stable green emitter

(2015) Kai Schickedanz et al.   CHEMICAL COMMUNICATIONS

Luminescent Quadrupolar Borazine Oligomers: Synthesis, Photophysics, and Two-Photon Absorption Properties

(2015) Pangkuan Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organotrifluoroborates: Another Branch of the Mighty Oak

(2015) Gary A. Molander   JOURNAL OF ORGANIC CHEMISTRY

Nature of Highly Efficient Thermally Activated Delayed Fluorescence in Organic Light-Emitting Diode Emitters: Nonadiabatic Effect between Excited States

(2015) Xian-Kai Chen et al.   Journal of Physical Chemistry C

Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles

(2015) Zuolun Zhang et al.   Chemical Science

Optical and electronic properties of air-stable organoboron compounds with strongly electron-accepting bis(fluoromesityl)boryl groups

(2015) Zuolun Zhang et al.   Chemical Science

Purely organic electroluminescent material realizing 100% conversion from electricity to light

(2015) Hironori Kaji et al.   Nature Communications

Blue-emitting organic electrofluorescence materials: progress and prospective

(2015) Wen-Cheng Chen et al.   Journal of Materials Chemistry C

Light blue and green thermally activated delayed fluorescence from 10H-phenoxaborin-derivatives and their application to organic light-emitting diodes

(2015) Yuichi Kitamoto et al.   Journal of Materials Chemistry C

Highly Electron-Deficient and Air-Stable Conjugated Thienylboranes

(2014) Xiaodong Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental and Theoretical Studies of Quadrupolar Oligothiophene-Cored Chromophores Containing Dimesitylboryl Moieties as π-Accepting End-Groups: Syntheses, Structures, Fluorescence, and One- and Two-Photon Absorption

(2014) Lei Ji et al.   CHEMISTRY-A EUROPEAN JOURNAL

D-π-A Triarylboron Compounds with Tunable Push-Pull Character Achieved by Modification of Both the Donor and Acceptor Moieties

(2014) Zuolun Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Third-generation organic electroluminescence materials

(2014) Chihaya Adachi   JAPANESE JOURNAL OF APPLIED PHYSICS

A general route for synthesis of N-aryl phenoxazines via copper(i)-catalyzed N-, N-, and O-arylations of 2-aminophenols

(2014) Nan Liu et al.   RSC Advances

A Hybridized Local and Charge-Transfer Excited State for Highly Efficient Fluorescent OLEDs: Molecular Design, Spectral Character, and Full Exciton Utilization

(2014) Weijun Li et al.   Advanced Optical Materials

Organic Light-Emitting Diodes with 30% External Quantum Efficiency Based on a Horizontally Oriented Emitter

(2013) Sei-Yong Kim et al.   ADVANCED FUNCTIONAL MATERIALS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

C-Functionalized, Air- and Water-Stable 9,10-Dihydro-9,10-diboraanthracenes: Efficient Blue to Red Emitting Luminophores

(2013) Christian Reus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of the CO2 Adducts of Amine/Bis(2,4,6-tris(trifluoromethyl)phenyl)borane Pairs

(2013) Zhenpin Lu et al.   ORGANOMETALLICS

Frustrated Lewis Pair Induced Boroauration of Terminal Alkynes

(2012) Hongyan Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enhanced Electroluminescence Efficiency in a Spiro-Acridine Derivative through Thermally Activated Delayed Fluorescence

(2012) Gábor Méhes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient organic light-emitting diodes through up-conversion from triplet to singlet excited states of exciplexes

(2012) Kenichi Goushi et al.   APPLIED PHYSICS LETTERS

High-efficiency organic light-emitting diodes utilizing thermally activated delayed fluorescence from triazine-based donor–acceptor hybrid molecules

(2012) Sae Youn Lee et al.   APPLIED PHYSICS LETTERS

Efficient green thermally activated delayed fluorescence (TADF) from a phenoxazine–triphenyltriazine (PXZ–TRZ) derivative

(2012) Hiroyuki Tanaka et al.   CHEMICAL COMMUNICATIONS

Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor–acceptor structure

(2012) Tetsuya Nakagawa et al.   CHEMICAL COMMUNICATIONS

TICT fluorescence of N-borylated 2,5-diarylpyrroles: a gear like dual motion in the excited state

(2012) Takuhiro Taniguchi et al.   DALTON TRANSACTIONS

Substituent Effects on Twisted Internal Charge Transfer Excited States of N-Borylated Carbazoles and (Diphenylamino)boranes

(2012) Jian Wang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Impact of Electronic Coupling, Symmetry, and Planarization on One- and Two-Photon Properties of Triarylamines with One, Two, or Three Diarylboryl Acceptors

(2012) Nikolay S. Makarov et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Design of Efficient Thermally Activated Delayed Fluorescence Materials for Pure Blue Organic Light Emitting Diodes

(2012) Qisheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly efficient organic light-emitting diodes from delayed fluorescence

(2012) Hiroki Uoyama et al.   NATURE

Organic light-emitting diodes employing efficient reverse intersystem crossing for triplet-to-singlet state conversion

(2012) Kenichi Goushi et al.   Nature Photonics

Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism

(2011) Zhenpin Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental and Theoretical Studies on Organic D-π-A Systems Containing Three-Coordinate Boron Moieties as both π-Donor and π-Acceptor

(2011) Lothar Weber et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-containing triarylboron compounds for optoelectronic applications

(2011) Zachary M. Hudson et al.   DALTON TRANSACTIONS

Fluoride Ion Complexation and Sensing Using Organoboron Compounds

(2010) Casey R. Wade et al.   CHEMICAL REVIEWS

Switching High Two-Photon Efficiency: From 3,8,13-Substituted Triindole Derivatives to Their 2,7,12-Isomers

(2010) Lei Ji et al.   ORGANIC LETTERS

Impact of Donor−Acceptor Geometry and Metal Chelation on Photophysical Properties and Applications of Triarylboranes

(2009) Zachary M. Hudson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fluoride Ion Recognition by Chelating and Cationic Boranes

(2009) Todd W. Hudnall et al.   ACCOUNTS OF CHEMICAL RESEARCH

9,10-Dihydro-9,10-diboraanthracene: Supramolecular Structure and Use as a Building Block for Luminescent Conjugated Polymers

(2009) Andreas Lorbach et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal phosphors with cyclometalating ligands: fundamentals and applications

(2009) Yun Chi et al.   CHEMICAL SOCIETY REVIEWS

Synthetic, structural, photophysical and computational studies on 2-arylethynyl-1,3,2-diazaboroles

(2009) Lothar Weber et al.   DALTON TRANSACTIONS

Syntheses, structures, two-photon absorption cross-sections and computed second hyperpolarisabilities of quadrupolar A–π–A systems containing E-dimesitylborylethenyl acceptors

(2009) Christopher D. Entwistle et al.   JOURNAL OF MATERIALS CHEMISTRY

Functional metallophosphors for effective charge carrier injection/transport: new robust OLED materials with emerging applications

(2009) Wai-Yeung Wong et al.   JOURNAL OF MATERIALS CHEMISTRY

Consistent van der Waals Radii for the Whole Main Group

(2009) Manjeera Mantina et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The Synthesis and One- and Two-Photon Optical Properties of Dipolar, Quadrupolar and Octupolar Donor-Acceptor Molecules Containing Dimesitylboryl Groups

(2008) Jonathan C. Collings et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intersystem Crossing Mediated by Photoinduced Intramolecular Charge Transfer:  Julolidine−Anthracene Molecules with Perpendicular π Systems

(2008) Zachary E. X. Dance et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Symmetry-dependent solvation of donor-substituted triarylboranes

(2008) Uwe Megerle et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

A New Design Strategy for Organic Optoelectronic Materials by Lateral Boryl Substitution

(2007) Mark Elbing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION